Methods for producing hydrogen using nanoparticle-catalyst mixtures
Abstract
Provided are compositions for and methods of producing hydrogen. For example, the compositions comprise nanocrystals, a catalyst, a source of electrons, and an aqueous medium. The nanocrystals, catalyst, aqueous medium, and, optionally, the source of electrons are present as a mixture. The methods produce hydrogen by exposing the compositions to electromagnetic radiation (e.g., solar flux).
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Rochester, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1600259
- Patent Number(s):
- 10471409
- Application Number:
- 14/439,304
- Assignee:
- University of Rochester (Rochester, NY)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- FG02-09ER16121; SC0002106
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 11/05/2013
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 08 HYDROGEN; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, and Han, Zhiji. Methods for producing hydrogen using nanoparticle-catalyst mixtures. United States: N. p., 2019.
Web.
Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, & Han, Zhiji. Methods for producing hydrogen using nanoparticle-catalyst mixtures. United States.
Krauss, Todd D., Eisenberg, Richard, Holland, Patrick, Qiu, Fen, and Han, Zhiji. Tue .
"Methods for producing hydrogen using nanoparticle-catalyst mixtures". United States. https://www.osti.gov/servlets/purl/1600259.
@article{osti_1600259,
title = {Methods for producing hydrogen using nanoparticle-catalyst mixtures},
author = {Krauss, Todd D. and Eisenberg, Richard and Holland, Patrick and Qiu, Fen and Han, Zhiji},
abstractNote = {Provided are compositions for and methods of producing hydrogen. For example, the compositions comprise nanocrystals, a catalyst, a source of electrons, and an aqueous medium. The nanocrystals, catalyst, aqueous medium, and, optionally, the source of electrons are present as a mixture. The methods produce hydrogen by exposing the compositions to electromagnetic radiation (e.g., solar flux).},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 12 00:00:00 EST 2019},
month = {Tue Nov 12 00:00:00 EST 2019}
}
Works referenced in this record:
Ni2+-doped ZnxCd1−xS photocatalysts from single-source precursors for efficient solar hydrogen production under visible light irradiation
journal, January 2012
- Wang, Yabo; Wu, Jianchun; Zheng, Jianwei
- Catal. Sci. Technol., Vol. 2, Issue 3
Quantum confinement controlled photocatalytic water splitting by suspended CdSe nanocrystals
journal, January 2012
- Holmes, Michael A.; Townsend, Troy K.; Osterloh, Frank E.
- Chem. Commun., Vol. 48, Issue 3
Mesoporous carbon nitride with in situ sulfur doping for enhanced photocatalytic hydrogen evolution from water under visible light
journal, January 2012
- Hong, Jindui; Xia, Xiaoyang; Wang, Yongsheng
- Journal of Materials Chemistry, Vol. 22, Issue 30
Highly active ZnxCd1−xS photocatalysts containing earth abundant elements only for H2 production from water under visible light
journal, January 2011
- Wang, Yabo; Wu, Jianchun; Zheng, Jianwei
- Catalysis Science & Technology, Vol. 1, Issue 6
Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006
- Lewis, N. S.; Nocera, D. G.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
Formation of 1D Hierarchical Structures Composed of Ni 3 S 2 Nanosheets on CNTs Backbone for Supercapacitors and Photocatalytic H 2 Production
journal, October 2012
- Zhu, Ting; Wu, Hao Bin; Wang, Yabo
- Advanced Energy Materials, Vol. 2, Issue 12
Synthesis and characterization of metal derivatives of dihydrolipoic acid and dihydrolipoamide
journal, February 1992
- Bonomi, F.; Pagani, S.; Cariati, F.
