Method of selective reduction of halodisilanes with alkyltin hydrides
Abstract
The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.
- Inventors:
-
- Fenton, MI
- Midland, MI
- Issue Date:
- Research Org.:
- Midwest Research Institute, Kansas City, MO (United States)
- OSTI Identifier:
- 866819
- Patent Number(s):
- 4798713
- Assignee:
- Dow Corning Corporation (Midland, MI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC02-83CH10093
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- method; selective; reduction; halodisilanes; alkyltin; hydrides; relates; sequential; reacting; compounds; temperature; below; trialkyltin; dialkyltin; dihydrides; free; radical; intermediates; selectively; sequentially; reduce; si-cl; si-br; si-i; bonds; leaving; intact; si-si; si-f; free radical; selective reduction; alkyltin hydrides; sequentially reduce; /423/
Citation Formats
D'Errico, John J, and Sharp, Kenneth G. Method of selective reduction of halodisilanes with alkyltin hydrides. United States: N. p., 1989.
Web.
D'Errico, John J, & Sharp, Kenneth G. Method of selective reduction of halodisilanes with alkyltin hydrides. United States.
D'Errico, John J, and Sharp, Kenneth G. Sun .
"Method of selective reduction of halodisilanes with alkyltin hydrides". United States. https://www.osti.gov/servlets/purl/866819.
@article{osti_866819,
title = {Method of selective reduction of halodisilanes with alkyltin hydrides},
author = {D'Errico, John J and Sharp, Kenneth G},
abstractNote = {The invention relates to the selective and sequential reduction of halodisilanes by reacting these compounds at room temperature or below with trialkyltin hydrides or dialkyltin dihydrides without the use of free radical intermediates. The alkyltin hydrides selectively and sequentially reduce the Si-Cl, Si-Br or Si-I bonds while leaving intact the Si-Si and Si-F bonds present.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 1989},
month = {Sun Jan 01 00:00:00 EST 1989}
}
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