Alkali metal ion battery with bimetallic electrode
Abstract
Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten alkali metal and the electrode comprising the combined alkali/non-alkali metals.
- Inventors:
- Issue Date:
- Research Org.:
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1502817
- Patent Number(s):
- 10205195
- Application Number:
- 14/678,602
- Assignee:
- Massachusetts Institute of Technology (Cambridge, MA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H - ELECTRICITY H02 - GENERATION H02J - CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER
- DOE Contract Number:
- AR0000047
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Apr 03
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Boysen, Dane A., Bradwell, David J., Jiang, Kai, Kim, Hojong, Ortiz, Luis A., Sadoway, Donald R., Tomaszowska, Alina A., Wei, Weifeng, and Wang, Kangli. Alkali metal ion battery with bimetallic electrode. United States: N. p., 2019.
Web.
Boysen, Dane A., Bradwell, David J., Jiang, Kai, Kim, Hojong, Ortiz, Luis A., Sadoway, Donald R., Tomaszowska, Alina A., Wei, Weifeng, & Wang, Kangli. Alkali metal ion battery with bimetallic electrode. United States.
Boysen, Dane A., Bradwell, David J., Jiang, Kai, Kim, Hojong, Ortiz, Luis A., Sadoway, Donald R., Tomaszowska, Alina A., Wei, Weifeng, and Wang, Kangli. Tue .
"Alkali metal ion battery with bimetallic electrode". United States. https://www.osti.gov/servlets/purl/1502817.
@article{osti_1502817,
title = {Alkali metal ion battery with bimetallic electrode},
author = {Boysen, Dane A. and Bradwell, David J. and Jiang, Kai and Kim, Hojong and Ortiz, Luis A. and Sadoway, Donald R. and Tomaszowska, Alina A. and Wei, Weifeng and Wang, Kangli},
abstractNote = {Electrochemical cells having molten electrodes having an alkali metal provide receipt and delivery of power by transporting atoms of the alkali metal between electrode environments of disparate chemical potentials through an electrochemical pathway comprising a salt of the alkali metal. The chemical potential of the alkali metal is decreased when combined with one or more non-alkali metals, thus producing a voltage between an electrode comprising the molten alkali metal and the electrode comprising the combined alkali/non-alkali metals.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 12 00:00:00 EST 2019},
month = {Tue Feb 12 00:00:00 EST 2019}
}
Works referenced in this record:
The Thermally Regenerative Liquid-Metal Cell
journal, January 1963
- Agruss, B.
- Journal of The Electrochemical Society, Vol. 110, Issue 11
Anode for a secondary, high-temperature electrochemical cell
patent, January 1976
- Vissers, Donald R.; Tani, Benjamin S.
- US Patent Document 3,933,521
Composition and energy storage device
patent, May 2012
- Soloveichik, Grigorii Lev; Hart, Richard Louis; Galloway, Roy C.
- US Patent Document 8,178,231
Electrochemical device with solid separator and solid electrolyte
patent, August 1980
- Cadart, Francois; Coulombeau, Alain
- US Patent Document 4,216,273
High-amperage energy storage device and method
patent-application, February 2008
- Sadoway, Donald; Ceder, Gerbrand; Bradwell, David
- US Patent Application 11/839413; 20080044725
Cathodes for Secondary Electrochemical Power-producing Cells
patent, February 1973
- Cairns, Elton J.; Kyle, Martin; Shimotake, Hiroshi
- US Patent Document 3,716,409
Method for electrowinning of titanium metal or alloy from titanium oxide containing compound in the liquid state
patent, March 2009
- Cardarelli, Francois
- US Patent Document 7,504,017
Features and Challenges of Molten Oxide Electrolytes for Metal Extraction
journal, November 2014
- Allanore, Antoine
- Journal of The Electrochemical Society, Vol. 162, Issue 1
New opportunities for metals extraction and waste treatment by electrochemical processing in molten salts
journal, March 1995
- Sadoway, Donald R.
- Journal of Materials Research, Vol. 10, Issue 3
Apparatus and method for the electrolytic production of metals
patent, March 1991
- Sadoway, Donald R.