- Inorganica Chimica Acta, Vol. 192, Issue 2
Method for Production of Doped Titanium Oxide, Doped Titanium Oxide, and Visible Light-Responsive Photocatalyst Comprising the Doped Titanium Oxide
patent-application, March 2010
- Jin, Ren-Hua; Zhu, Pei-Xin; Fukazawa, Norimasa
- US Patent Application 12/518957; 20100062928
Nickel–Thiolate Complex Catalyst Assembled in One Step in Water for Solar H 2 Production
journal, December 2011
- Zhang, Wei; Hong, Jindui; Zheng, Jianwei
- Journal of the American Chemical Society, Vol. 133, Issue 51
A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012
- Han, Zhiji; McNamara, William R.; Eum, Min-Sik
- Angewandte Chemie International Edition, Vol. 51, Issue 7
Ellipsoidal hollow nanostructures assembled from anatase TiO2 nanosheets as a magnetically separable photocatalyst
journal, January 2011
- Chen, Jun Song; Chen, Chunping; Liu, Jian
- Chemical Communications, Vol. 47, Issue 9
Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures
journal, March 2010
- Amirav, Lilac; Alivisatos, A. Paul
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 7
Photocatalysis and solar hydrogen production
journal, January 2007
- Kudo, Akihiko
- Pure and Applied Chemistry, Vol. 79, Issue 11
Reductive Side of Water Splitting in Artificial Photosynthesis: New Homogeneous Photosystems of Great Activity and Mechanistic Insight
journal, November 2010
- McCormick, Theresa M.; Calitree, Brandon D.; Orchard, Alexandra
- Journal of the American Chemical Society, Vol. 132, Issue 44
CdS photocatalyst for hydrogen production, preparation therefor and method for producing hydrogen by use of the same
patent, October 2001
- Park, Dae Chul; Baeg, Jin-Ook
- US Patent Document 6,300,274
Liquid composition for promoting plant growth containing titanium dioxide nanoparticles
patent, May 2012
- Choi, Kwang Soo
- US Patent Document 8,188,005
Characterization of Photochemical Processes for H 2 Production by CdS Nanorod–[FeFe] Hydrogenase Complexes
journal, March 2012
- Brown, Katherine A.; Wilker, Molly B.; Boehm, Marko
- Journal of the American Chemical Society, Vol. 134, Issue 12
Doped Solid Solution: (Zn0.95Cu0.05)1−xCdxS Nanocrystals with High Activity for H2 Evolution from Aqueous Solutions under Visible Light
journal, October 2008
- Zhang, Wei; Zhong, Ziyi; Wang, Yongsheng
- The Journal of Physical Chemistry C, Vol. 112, Issue 45
Molecular Cobalt Pentapyridine Catalysts for Generating Hydrogen from Water
journal, June 2011
- Sun, Yujie; Bigi, Julian P.; Piro, Nicholas A.
- Journal of the American Chemical Society, Vol. 133, Issue 24
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst
journal, November 2012
- Han, Z.; Qiu, F.; Eisenberg, R.
- Science, Vol. 338, Issue 6112
Efficient photochemical production of hydrogen in aqueous solution by simply incorporating a water-insoluble hydrogenase mimic into a hydrogel
journal, January 2014
- Yu, Tianjun; Zeng, Yi; Chen, Jinping
- J. Mater. Chem. A, Vol. 2, Issue 48
Efficient hydrogen production by photocatalytic water splitting using surface plasmons in hybrid nanoparticles
patent-application, June 2012
- Smolyakov, Gennady A.; Osinski, Marek A.
- US Patent Application 13/374364; 20120145532
Molecular systems for light driven hydrogen production
journal, January 2012
- Eckenhoff, William T.; Eisenberg, Richard
- Dalton Transactions, Vol. 41, Issue 42
A Highly Efficient Photocatalytic System for Hydrogen Production by a Robust Hydrogenase Mimic in an Aqueous Solution
journal, March 2011
- Wang, Feng; Wang, Wen-Guang; Wang, Xiao-Jun
- Angewandte Chemie International Edition, Vol. 50, Issue 14
Homogeneous catalysis of the photoreduction of water by visible light. Mediation by a tris(2,2'-bipyridine)ruthenium(II)-cobalt(II) macrocycle system
journal, February 1979
- Brown, Gilbert M.; Brunschwig, Bruce S.; Creutz, Carol
- Journal of the American Chemical Society, Vol. 101, Issue 5
Controlled Assembly of Hydrogenase-CdTe Nanocrystal Hybrids for Solar Hydrogen Production
journal, July 2010
- Brown, Katherine A.; Dayal, Smita; Ai, Xin
- Journal of the American Chemical Society, Vol. 132, Issue 28
Orchestrated Photocatalytic Water Reduction Using Surface-Adsorbing Iridium Photosensitizers
journal, August 2011
- DiSalle, Brian F.; Bernhard, Stefan
- Journal of the American Chemical Society, Vol. 133, Issue 31
Synthesis and Photocatalytic Properties of a Family of CdS-PdX Hybrid Nanoparticles
journal, December 2010
- Shemesh, Yossi; Macdonald, Janet E.; Menagen, Gabi
- Angewandte Chemie International Edition, Vol. 50, Issue 5, p. 1185-1189
Ni(OH)2 modified CdS nanorods for highly efficient visible-light-driven photocatalytic H2 generation
journal, January 2011
- Ran, Jingrun; Yu, Jiaguo; Jaroniec, Mietek
- Green Chemistry, Vol. 13, Issue 10
Cobaloxime-Based Photocatalytic Devices for Hydrogen Production
journal, January 2008
- Fihri, Aziz; Artero, Vincent; Razavet, Mathieu
- Angewandte Chemie International Edition, Vol. 47, Issue 3
Synthesis of Zn–Cu–Cd sulfide nanospheres with controlled copper locations and their effects on photocatalytic activities for H2 production
journal, June 2010
- Wang, Yabo; Wang, Yongsheng; Xu, Rong
- International Journal of Hydrogen Energy, Vol. 35, Issue 11
Photocatalytic H2 production on hybrid catalyst system composed of inorganic semiconductor and cobaloximes catalysts
journal, July 2011
- Wen, Fuyu; Yang, Jinhui; Zong, Xu
- Journal of Catalysis, Vol. 281, Issue 2
Hydrogen Production by Molecular Photocatalysis
journal, October 2007
- Esswein, Arthur J.; Nocera, Daniel G.
