Protective coatings for lithium anodes

Elam, Jeffrey W.; Chen, Lin

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Title: Protective coatings for lithium anodes

Abstract

A hybrid protective coating includes an inorganic component and an organic component such that the inorganic component includes at least one of a metal oxide, a metal fluoride, or combination thereof, and the organic component includes at least one metalcone.

Inventors:: Elam, Jeffrey W.; Chen, Lin

Issue Date:: Tue Feb 04 00:00:00 EST 2020

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1632532

Patent Number(s):: 10553874

Application Number:: 15/669,771

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL

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B - PERFORMING OPERATIONS B05 - SPRAYING OR ATOMISING IN GENERAL B05D - PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
B05D7/50 - {Multilayers}
B05D7/56 - {Three layers or more}

C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
C23C16/22 - characterised by the deposition of inorganic material, other than metallic material
C23C16/30 - Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
C23C16/40 - Oxides
C23C16/403 - {of aluminium, magnesium or beryllium}
C23C16/45527 - {characterized by the ALD cycle, e.g. different flows or temperatures during half-reactions, unusual pulsing sequence, use of precursor mixtures or auxiliary reactants or activations}
C23C16/45553 - {characterized by the use of precursors specially adapted for ALD}

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/4235 - {Safety or regulating additives or arrangements in electrodes, separators or electrolyte
H01M2004/027 - {Negative electrodes}
H01M4/0423 - {Physical vapour deposition}
H01M4/134 - Electrodes based on metals, Si or alloys
H01M4/1395 - of electrodes based on metals, Si or alloys
H01M4/366 - {as layered products}
H01M4/382 - {Lithium
H01M4/628 - {Inhibitors, e.g. gassing inhibitors, corrosion inhibitors}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 08/04/2017

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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                    Elam, Jeffrey W., and Chen, Lin. Protective coatings for lithium anodes.  United States: N. p., 2020. 
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                    Elam, Jeffrey W., & Chen, Lin. Protective coatings for lithium anodes.  United States.

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                    Elam, Jeffrey W., and Chen, Lin. Tue .  
        "Protective coatings for lithium anodes".  United States.  https://www.osti.gov/servlets/purl/1632532.

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@article{osti_1632532,

  title        = {Protective coatings for lithium anodes},

  author       = {Elam, Jeffrey W. and Chen, Lin},

  abstractNote = {A hybrid protective coating includes an inorganic component and an organic component such that the inorganic component includes at least one of a metal oxide, a metal fluoride, or combination thereof, and the organic component includes at least one metalcone.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Feb 04 00:00:00 EST 2020},

  month        = {Tue Feb 04 00:00:00 EST 2020}

}

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Works referenced in this record:

Chalcogenide battery
patent, February 1977

Whittingham, M. Stanley
US Patent Document 4,009,052
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4009052

PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries
journal, January 2005

Shin, Joon-Ho; Henderson, Wesley A.; Passerini, Stefano
Journal of The Electrochemical Society, Vol. 152, Issue 5
https://doi.org/10.1149/1.1890701

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
Nature Nanotechnology, Vol. 9, Issue 8
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Electrical Energy Storage and Intercalation Chemistry
journal, June 1976

Whittingham, M. S.
Science, Vol. 192, Issue 4244
https://doi.org/10.1126/science.192.4244.1126

Lithium metal anode for lithium battery
patent-application, April 2004

Cho, Chung-kun; Lee, Sang-mock; Lee, Jong-ki
US Patent Application 10/389752; 20040072066
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Multifunctional Hybrid Coatings for Electrodes Made by Atomic Layer Deposition Techniques
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Xiao, Xingcheng; Verbrugge, Mark W.; Wang, John S.
US Patent Application 14/138267; 20150180023
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The Study of Surface Phenomena Related to Electrochemical Lithium Intercalation into Li[sub x]MO[sub y] Host Materials (M = Ni, Mn)
journal, January 2000

Aurbach, Doron; Gamolsky, Kira; Markovsky, Boris
Journal of The Electrochemical Society, Vol. 147, Issue 4
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Anode Protector of Lithium-Ion Battery and Method for Fabricating the Same
patent-application, July 2013

Wang, Fu-Ming; Wang, Hsin-Yi; Cheng, Chin-Shu
US Patent Application 13/410,299; 2013/0177808 Al
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Protection Layers for Metal Anodes
patent-application, September 2017

Kozen, Alexander C.; Schroeder, Marshall A.; Rubloff, Gary W.
US Patent Application 15/517,126; 2017/0263935 Al
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Nano-Engineered Coatings for Anode Active Materials, Cathode Active Materials, and Solid-State Electrolytes and Methods of Making Batteries Containing Nano-Engineered Coatings
patent-application, December 2016

