DOE Patents title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Devices for electrocatalytic conversion of carbon dioxide

Abstract

An electrocatalytic device for carbon dioxide conversion includes a cathode with a Catalytically Active Elementa metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO.sup.-, H.sub.2CO, (HCOO).sup.-, HCOOH, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, (COO.sup.-).sub.2, and CF.sub.3COOH.

Inventors:
Issue Date:
Research Org.:
US Department of Energy (USDOE), Washington, DC (United States). Advanced Research Projects Agency-Energy (ARPA-E)
Sponsoring Org.:
USDOE
OSTI Identifier:
1496610
Patent Number(s):
10173169
Application Number:
15/724,933
Assignee:
Dioxide Materials, Inc (Boca Raton, FL)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
AR-0000345; AR0000684
Resource Type:
Patent
Resource Relation:
Patent File Date: 2017 Oct 04
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Masel, Richard I. Devices for electrocatalytic conversion of carbon dioxide. United States: N. p., 2019. Web.
Masel, Richard I. Devices for electrocatalytic conversion of carbon dioxide. United States.
Masel, Richard I. Tue . "Devices for electrocatalytic conversion of carbon dioxide". United States. https://www.osti.gov/servlets/purl/1496610.
@article{osti_1496610,
title = {Devices for electrocatalytic conversion of carbon dioxide},
author = {Masel, Richard I.},
abstractNote = {An electrocatalytic device for carbon dioxide conversion includes a cathode with a Catalytically Active Elementa metal in the form of supported or unsupported particles or flakes with an average size between 0.6 nm and 100 nm. The reaction products comprise at least one of CO, HCO.sup.-, H.sub.2CO, (HCOO).sup.-, HCOOH, CH.sub.3OH, CH.sub.4, C.sub.2H.sub.4, CH.sub.3CH.sub.2OH, CH.sub.3COO.sup.-, CH.sub.3COOH, C.sub.2H.sub.6, (COOH).sub.2, (COO.sup.-).sub.2, and CF.sub.3COOH.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 08 00:00:00 EST 2019},
month = {Tue Jan 08 00:00:00 EST 2019}
}

Works referenced in this record:

Means and method for reducing carbon dioxide to provide a product
patent, June 1985


CO2 attraction by specifically adsorbed anions and subsequent accelerated electrochemical reduction
journal, December 2010


Urethane (meth) acrylates containing cyclic carbonate groups
patent, June 1998


Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode
journal, May 2005


Isolation of Nucleic Acids Using Silica-Gel Based Membranes: Methods Based on the Use of QIAamp Spin Columns
book, January 1997


Effect of surface order on adsorption of sulfate ions on silver electrodes
journal, January 1998


Influence of substituted benzaldehydes and their derivatives as inhibitors for hydrogen evolution in lead/acid batteries
journal, February 1995


Development of a continuous reactor for the electro-reduction of carbon dioxide to formate – Part 1: Process variables
journal, August 2006


Structure sensitivity and nanoscale effects in electrocatalysis
journal, January 2011


Oxygen Reduction on Silver Low-Index Single-Crystal Surfaces in Alkaline Solution:  Rotating Ring DiskAg(hkl) Studies
journal, March 2006


Method for producing formic acid or its derivatives
patent, June 1997


Recent advances in the homogeneous hydrogenation of carbon dioxide
journal, December 2004


Electrocatalyst powders, methods for producing powder and devices fabricated from same
patent-application, April 2004


Methods and apparatus for cardiac valve repair
patent, April 2010


Studies on Suppression of Hydrogen Evolution Reaction for Zinc/Air Fuel Cell
journal, March 2007


Hydroxyl-functionalized ionic liquid: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate
journal, May 2008


Means and method for reducing carbn dioxide to provide an oxalate product
patent, June 1986


Shape-dependent electrocatalysis: methanol and formic acid electrooxidation on preferentially oriented Pt nanoparticles
journal, January 2008

  • Solla-Gullón, J.; Vidal-Iglesias, F. J.; López-Cudero, A.
  • Physical Chemistry Chemical Physics, Vol. 10, Issue 25, p. 3689-3698
  • https://doi.org/10.1039/b802703j

