Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide
Abstract
A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.
- Inventors:
-
- Lockport, IL
- Westmount, IL
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- OSTI Identifier:
- 868718
- Patent Number(s):
- 5198589
- Assignee:
- United States of America as represented by United States (Washington, DC)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- DOE Contract Number:
- W-31109-ENG-38
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- cobalt; carbonyl; catalyzed; olefin; hydroformylation; supercritical; carbon; dioxide; method; provided; reacts; catalyst; reaction; gases; hydrogen; monoxide; presence; solvent; provides; yields; n-isomer; product; gas-liquid; mixing; rate; limitation; seen; conventional; oxo; processes; liquid; media; reaction gases; supercritical carbon; reaction gas; carbon dioxide; carbon monoxide; cobalt carbonyl; carbonyl catalyst; olefin hydroformylation; /999/
Citation Formats
Rathke, Jerome W, and Klingler, Robert J. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide. United States: N. p., 1993.
Web.
Rathke, Jerome W, & Klingler, Robert J. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide. United States.
Rathke, Jerome W, and Klingler, Robert J. Fri .
"Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide". United States. https://www.osti.gov/servlets/purl/868718.
@article{osti_868718,
title = {Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide},
author = {Rathke, Jerome W and Klingler, Robert J},
abstractNote = {A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 1993},
month = {Fri Jan 01 00:00:00 EST 1993}
}
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Works referenced in this record:
Propylene hydroformylation in supercritical carbon dioxide
journal, May 1991
- Rathke, J. W.; Klingler, R. J.; Krause, T. R.
- Organometallics, Vol. 10, Issue 5