Process for Photochemical Chlorination of Hydrocarbons
Abstract
A process for chlorination of a major portion of the hydrogen atoms of paraffinic hydrocarbons of five or more carbon atoms may be replaced by subjecting the hydrocarbon to the action of chlorine under active light. The initial chlorination is begun at 25 to 30 deg C with the chlorine diluted with HCl. The later stages may be carried out with undiluted chlorine and the temperature gradually raised to about 129 deg C.
- Inventors:
- Issue Date:
- Research Org.:
- Originating Research Org. not identified
- Sponsoring Org.:
- US Atomic Energy Commission (AEC)
- OSTI Identifier:
- 4431708
- Patent Number(s):
- 2566052
- Application Number:
- US Patent Application 542623
- Assignee:
- U.S. Atomic Energy Commission
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- NSA Number:
- NSA-04-001390
- Resource Type:
- Patent
- Resource Relation:
- Other Information: Orig. Receipt Date: 31-DEC-50
- Country of Publication:
- United States
- Language:
- English
- Subject:
- CHEMISTRY; CHEMICAL REACTIONS; CHLORINATED HYDROCARBONS; CHLORINATION; CHLORINE; HYDROCARBONS; HYDROCHLORIC ACID; LIGHT; ORGANIC CHLORINE COMPOUNDS; PARAFFIN; PHOTOCHEMISTRY; SOLUTIONS; TEMPERATURE
Citation Formats
Beanblossom, W S. Process for Photochemical Chlorination of Hydrocarbons. United States: N. p., 1951.
Web.
Beanblossom, W S. Process for Photochemical Chlorination of Hydrocarbons. United States.
Beanblossom, W S. Tue .
"Process for Photochemical Chlorination of Hydrocarbons". United States. https://www.osti.gov/servlets/purl/4431708.
@article{osti_4431708,
title = {Process for Photochemical Chlorination of Hydrocarbons},
author = {Beanblossom, W S},
abstractNote = {A process for chlorination of a major portion of the hydrogen atoms of paraffinic hydrocarbons of five or more carbon atoms may be replaced by subjecting the hydrocarbon to the action of chlorine under active light. The initial chlorination is begun at 25 to 30 deg C with the chlorine diluted with HCl. The later stages may be carried out with undiluted chlorine and the temperature gradually raised to about 129 deg C.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 28 00:00:00 EDT 1951},
month = {Tue Aug 28 00:00:00 EDT 1951}
}
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