- US Patent Document 4,999,097
Phase-Field Modeling of Transport-Limited Electrolysis in Solid and Liquid States
journal, January 2007
- Pongsaksawad, Wanida; Powell, Adam C.; Dussault, David
- Journal of The Electrochemical Society, Vol. 154, Issue 6
ENERGY STORAGE DEVICE AND METHOD
patent-application, June 2008
- Iacovangelo, Charles Dominic; Bogdan, David Charles; Tysoe, Steven Alfred
- US Patent Application 11/769752; 20080145755
Fluid-surfaced electrode
patent, June 2013
- Deane, Geoffrey F.; Ferren, Bran; Gates, William
- US Patent Document 8,460,814
Arrangement and Method for Storing Electric Energy in Electrochemical Cells with a Large Diameter and High Storage Capacity
patent-application, March 2013
- Stefani, Frank; Weier, Tom; Gerbeth, Gunter
- US Patent Document 13/634418; 20130059176
Electrochemical Energy Storage Devices
patent-application, January 2015
- Bradwell, David J.; Vai, Alex T.; Kinney, Tom
- US Patent Document 14/178806; 20150004455
Metal--Salt Interactions at High Temperatures: The Solubilities of Some Alkaline Earth Metals in their Halides
journal, June 1949
- Cubicciotti, D. D.; Thurmond, C. D.
- Journal of the American Chemical Society, Vol. 71, Issue 6, p. 2149-2153
Low temperature alkali metal electrolysis
patent, May 2004
- Thompson, Jeffery Scott; Blank, Howard M.; Simmons, Walter John
- US Patent Document 6,730,210
Apparatus for electrolysis of molten oxides
patent-application, January 2008
- Sadoway, Donald
- US Patent Application 11/496615; 20080023321
Semi-Solid Electrode Cell Having A Porous Current Collector And Methods Of Manufacture
patent-application, March 2013
- Chiang, Yet-Ming; Carter, William; Cross, James
- US Patent Application 13/606986; 20130065122
Toward new technologies for the production of lithium
journal, May 1998
- Sadoway, Donald R.
- JOM, Vol. 50, Issue 5
Cathode active material for lithium secondary battery
patent-application, October 2012
- Sugiura, Ryuta; Kobayashi, Nobuyuki; Nanataki, Tsutomu
- US Patent Application 13/431062; 20120264021
Electrochemical Cell
patent, January 1970
- Shimotake, Hiroshi; Johnson, Carl E.; Foster, Melvin S.
- US Patent Document 3,488,221
A new proposal for the binary (Sn,Sb) phase diagram and its thermodynamic properties based on a new e.m.f. study
journal, January 1997
- Vassiliev, V.; Lelaurain, M.; Hertz, J.
- Journal of Alloys and Compounds, Vol. 247, Issue 1-2
A mathematical model for fluid flow in a weld pool at high currents
journal, June 1980
- Atthey, D. R.
- Journal of Fluid Mechanics, Vol. 98, Issue 4
Lithium anodes for electrochemical cells
patent, May 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,733,924
Method for Production of Metal by Molten-Salt Electrolysis and Method for Production of Titanium Metal
patent-application, March 2008
- Yamaguchi, Masanori; Ono, Yuichi; Kosemura, Susumu
- US Patent Application 11/576891; 20080053838
Secondary Cells with Lithium Anodes and Immobilized Fused-Salt Electrolytes
journal, January 1969
- Shimotake, Hiroshi; Rogers, G. L.; Cairns, E. J.
- Industrial & Engineering Chemistry Process Design and Development, Vol. 8, Issue 1
High Performance Liquid Metal Battery with Environmentally Friendly Antimony–Tin Positive Electrode
journal, May 2016
- Li, Haomiao; Wang, Kangli; Cheng, Shijie
- ACS Applied Materials & Interfaces, Vol. 8, Issue 20
Electrochemical cell
patent, December 1995
- Coetzer, Johan; Vlok, Isak L.
- US Patent Document 5,476,733
Electrochemical device and methods for energy conversion
patent, March 2010
- Tao, Tao; Bai, Wei
- US Patent Document 7,678,484
Liquid metal alloy energy storage device
patent, July 2015
- Bradwell, David J.; Ceder, Gerbrand; Ortiz, Luis Angel Ramirez
- US Patent Document 9,076,996
Recycling ZnTe, CdTe, and Other Compound Semiconductors by Ambipolar Electrolysis
journal, December 2011
- Bradwell, David J.; Osswald, Sebastian; Wei, Weifeng
- Journal of the American Chemical Society, Vol. 133, Issue 49
Alkaline earth metal ion battery
patent-application, January 2011
- Bradwell, David; Sadoway, Donald R.
- US Patent Application 12/505937; 20110014503
Secondary Electrochemical Cells with a Chalcogen Cathode
patent, September 1974
- Rubischko, Richard J.; Cairns, Elton J.; Steunenberg, Robert K.
