Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Chen, Zonghai; Amine, Khalil

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Title: Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Abstract

Lithium-air cells using poly(ethyleneoxide) (PEO) siloxane-based or poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO silioxanes and phosphates generally have the formulas Ia, Ib, Ic, Id, IIa, IIb, IIc, where: ##STR00001##

Inventors:: Chen, Zonghai; Amine, Khalil

Issue Date:: Tue Jul 02 00:00:00 EDT 2013

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1531853

Patent Number(s):: 8475688

Application Number:: 12/146,020

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

Show more

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/0525 - Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes
H01M10/056 - characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes {
H01M10/0565 - Polymeric materials, e.g. gel-type or solid-type
H01M12/06 - with one metallic and one gaseous electrode
H01M12/08 - composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
H01M2300/0025 - Organic electrolyte
H01M2300/0085 - Immobilising or gelification of electrolyte
H01M4/382 - {Lithium
H01M4/90 - Selection of catalytic material

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage
Y02E60/50 - Fuel cells

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02T - CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
Y02T10/70 - Energy storage for electromobility

Show less

DOE Contract Number:: AC02-06CH11357

Resource Type:: Patent

Resource Relation:: Patent File Date: 2008-06-25

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE

Citation Formats


                    Chen, Zonghai, and Amine, Khalil. Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes.  United States: N. p., 2013. 
        Web.

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                    Chen, Zonghai, & Amine, Khalil. Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes.  United States.

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                    Chen, Zonghai, and Amine, Khalil. Tue .  
        "Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes".  United States.  https://www.osti.gov/servlets/purl/1531853.

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@article{osti_1531853,

  title        = {Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes},

  author       = {Chen, Zonghai and Amine, Khalil},

  abstractNote = {Lithium-air cells using poly(ethyleneoxide) (PEO) siloxane-based or poly(ethyleneoxide) phosphate-based electrolytes may be prepared and exhibit improved charge carrying capacity. Such PEO silioxanes and phosphates generally have the formulas Ia, Ib, Ic, Id, IIa, IIb, IIc, where: ##STR00001##},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Jul 02 00:00:00 EDT 2013},

  month        = {Tue Jul 02 00:00:00 EDT 2013}

}

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Similar Records

Title: Lithium batteries using poly(ethylene oxide)-based non-aqueous electrolytes

Abstract

Citation Formats

Erratum: Li–O2 and Li–S batteries with high energy storage journal, December 2011

Mesoporous network electrode for electrochemical cell patent-application, July 2004

Nonaqueous secondary battery patent, May 2001

Electrolyte for use in electrochemical devices patent, September 2009

Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes journal, December 2011

Novel silane compounds as electrolyte solvents for Li-ion batteries journal, March 2006

Layer for stabilization of lithium anode patent, January 1996

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt patent, January 2003

LI/AIR NON-AQUEOUS BATTERIES patent-application, May 2007

Electrochemical device having electrolyte including disiloxane patent-application, August 2005

Rechargeable lithium electrochemical cell patent-application, February 2004

Non-aqueous electrolyte battery patent, September 2001

Solid polymer electrolyte and method of preparation patent-application, January 2005

Oxygen Reactions in a Non-Aqueous Li+ Electrolyte journal, May 2011

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn 2 O 4 Rechargable Battery journal, December 2002

Additive for enhancing the performance of electrochemical cells patent, February 2007

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes patent, April 2000

Electrolyte for a rechargeable cell patent, May 2002

Methods for fabricating lithium rechargeable batteries patent-application, December 2005

Reaction mechanisms for the limited reversibility of Li–O2 chemistry in organic carbonate electrolytes journal, November 2011

Rechargeable lithium/water, lithium/air batteries patent-application, September 2007

Lithium-based active materials and preparation thereof patent-application, April 2002

Alkylspiroborate salts for use in electrochemical cells patent-application, October 2001

Non-Aqueous Electrolytes patent-application, December 2008

Electrochemical device having an electrolyte that includes a tetrasiloxane patent-application, February 2006

Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents patent, December 1998

Polymer electrolyte for electrochemical cell patent-application, October 2004

Poly(Ethyleneoxide) Siloxane Gel Electrolytes patent-application, June 2008

Electrolytic solution for lithium secondary battery and lithium secondary battery using the same patent, March 1998

Reactions in the Rechargeable Lithium–O 2 Battery with Alkyl Carbonate Electrolytes journal, May 2011

Ion conducting fluoropolymer carbonates for alkali metal ion batteries patent, September 2017

Ion conducting polymers and polymer blends for alkali metal ion batteries patent, August 2017

Functionalized fluoropolymers and electrolyte compositions patent, September 2018

Lithium oxygen battery and electrolyte composition patent, May 2017

Functionalized fluoropolymers and electrolyte compositions patent, March 2019

Functionalized ionic liquid electrolytes for lithium ion batteries patent, June 2018

Erratum: Li–O2 and Li–S batteries with high energy storage
journal, December 2011

Mesoporous network electrode for electrochemical cell
patent-application, July 2004

Nonaqueous secondary battery
patent, May 2001

Electrolyte for use in electrochemical devices
patent, September 2009

Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes
journal, December 2011

Novel silane compounds as electrolyte solvents for Li-ion batteries
journal, March 2006

Layer for stabilization of lithium anode
patent, January 1996

Lithium bisoxalatoborate, the production thereof and its use as a conducting salt
patent, January 2003

LI/AIR NON-AQUEOUS BATTERIES
patent-application, May 2007

Electrochemical device having electrolyte including disiloxane
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Rechargeable lithium electrochemical cell
patent-application, February 2004

Non-aqueous electrolyte battery
patent, September 2001

Solid polymer electrolyte and method of preparation
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Oxygen Reactions in a Non-Aqueous Li⁺ Electrolyte
journal, May 2011

2-Vinylpyridine as Film-forming Additve to Suppress the Degradation of Carbon Anode by Dissolved Manganese for C/LiMn ₂ O ₄ Rechargable Battery
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Additive for enhancing the performance of electrochemical cells
patent, February 2007

Electrochemical storage cell containing a substituted anisole or di-anisole redox shuttle additive for overcharge protection and suitable for use in liquid organic and solid polymer electrolytes
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Electrolyte for a rechargeable cell
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Methods for fabricating lithium rechargeable batteries
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Reaction mechanisms for the limited reversibility of Li–O₂ chemistry in organic carbonate electrolytes
journal, November 2011

Rechargeable lithium/water, lithium/air batteries
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Lithium-based active materials and preparation thereof
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Alkylspiroborate salts for use in electrochemical cells
patent-application, October 2001

Non-Aqueous Electrolytes
patent-application, December 2008

Electrochemical device having an electrolyte that includes a tetrasiloxane
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Wide electrochemical window solvents for use in electrochemical devices and electrolyte solutions incorporating such solvents
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Polymer electrolyte for electrochemical cell
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Poly(Ethyleneoxide) Siloxane Gel Electrolytes
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Electrolytic solution for lithium secondary battery and lithium secondary battery using the same
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Reactions in the Rechargeable Lithium–O ₂ Battery with Alkyl Carbonate Electrolytes
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Ion conducting fluoropolymer carbonates for alkali metal ion batteries
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Ion conducting polymers and polymer blends for alkali metal ion batteries
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Functionalized fluoropolymers and electrolyte compositions
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