DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methods of preparing single-walled carbon nanotube networks

Abstract

Methods for determining desired doping conditions for a semiconducting single-walled carbon nanotube (s-SWCNT) are provided. One exemplary method includes doping each of a plurality of s-SWCNT networks under a respective set of doping conditions; determining a thermoelectric (TE) power factor as a function of a fractional bleach of an absorption spectrum for the plurality of s-SWCNT networks doped under the respective sets of doping conditions; and using the function to identify one of the TE power factors within a range of the fractional bleach of the absorption spectrum. The identified TE power factor corresponds to the desired doping conditions.

Inventors:
; ;
Issue Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1637802
Patent Number(s):
10598614
Application Number:
15/741,895
Assignee:
Alliance for Sustainable Energy, LLC (Golden, CO)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 07/13/2016
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; 36 MATERIALS SCIENCE

Citation Formats

Avery, Azure Dee, Blackburn, Jeffrey Lee, and Ferguson, Andrew John. Methods of preparing single-walled carbon nanotube networks. United States: N. p., 2020. Web.
Avery, Azure Dee, Blackburn, Jeffrey Lee, & Ferguson, Andrew John. Methods of preparing single-walled carbon nanotube networks. United States.
Avery, Azure Dee, Blackburn, Jeffrey Lee, and Ferguson, Andrew John. Tue . "Methods of preparing single-walled carbon nanotube networks". United States. https://www.osti.gov/servlets/purl/1637802.
@article{osti_1637802,
title = {Methods of preparing single-walled carbon nanotube networks},
author = {Avery, Azure Dee and Blackburn, Jeffrey Lee and Ferguson, Andrew John},
abstractNote = {Methods for determining desired doping conditions for a semiconducting single-walled carbon nanotube (s-SWCNT) are provided. One exemplary method includes doping each of a plurality of s-SWCNT networks under a respective set of doping conditions; determining a thermoelectric (TE) power factor as a function of a fractional bleach of an absorption spectrum for the plurality of s-SWCNT networks doped under the respective sets of doping conditions; and using the function to identify one of the TE power factors within a range of the fractional bleach of the absorption spectrum. The identified TE power factor corresponds to the desired doping conditions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 24 00:00:00 EDT 2020},
month = {Tue Mar 24 00:00:00 EDT 2020}
}

Works referenced in this record:

Electronic transport properties of conducting polymers and carbon nanotubes
journal, December 2000


Layer-by-Layer Polymer Coating of Carbon Nanotubes: Tuning of Electrical Conductivity in Random Networks
journal, March 2010


Thermoelectric Properties of Molecular Nanowires
journal, November 2011


Solid-State 13C NMR Assignment of Carbon Resonances on Metallic and Semiconducting Single-Walled Carbon Nanotubes
journal, July 2010


Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene)
journal, May 2011


Conducting polymers: Efficient thermoelectric materials
journal, February 2011


Networks of Semiconducting SWNTs: Contribution of Midgap Electronic States to the Electrical Transport
journal, July 2015


High performance transistors via aligned polyfluorene-sorted carbon nanotubes
journal, February 2014


Flash Method of Determining Thermal Diffusivity, Heat Capacity, and Thermal Conductivity
journal, September 1961


H-Bonded Supramolecular Polymer for the Selective Dispersion and Subsequent Release of Large-Diameter Semiconducting Single-Walled Carbon Nanotubes
journal, March 2015


Electrochemical determination of the ionization potential and electron affinity of poly(9,9-dioctylfluorene)
journal, October 1998


Sorting carbon nanotubes by electronic structure using density differentiation
journal, October 2006


Light-Weight Flexible Carbon Nanotube Based Organic Composites with Large Thermoelectric Power Factors
journal, September 2011


Thermoelectric Behavior of Segregated-Network Polymer Nanocomposites
journal, December 2008


Thermoelectric Conversion Material and Thermoelectric Conversion Element
patent-application, August 2014


Microscopic Understanding of the Anisotropic Conductivity of PEDOT:PSS Thin Films
journal, May 2007


Electronic conduction in polymers, carbon nanotubes and graphene
journal, January 2011


Tailored semiconducting carbon nanotube networks with enhanced thermoelectric properties
journal, April 2016


Precision printing and optical modeling of ultrathin SWCNT/C 60 heterojunction solar cells
journal, January 2015


Effect of Intertube Junctions on the Thermoelectric Power of Monodispersed Single Walled Carbon Nanotube Networks
journal, November 2014


Treating Poly(3-hexylthiophene) with Dimethylsulfate Improves Its Photoelectrical Properties
journal, October 2008