- US Patent Document 3,833,421
Battery disposal system
patent-application, March 2013
- Camp, John; Camp, David M.
- US Patent Application 13/587815; 20130071306
High-Temperature Batteries
journal, June 1969
- Cairns, E. J.; Shimotake, H.
- Science, Vol. 164, Issue 3886
The Electrical Conductivity of Solutions of Metals in Their Molten Halides. VIII. Alkaline Earth Metal Systems
journal, July 1966
- Dworkin, A. S.; Bronstein, H. R.; Bredig, M. A.
- The Journal of Physical Chemistry, Vol. 70, Issue 7, p. 2384-2388
The Sodium∣Tin Liquid-Metal Cell
journal, January 1962
- Weaver, Robert D.; Smith, Stanley W.; Willmann, Norman L.
- Journal of The Electrochemical Society, Vol. 109, Issue 8, p. 653-657
Metal electrode assembly for flow batteries
patent, June 2012
- Winter, Rick; Kell, Brad; Hall, Jonathan
- US Patent Document 8,202,641
Extraction of liquid elements by electrolysis of oxides
patent, July 2014
- Allanore, Antoine; Sadoway, Donald R.
- US Patent Document 8,764,962
Electrolytic production of metals using consumable anodes
patent, February 1993
- Sadoway, Donald R.
- US Patent Document 5,185,068
Porous carbonaceous electrode structure and method for secondary electrochemical cell
patent, March 1977
- Kaun, Thomas D.
- US Patent Document 4,011,374
Alkali metal ion battery with bimetallic electrode
patent, April 2015
- Boysen, Dane; Bradwell, David J.; Jiang, Kai-Li
- US Patent Document 9,000,713
Electrochemical Energy Storage Devices
patent-application, April 2014
- Bradwell, David J.; Nayar, Hari
- US Patent Document 13/801333; 20140113181
Voltage-enhanced energy storage devices
patent-application, January 2015
- Bradwell, David J.; Yu, Xingwen; Thompson, Greg A.
- US Patent Application 14/286369; 20150015210
Regeneration of EMF Cells Having Molten Metal Electrodes and a Fused Salt Electrolyte
patent, March 1966
- Foster, Melvin S.; Crouthamel, Carl E.
- US Patent Document 3,238,437
High Energy Density Redox Flow Device
patent-application, August 2011
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan
- US Patent Application 12/970753; 20110200848
Liquid Electrode Battery
patent-application, January 2011
- Bradwell, David; Ceder, Gerbrand; Ortiz, Luis
- US Patent Document 12/839130; 20110014505
Electrolysis of Molten Iron Oxide with an Iridium Anode: The Role of Electrolyte Basicity
journal, January 2011
- Kim, Hojong; Paramore, James; Allanore, Antoine
- Journal of The Electrochemical Society, Vol. 158, Issue 10
Method for electrolytic production and refining of metals
patent-application, September 2007
- Johansen, Kai; Sadoway, Donald R.; Myhre, Bjorn
- US Patent Application 11/682457; 20070215483
The eelectrochemical processing of refractory metals
journal, July 1991
- Sadoway, Donald R.
- JOM, Vol. 43, Issue 7
High Energy Density Redox Flow Device
patent-application, February 2010
- Chiang, Yet-Ming; Carter, W. Craig; Ho, Bryan H.
- US Patent Document 12/484113; 20100047671
Voltage-enhanced energy storage devices
patent-application, May 2015
- Bradwell, David J.; Yu, Xingwen; Thompson, Greg A.
- US Patent Application 14/536549; 20150132627
Electrochemical Energy Storage Devices
patent-application, May 2015
- Bradwell, David J.; Vai, Alex; Kinney, Tom
- US Patent Document 14/536563; 20150132628
A new anode material for oxygen evolution in molten oxide electrolysis
journal, May 2013
- Allanore, Antoine; Yin, Lan; Sadoway, Donald R.
- Nature, Vol. 497, Issue 7449
Process and Cell for the Production of Manganese of Low Carbon Content by Means of a Fused Electrolytic Bath
patent, October 1970
- Winand, Rene F. P.
- US Patent Document 3,535,214
Low temperature alkali metal electrolysis
patent, April 2002
- Thompson, Jeffrey; Blank, Howard M.; Simmons, Walter John
- US Patent Document 6,368,486
Lithium Storage Cells with a Fused Electrolyte
patent, November 1973
- Ryerson, Joseph L.
- US Patent Document 3,775,181