Molybdenum recovery from aqueous nitric acid solution by solvent extraction
Abstract
The invention provides a method for extracting transition metals, the method comprising supplying a feedstream containing transition metal, mixing the feedstream with nitric acid for a time and at a concentration sufficient to form an aqueous phase containing the transition metal, combining the aqueous phase with organic extractant phase for a time and at a concentration sufficient to cause the transition metal to reside within the organic extractant phase, and combining the transition metal-containing organic extractant phase with an hydroxamic acid-containing aqueous phase at a concentration and for a time sufficient to cause the transition metal to reside in the hydroxamic acid-containing aqueous phase.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1525028
- Patent Number(s):
- 10221466
- Application Number:
- 14/819,105
- Assignee:
- UChicago Argonne, LLC (Chicago, IL)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C22 - METALLURGY C22B - PRODUCTION AND REFINING OF METALS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015-08-05
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Gelis, Artem V., and Brown, Michael Alexander. Molybdenum recovery from aqueous nitric acid solution by solvent extraction. United States: N. p., 2019.
Web.
Gelis, Artem V., & Brown, Michael Alexander. Molybdenum recovery from aqueous nitric acid solution by solvent extraction. United States.
Gelis, Artem V., and Brown, Michael Alexander. Tue .
"Molybdenum recovery from aqueous nitric acid solution by solvent extraction". United States. https://www.osti.gov/servlets/purl/1525028.
@article{osti_1525028,
title = {Molybdenum recovery from aqueous nitric acid solution by solvent extraction},
author = {Gelis, Artem V. and Brown, Michael Alexander},
abstractNote = {The invention provides a method for extracting transition metals, the method comprising supplying a feedstream containing transition metal, mixing the feedstream with nitric acid for a time and at a concentration sufficient to form an aqueous phase containing the transition metal, combining the aqueous phase with organic extractant phase for a time and at a concentration sufficient to cause the transition metal to reside within the organic extractant phase, and combining the transition metal-containing organic extractant phase with an hydroxamic acid-containing aqueous phase at a concentration and for a time sufficient to cause the transition metal to reside in the hydroxamic acid-containing aqueous phase.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 05 00:00:00 EST 2019},
month = {Tue Mar 05 00:00:00 EST 2019}
}
Works referenced in this record:
Process for the two-phase extraction of metal ions from phases containing solid metal oxides, agents and the use thereof
patent, November 1993
- Schwab, Werner; Kehl, Ralf
- US Patent Document 5,260,039
Actinide and lanthanide separation process (ALSEP)
patent, January 2013
- Guelis, Artem V.
- US Patent Document 8,354,085
Common separation of contaminating elements from electrolyte solutions of valuable metals
patent, May 1989
- Schwab, Werner; Kehl, Ralf
- US Patent Document 4,834,951
Solvent Extraction of Metal Ions Using N-Substituted Hydroxamic Acids
patent, June 1974
- Lucid, Michael Francis
- US Patent Document 3,821,351
Solvent extraction of nickel using hydroxamic acids
patent, December 1990
- Monzyk, Bruce F.; Henn, Arthur R.
- US Patent Document 4,975,253