Ion-Conducting Membranes
patent-application, April 2016


Electrochemical activation of CO2 in ionic liquid (BMIMBF4): synthesis of organic carbonates under mild conditions
journal, January 2008


Novel catalyst mixtures
patent-application, September 2011


Direct Electrodeposition of Tetrahexahedral Pd Nanocrystals with High-Index Facets and High Catalytic Activity for Ethanol Electrooxidation
journal, June 2010


Electrochemical devices comprising novel catalyst mixtures
patent, October 2016


Gas Phase Electrochemical Reduction Of Carbon Dioxide
patent-application, July 2012


Reduction of carbon dioxide in 1-butyl-3-methylimidazolium acetate
journal, January 2009


Size effects on reactivity of Pt nanoparticles in CO monolayer oxidation: The role of surface mobility
journal, January 2004


Effect of additives in zinc alloy powder on suppressing hydrogen evolution
journal, July 1998


Specific surface reactions for identification of platinum surface domains
journal, August 2005


Some Reactions of Atomic Hydrogen
journal, November 1929


Bioinspired Energy Conversion Systems for Hydrogen Production and Storage
journal, March 2008


In situ FT-IR and ex situ EPR analysis for the study of the electroreduction of carbon dioxide in N,N-dimethylformamide on a gold interface
journal, April 2005


Methods of Sequestering CO2
patent-application, July 2009


A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
journal, August 2006


Electrochemical activation of carbon dioxide in ionic liquid: synthesis of cyclic carbonates at mild reaction conditions
journal, January 2002


Method for reducing carbon dioxide to provide a product
patent, October 1985


Material for a facility for the production of anhydrous formic acid
patent, July 2007


Design of an Electrochemical Cell Making Syngas  (CO + H2)  from CO2 and H2O Reduction at Room Temperature
journal, January 2008


Efficient Homogeneous Catalysis in the Reduction of CO2 to CO
journal, December 2005

  • Laitar, David S.; Müller, Peter; Sadighi, Joseph P.
  • Journal of the American Chemical Society, Vol. 127, Issue 49, p. 17196-17197
  • https://doi.org/10.1021/ja0566679

Electrochemical Sensor
patent-application, June 2010


Reduction of CO2 under high pressure and high temperature on Pb-granule electrodes in a fixed-bed reactor in aqueous medium
journal, October 2004


Effect of sodium cation on the electrochemical reduction of CO2 at a copper electrode in methanol
journal, August 2006


A new class of proton-conducting ionic plastic crystals based on organic cations and dihydrogen phosphate
journal, May 2007


Influence of adsorption processes on the CO2 electroreduction: An electrochemical mass spectrometry study
journal, August 2005


Nanoelectronic Carbon Dioxide Sensors
journal, October 2004


Electrochemical Production of Synthesis Gas from Carbon Dioxide
patent-application, May 2011


A short review of catalysis for CO2 conversion
journal, November 2009


Production of formate salts
patent, November 1989


System and High Surface Area Electrodes for the Electrochemical Reduction of Carbon Dioxide
patent-application, May 2013


Alkaline Stable C2-Substituted Imidazolium-Based Anion-Exchange Membranes
journal, April 2013


Low contaminant formic acid fuel for direct liquid fuel cell
patent, November 2009


Electrochemistry in Room Temperature Ionic Liquids: A Review and Some Possible Applications
journal, October 2006


Cathode for reduction of carbon dioxide and method for manufacturing such a cathode
patent, September 1998


Electrochemical Reduction of CO2 to Methane at the Cu Electrode in Methanol with Sodium Supporting Salts and Its Comparison with Other Alkaline Salts
journal, January 2006


Method and apparatus for interactive music accompaniment
patent, February 1999


Reduction of CO2 to Ethylene at Three-Phase Interface Effects of Electrode Substrate and Catalytic Coating
journal, January 2005


Method and device for producing formates and the use thereof
patent, January 2008


Electrosynthesis of hydroxylammonium salts and hydroxylamine using a mediator
patent, February 2000


Comparison of Oxygen Reduction Reaction at Silver Nanoparticles and Polycrystalline Silver Electrodes in Alkaline Solution
journal, May 2012


