DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Methods for producing hydrogen using nanoparticle-catalyst mixtures

Abstract

Provided are compositions for and methods of producing hydrogen. For example, the compositions comprise nanocrystals, a catalyst, a source of electrons, and an aqueous medium. The nanocrystals, catalyst, aqueous medium, and, optionally, the source of electrons are present as a mixture. The methods produce hydrogen by exposing the compositions to electromagnetic radiation (e.g., solar flux).

Inventors:
; ; ; ;
Issue Date:
Research Org.:
Univ. of Rochester, NY (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1600259
Patent Number(s):
10471409
Application Number:
14/439,304
Assignee:
University of Rochester (Rochester, NY)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
DOE Contract Number:  
FG02-09ER16121; SC0002106
Resource Type:
Patent
Resource Relation:
Patent File Date: 11/05/2013
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, and Han, Zhiji. Methods for producing hydrogen using nanoparticle-catalyst mixtures. United States: N. p., 2019. Web.
Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, & Han, Zhiji. Methods for producing hydrogen using nanoparticle-catalyst mixtures. United States.
Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, and Han, Zhiji. Tue . "Methods for producing hydrogen using nanoparticle-catalyst mixtures". United States. https://www.osti.gov/servlets/purl/1600259.
@article{osti_1600259,
title = {Methods for producing hydrogen using nanoparticle-catalyst mixtures},
author = {Krauss, Todd D. and Eisenberg, Richard and Holland, Patrick and Qiu, Fen and Han, Zhiji},
abstractNote = {Provided are compositions for and methods of producing hydrogen. For example, the compositions comprise nanocrystals, a catalyst, a source of electrons, and an aqueous medium. The nanocrystals, catalyst, aqueous medium, and, optionally, the source of electrons are present as a mixture. The methods produce hydrogen by exposing the compositions to electromagnetic radiation (e.g., solar flux).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 12 00:00:00 EST 2019},
month = {Tue Nov 12 00:00:00 EST 2019}
}

Works referenced in this record:

Quantum confinement controlled photocatalytic water splitting by suspended CdSe nanocrystals
journal, January 2012


Mesoporous carbon nitride with in situ sulfur doping for enhanced photocatalytic hydrogen evolution from water under visible light
journal, January 2012


Highly active ZnxCd1−xS photocatalysts containing earth abundant elements only for H2 production from water under visible light
journal, January 2011


Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006


Synthesis and characterization of metal derivatives of dihydrolipoic acid and dihydrolipoamide
journal, February 1992


Nickel–Thiolate Complex Catalyst Assembled in One Step in Water for Solar H 2 Production
journal, December 2011


A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012


Ellipsoidal hollow nanostructures assembled from anatase TiO2 nanosheets as a magnetically separable photocatalyst
journal, January 2011


Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures
journal, March 2010


Photocatalysis and solar hydrogen production
journal, January 2007


Reductive Side of Water Splitting in Artificial Photosynthesis: New Homogeneous Photosystems of Great Activity and Mechanistic Insight
journal, November 2010


Characterization of Photochemical Processes for H 2 Production by CdS Nanorod–[FeFe] Hydrogenase Complexes
journal, March 2012


Doped Solid Solution: (Zn0.95Cu0.05)1−xCdxS Nanocrystals with High Activity for H2 Evolution from Aqueous Solutions under Visible Light
journal, October 2008


Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water
journal, June 2011


Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
journal, November 2012


Efficient hydrogen production by photocatalytic water splitting using surface plasmons in hybrid nanoparticles
patent-application, June 2012


Molecular systems for light driven hydrogen production
journal, January 2012


A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution
journal, March 2011


Homogeneous catalysis of the photoreduction of water by visible light. Mediation by a tris(2,2'-bipyridine)ruthenium(II)-cobalt(II) macrocycle system
journal, February 1979


Controlled Assembly of Hydrogenase-CdTe Nanocrystal Hybrids for Solar Hydrogen Production
journal, July 2010


Orchestrated Photocatalytic Water Reduction Using Surface-Adsorbing Iridium Photosensitizers
journal, August 2011


Synthesis and Photocatalytic Properties of a Family of CdS-PdX Hybrid Nanoparticles
journal, December 2010


Ni(OH)2 modified CdS nanorods for highly efficient visible-light-driven photocatalytic H2 generation
journal, January 2011


Cobaloxime-Based Photocatalytic Devices for Hydrogen Production
journal, January 2008


Hydrogen Production by Molecular Photocatalysis
journal, October 2007


Photocatalytic H 2 Production from Water with Rhenium and Cobalt Complexes
journal, April 2011


Chemical Approaches to Artificial Photosynthesis. 2
journal, October 2005


A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation
journal, February 2012


Water Splitting by Visible Light: A Nanophotocathode for Hydrogen Production
journal, February 2010


Hydrogen generating method using gamma rays
patent, July 1997


A molecular molybdenum-oxo catalyst for generating hydrogen from water
journal, April 2010


Discovering the Balance of Steric and Electronic Factors Needed To Provide a New Structural Motif for Photocatalytic Hydrogen Production from Water
journal, October 2011


Size-Dependent Valence and Conduction Band-Edge Energies of Semiconductor Nanocrystals
journal, June 2011


Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions
journal, June 2012


A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012


Nanostructural Substance
patent-application, June 2006


High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site
journal, January 2010


Near Unity Quantum Yield of Light-Driven Redox Mediator Reduction and Efficient H 2 Generation Using Colloidal Nanorod Heterostructures
journal, July 2012