- Chemical Reviews, Vol. 107, Issue 10
Method for improving product yields in an anionic metalloporphyrin-based artificial photosynthesis system
patent, February 1986
- Shelnutt, John A.
- US Patent Document 4,568,435
Self-assembled dye–layered double hydroxide–Pt nanoparticles: a novel H2 evolution system with remarkably enhanced stability
journal, January 2011
- Hong, Jindui; Wang, Yabo; Pan, Jisheng
- Nanoscale, Vol. 3, Issue 11
Photocatalytic H 2 Production from Water with Rhenium and Cobalt Complexes
journal, April 2011
- Probst, Benjamin; Guttentag, Miguel; Rodenberg, Alexander
- Inorganic Chemistry, Vol. 50, Issue 8
Chemical Approaches to Artificial Photosynthesis. 2
journal, October 2005
- Alstrum-Acevedo, James H.; Brennaman, M. Kyle; Meyer, Thomas J.
- Inorganic Chemistry, Vol. 44, Issue 20
A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation
journal, February 2012
- Karunadasa, H. I.; Montalvo, E.; Sun, Y.
- Science, Vol. 335, Issue 6069
Nickel-complexes with a mixed-donor ligand for photocatalytic hydrogen evolution from aqueous solutions under visible light
journal, January 2012
- Han, Jianyu; Zhang, Wei; Zhou, Tianhua
- RSC Advances, Vol. 2, Issue 22
Water Splitting by Visible Light: A Nanophotocathode for Hydrogen Production
journal, February 2010
- Nann, Thomas; Ibrahim, Saad K.; Woi, Pei-Meng
- Angewandte Chemie International Edition, Vol. 49, Issue 9
Hydrogen generating method using gamma rays
patent, July 1997
- Wada, Yukio; Myochin, Munetaka; Kawaguchi, Kouichi
- US Patent Document 5,650,051
A molecular molybdenum-oxo catalyst for generating hydrogen from water
journal, April 2010
- Karunadasa, Hemamala I.; Chang, Christopher J.; Long, Jeffrey R.
- Nature, Vol. 464, Issue 7293
Discovering the Balance of Steric and Electronic Factors Needed To Provide a New Structural Motif for Photocatalytic Hydrogen Production from Water
journal, October 2011
- White, Travis A.; Whitaker, Brittany N.; Brewer, Karen J.
- Journal of the American Chemical Society, Vol. 133, Issue 39
Size-Dependent Valence and Conduction Band-Edge Energies of Semiconductor Nanocrystals
journal, June 2011
- Jasieniak, Jacek; Califano, Marco; Watkins, Scott E.
- ACS Nano, Vol. 5, Issue 7
Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions
journal, June 2012
- McNamara, W. R.; Han, Z.; Yin, C. -J.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012
- Han, Zhiji; McNamara, William R.; Eum, Min-Sik
- Angewandte Chemie, Vol. 124, Issue 7
Nanostructural Substance
patent-application, June 2006
- Honda, Tomohiro; Urai, Tomoaki; Kurata, Katsuaki
- US Patent Application 11/258383; 20060116282
High-Turnover Photochemical Hydrogen Production Catalyzed by a Model Complex of the [FeFe]-Hydrogenase Active Site
journal, January 2010
- Streich, Daniel; Astuti, Yeni; Orlandi, Michele
- Chemistry - A European Journal, Vol. 16, Issue 1
Near Unity Quantum Yield of Light-Driven Redox Mediator Reduction and Efficient H 2 Generation Using Colloidal Nanorod Heterostructures
journal, July 2012
- Zhu, Haiming; Song, Nianhui; Lv, Hongjin
- Journal of the American Chemical Society, Vol. 134, Issue 28