Ultrafast Spectroscopic Signature of Charge Transfer between Single-Walled Carbon Nanotubes and C 60
journal, July 2014


Thermoelectricity in polymer composites due to fluctuation-induced tunneling
journal, January 2015


Anisotropic hopping conduction in spin-coated PEDOT:PSS thin films
journal, August 2007


Power Factor Enhancement in Solution-Processed Organic n-Type Thermoelectrics Through Molecular Design
journal, March 2014


Thermoelectric Apparatus And Applications Thereof
patent-application, November 2013


Redox Sorting of Carbon Nanotubes
journal, February 2015


Enhancing extraction of photogenerated excitons from semiconducting carbon nanotube films as photocurrent
journal, February 2013


Photoinduced Energy and Charge Transfer in P3HT:SWNT Composites
journal, July 2010


Impact of the Doping Method on Conductivity and Thermopower in Semiconducting Polythiophenes
journal, October 2014


Effect of quantum-well structures on the thermoelectric figure of merit
journal, May 1993


Doped Carbon Nanotubes and Transparent Conducting Films Containing the Same
patent-application, March 2012


Engineered doping of organic semiconductors for enhanced thermoelectric efficiency
journal, May 2013


DNA sequence motifs for structure-specific recognition and separation of carbon nanotubes
journal, July 2009


Modeling of the Thermoelectric Power Factor in Quasi-One-Dimensional Organic Crystals
conference, August 2006


Graphene-Polymer Layered Composite And Process For Preparing The Same
patent-application, March 2012


Observation of a Type II Heterojunction in a Highly Ordered Polymer−Carbon Nanotube Nanohybrid Structure
journal, October 2009


Free Carrier Generation and Recombination in Polymer-Wrapped Semiconducting Carbon Nanotube Films and Heterojunctions
journal, October 2013


Polyfluorene-Sorted, Carbon Nanotube Array Field-Effect Transistors with Increased Current Density and High On/Off Ratio
journal, November 2014


High-Yield Dispersions of Large-Diameter Semiconducting Single-Walled Carbon Nanotubes with Tunable Narrow Chirality Distributions
journal, February 2013


Defect Engineering in π-Conjugated Polymers
journal, October 2009


The Thermoelectric Performance of Poly(3,4-ethylenedi oxythiophene)/Poly(4-styrenesulfonate) Thin Films
journal, April 2009


Synthesis and Characterization of Boron-Doped Single-Wall Carbon Nanotubes Produced by the Laser Vaporization Technique
journal, May 2006


Stable Charge-Transfer Doping of Transparent Single-Walled Carbon Nanotube Films
journal, September 2010


Giant Seebeck coefficient in semiconducting single-wall carbon nanotube film
journal, January 2014


Impacts of doping on thermal and thermoelectric properties of nanomaterials
journal, January 2010


Thermal conductivity of single-walled carbon nanotubes
journal, January 1999


Conductivity, work function, and environmental stability of PEDOT:PSS thin films treated with sorbitol
journal, October 2008


n-Type Transparent Conducting Films of Small Molecule and Polymer Amine Doped Single-Walled Carbon Nanotubes
journal, March 2011


Electrical properties of single-wall carbon nanotube-polymer composite films
journal, April 2006


Semi-metallic polymers
journal, December 2013


Turning Carbon Nanotubes from Exceptional Heat Conductors into Insulators
journal, March 2009


Water-Processable Polymer−Nanocrystal Hybrids for Thermoelectrics
journal, November 2010


Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers
journal, September 2007


Isolation of >1 nm Diameter Single-Wall Carbon Nanotube Species Using Aqueous Two-Phase Extraction
journal, April 2015


Thermal Conductance of an Individual Single-Wall Carbon Nanotube above Room Temperature
journal, January 2006


Thermal conductivity of micromachined low-stress silicon-nitride beams from 77 to 325 K
journal, February 2009


Excitons in carbon nanotubes: Diameter and chirality trends
journal, November 2007


Thermal Conductance and Thermopower of an Individual Single-Wall Carbon Nanotube
journal, September 2005


Multilayered Carbon Nanotube/Polymer Composite Based Thermoelectric Fabrics
journal, February 2012


Complex thermoelectric materials
journal, February 2008


Thermoelectric figure of merit of a one-dimensional conductor
journal, June 1993


Enhanced thermoelectric performance of rough silicon nanowires
journal, January 2008


A Morphological Model for the Solvent-Enhanced Conductivity of PEDOT:PSS Thin Films
journal, March 2008


Completely Organic Multilayer Thin Film with Thermoelectric Power Factor Rivaling Inorganic Tellurides
journal, April 2015