Thermochemical production of hydrogen

Dreyfuss, Robert M

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Title: Thermochemical production of hydrogen

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Abstract

A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal and Z represents a metalloid selected from the arsenic-antimony-bismuth and selenium-tellurium subgroups of the periodic system: 2MO + Z + SO.sub.2 .fwdarw. MZ + MSO.sub.4 (1) mz + h.sub.2 so.sub.4 .fwdarw. mso.sub.4 + h.sub.2 z (2) 2mso.sub.4 .fwdarw. 2mo + so.sub.2 + so.sub.3 + 1/20.sub.2 (3) h.sub.2 z .fwdarw. z + h.sub.2 (4) h.sub.2 o + so.sub.3 .fwdarw. h.sub.2 so.sub.4 (5) the net reaction is the decomposition of water into hydrogen and oxygen.

Inventors:

Dreyfuss, Robert M ^[1]

Mount Vernon, NY

Issue Date:: Tue Jul 13 00:00:00 EDT 1976

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

OSTI Identifier:: 862596

Patent Number(s):: 3969495

Assignee:: United States of America as represented by United States Energy (Washington, DC)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
C01B3/068 - {the hydrogen being generated from the water as a result of a cyclus of reactions, not covered by groups C01B3/063 or C01B3/105}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/36 - Hydrogen production from non-carbon containing sources

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DOE Contract Number:: W-740-5ENG-48

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: thermochemical; production; hydrogen; reaction; cycle; generation; water; comprising; following; sequence; reactions; represents; metal; z; metalloid; selected; arsenic-antimony-bismuth; selenium-tellurium; subgroups; periodic; 2mo; fwdarw; mz; mso; 2mso; 20; net; decomposition; oxygen; chemical reaction; reaction cycle; thermochemical production; chemical product; following sequence; water comprising; thermochemical reaction; /423/

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                    Dreyfuss, Robert M. Thermochemical production of hydrogen.  United States: N. p., 1976. 
        Web.

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                    Dreyfuss, Robert M. Thermochemical production of hydrogen.  United States.

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                    Dreyfuss, Robert M. Tue .  
        "Thermochemical production of hydrogen".  United States.  https://www.osti.gov/servlets/purl/862596.

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@article{osti_862596,

  title        = {Thermochemical production of hydrogen},

  author       = {Dreyfuss, Robert M},

  abstractNote = {A thermochemical reaction cycle for the generation of hydrogen from water comprising the following sequence of reactions wherein M represents a metal and Z represents a metalloid selected from the arsenic-antimony-bismuth and selenium-tellurium subgroups of the periodic system: 2MO + Z + SO.sub.2 .fwdarw. MZ + MSO.sub.4 (1) mz + h.sub.2 so.sub.4 .fwdarw. mso.sub.4 + h.sub.2 z (2) 2mso.sub.4 .fwdarw. 2mo + so.sub.2 + so.sub.3 + 1/20.sub.2 (3) h.sub.2 z .fwdarw. z + h.sub.2 (4) h.sub.2 o + so.sub.3 .fwdarw. h.sub.2 so.sub.4 (5) the net reaction is the decomposition of water into hydrogen and oxygen.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Jul 13 00:00:00 EDT 1976},

  month        = {Tue Jul 13 00:00:00 EDT 1976}

}

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