Role of surface defect sites: from Pt model surfaces to shape-controlled nanoparticles
journal, January 2012


Novel Catalyst Mixtures
patent-application, December 2012


Composite blend polymer membranes with increased proton selectivity and lifetime for vanadium redox flow batteries
journal, June 2013


Method for producing adiponitrile
patent, December 1988


Work functions of metal clusters
journal, December 1994


The electrooxidation of small organic molecules on platinum nanoparticles supported on gold: influence of platinum deposition procedure
journal, June 2007


Electrochemical CO2 Reduction on Metal Electrodes
book, January 2008


Process for reduction of carbon dioxide with organometallic complex
patent-application, February 2007


Electrosorption of carbon dioxide on platinum group metals and alloys—a review
journal, July 2008


Heterocycle Catalyzed Electrochemical Process
patent-application, September 2011


A Supramolecular Cobalt–Porphyrin-modified Electrode, toward the Electroreduction of Co2
journal, February 2004


Investigation of proton dynamics and the proton transport pathway in choline dihydrogen phosphate using solid-state NMR
journal, January 2010


Basic Research Needs: Catalysis for Energy
report, March 2008


Preparation for production of formic acid formates
patent, June 2005


Electrochemical Reduction of Benzoic Acid and Substituted Benzoic Acids in Some Room Temperature Ionic Liquids
journal, August 2008


Electrocatalytic Reduction of CO2 to Small Organic Molecule Fuels on Metal Catalysts
book, January 2010


Hydrogenation of CO2 to Formic Acid Promoted by a Diamine-Functionalized Ionic Liquid
journal, March 2009


Solvent-free synthesis of substituted ureas from CO2 and amines with a functional ionic liquid as the catalyst
journal, January 2008


Electrophoresis process using ionic liquids
patent-application, February 2004


Electrochemical Processing of Carbon Dioxide
journal, May 2008


Electrochemical apparatus for simultaneously monitoring two gases
patent, February 1982


Electrochemical and Surface Studies of Carbon Dioxide Reduction to Methane and Ethylene at Copper Electrodes in Aqueous Solutions
journal, January 1989


Photoelectrochemical reduction of CO2 at p-InP electrode in copper particle-suspended methanol
journal, May 2009


Electrocatalysts for carbon dioxide conversion
patent, April 2015


Electrochemical reduction of supercritical carbon dioxide in ionic liquid 1-n-butyl-3-methylimidazolium hexafluorophosphate
journal, December 2004


Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
journal, December 2009


Electrocatalytic Carbon Dioxide Activation: The Rate-Determining Step of Pyridinium-Catalyzed CO2 Reduction
journal, February 2011


Catalytic Composition for the Insertion of Carbon Dioxide Into Organic Compounds
patent-application, May 2008


Electrolysis of Carbon Dioxide in Aqueous Media to Carbon Monoxide and Hydrogen for Production of Methanol
patent-application, January 2009


Hydrogenation of Carbon Dioxide is Promoted by a Task-Specific Ionic Liquid
journal, January 2008


Electroreduction of carbon dioxide on palladium electrodes at potentials higher than the reversible hydrogen potential
journal, August 1994


Electrochemical Methods of Sequestering CO2
patent-application, June 2010


Process for preparing hydrocarbons
patent, September 1999


Electrochemical device for converting carbon dioxide to a reaction product
patent, November 2016


Method for the natural production of formic acid or formate
patent, March 1999


Carboxylation of Terminal Alkynes with Carbon Dioxide Catalyzed by Poly(N-Heterocyclic Carbene)-Supported Silver Nanoparticles
journal, April 2012


Electrochemical reduction of CO2 in copper particle-suspended methanol
journal, June 2006


New process for the preparation of 2-aryl-propionic acids
patent, February 1992


The Catalytic Combination of Ethylene and Hydrogen in the Presence of Metallic Copper III. Carbon Monoxide as a Catalyst Poison
journal, May 1925


Development of a continuous reactor for the electro-reduction of carbon dioxide to formate – Part 2: Scale-up
journal, July 2007


Voltammetry of carbon dioxide: Part I. A general survey of voltammetry at different electrode materials in different solvents
journal, June 1983