Albano, Fabio; Dahlberg, Kevin; Anderson, Erik
US Patent Application 15/170374; 20160351973
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Gas Permeation Barrier Material
patent-application, December 2013

Carcia, Peter Francis; McLean, Robert Scott
US Patent Application 13/523,414; 2013/0337259 Al
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A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

Aurbach, D.
Solid State Ionics, Vol. 148, Issue 3-4
https://doi.org/10.1016/S0167-2738(02)00080-2

Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015

Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.
ACS Nano, Vol. 9, Issue 6
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Comparison of Solvent-Cast and Hot-Pressed P(EO)[sub 20]LiN(SO[sub 2]CF[sub 2]CF[sub 3])[sub 2] Polymer Electrolytes Containing Nanosized SiO[sub 2]
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Shin, Joon-Ho; Alessandrini, Fabrizio; Passerini, Stefano
Journal of The Electrochemical Society, Vol. 152, Issue 2
https://doi.org/10.1149/1.1846713

Materials for Solid State Electrolytes and Protective Electrode Coatings for Lithium Batteries
patent-application, December 2015

Elam, Jeffrey W.; Meng, Xiangbo
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Metal oxide coated positive electrode materials for lithium-based batteries
patent, September 2013

Karthikeyan, Deepak Kumaar Kandasamy; Venkatachalam, Subramanian; Lopez, Herman A.
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Similar Records

Title: Protective coatings for lithium anodes

Abstract

Citation Formats

Chalcogenide battery patent, February 1977

PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries journal, January 2005

Interconnected hollow carbon nanospheres for stable lithium metal anodes journal, July 2014

Electrical Energy Storage and Intercalation Chemistry journal, June 1976

Lithium metal anode for lithium battery patent-application, April 2004

Multifunctional Hybrid Coatings for Electrodes Made by Atomic Layer Deposition Techniques patent-application, June 2015

The Study of Surface Phenomena Related to Electrochemical Lithium Intercalation into Li[sub x]MO[sub y] Host Materials (M = Ni, Mn) journal, January 2000

Anode Protector of Lithium-Ion Battery and Method for Fabricating the Same patent-application, July 2013

Protection Layers for Metal Anodes patent-application, September 2017

Nano-Engineered Coatings for Anode Active Materials, Cathode Active Materials, and Solid-State Electrolytes and Methods of Making Batteries Containing Nano-Engineered Coatings patent-application, December 2016

Gas Permeation Barrier Material patent-application, December 2013

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions journal, June 2002

Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition journal, May 2015

Comparison of Solvent-Cast and Hot-Pressed P(EO)[sub 20]LiN(SO[sub 2]CF[sub 2]CF[sub 3])[sub 2] Polymer Electrolytes Containing Nanosized SiO[sub 2] journal, January 2005

Materials for Solid State Electrolytes and Protective Electrode Coatings for Lithium Batteries patent-application, December 2015

Metal oxide coated positive electrode materials for lithium-based batteries patent, September 2013

Chalcogenide battery
patent, February 1977

PEO-Based Polymer Electrolytes with Ionic Liquids and Their Use in Lithium Metal-Polymer Electrolyte Batteries
journal, January 2005

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Electrical Energy Storage and Intercalation Chemistry
journal, June 1976

Lithium metal anode for lithium battery
patent-application, April 2004

Multifunctional Hybrid Coatings for Electrodes Made by Atomic Layer Deposition Techniques
patent-application, June 2015

The Study of Surface Phenomena Related to Electrochemical Lithium Intercalation into Li[sub x]MO[sub y] Host Materials (M = Ni, Mn)
journal, January 2000

Anode Protector of Lithium-Ion Battery and Method for Fabricating the Same
patent-application, July 2013

Protection Layers for Metal Anodes
patent-application, September 2017

Nano-Engineered Coatings for Anode Active Materials, Cathode Active Materials, and Solid-State Electrolytes and Methods of Making Batteries Containing Nano-Engineered Coatings
patent-application, December 2016

Gas Permeation Barrier Material
patent-application, December 2013

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition
journal, May 2015

Comparison of Solvent-Cast and Hot-Pressed P(EO)[sub 20]LiN(SO[sub 2]CF[sub 2]CF[sub 3])[sub 2] Polymer Electrolytes Containing Nanosized SiO[sub 2]
journal, January 2005

Materials for Solid State Electrolytes and Protective Electrode Coatings for Lithium Batteries
patent-application, December 2015

Metal oxide coated positive electrode materials for lithium-based batteries
patent, September 2013