Methods of Sequestering CO2
patent-application, June 2010


Particle size effect for ethanol electro-oxidation on Pt/C catalysts in half-cell and in a single direct ethanol fuel cell
journal, May 2011


Electrochemical Cell for Production of Synthesis Gas Using Atmospheric Air and Water
patent-application, March 2007


Zinc Ion Effect on the Electrochemical Reduction of Carbon Dioxide at Zinc Electrode in Aqueous Solutions
journal, January 1999


Continuous Co-Current Electrochemical Reduction of Carbon Dioxide
patent-application, September 2008


Preparation of formic acid by thermal cleavage of quaternary ammonium formates
patent, March 1994


Application of ionic liquids as an electrolyte additive on the electrochemical behavior of lead acid battery
journal, February 2009


Electrochemical reduction of carbon dioxide catalyzed by [Pd(triphosphine)(solvent)](BF4)2 complexes: synthetic and mechanistic studies
journal, November 1991


Electrochemical decomposition of choline chloride based ionic liquid analogues
journal, January 2009


Electrodeposition of tin and antimony in 1-ethyl- 3-methylimidazolium tetrafluoroborate ionic liquid
journal, December 2007


Influence of particle agglomeration on the catalytic activity of carbon-supported Pt nanoparticles in CO monolayer oxidation
journal, January 2005


Ionic Liquid-Mediated Selective Conversion of CO2 to CO at Low Overpotentials
journal, September 2011


Electrocatalyst powders, methods for producing powders and devices fabricated from same
patent, December 2003


Water-Retention Effect of Composite Membranes with Different Types of Nanometer Silicon Dioxide
journal, January 2008


Activation of carbon dioxide: nickel-catalyzed electrochemical carboxylation of diynes
journal, April 1993


Conversion of carbon dioxide to organic products
patent, November 2012


Model approach to evaluate particle size effects in electrocatalysis: preparation and properties of Pt nanoparticles supported on GC and HOPG
journal, November 2003


Electrochemical reduction of carbon dioxide at various series of copper single crystal electrodes
journal, May 2003


CO monolayer oxidation on semi-spherical and preferentially oriented (100) and (111) platinum nanoparticles
journal, January 2006


High performance RuPd catalysts for CO2 reduction at gas-diffusion electrodes
journal, June 1997


Electrocatalysis of CO2 reduction by ruthenium benzothiazole and bithiazole complexes
journal, October 2007


Electrochemical Device For Converting Carbon Dioxide To A Reaction Product
patent-application, April 2016


Process for producing formic ester or methanol and synthesis catalyst therefor
patent, July 2006


Electrochemical synthesis of methane
patent, September 1986


Electrochemical reduction of aqueous carbon dioxide to methanol
patent, September 1986


Development and Commercialization of the Monsanto Electrochemical Adiponitrile Process
journal, January 1984


Formose sugars from formaldehyde
journal, September 1981


Two routes to formaldehyde from formic acid on TiO2(001) surfaces
journal, March 1996


Adsorption of CO2 on the Rutile (110) Surface in Ionic Liquid. A Molecular Dynamics Simulation
journal, October 2009


Electrochemical sensor
patent, September 1997


Electrochemical Reduction of Liquid CO2: Drastic Enhancement of Current Density
journal, January 1994


Selective Formation of Formic Acid, Oxalic Acid, and Carbon Monoxide by Electrochemical Reduction of Carbon Dioxide
journal, July 1987


Imidazolium functionalized polysulfone anion exchange membrane for fuel cell application
journal, January 2011


Gas sensor
patent, October 1984


Electrochemical evidence of intermediate formation of adsorbed CO in cathodic reduction of CO2 at a nickel electrode
journal, November 1990


Particle-size effect of nanoscale platinum catalysts in oxygen reduction reaction: an electrochemical and 195Pt EC-NMR study
journal, January 2006


Novel anion exchange membranes based on polymerizable imidazolium salt for alkaline fuel cell applications
journal, January 2011


Particle size effect for oxygen reduction and methanol oxidation on Pt/C inside a proton exchange membrane
journal, August 1994


Method for producing anhydrous formic acid
patent, January 2005


Reducing Carbon Dioxide To Products
patent-application, May 2011


Method for Conversion of Atmospheric Carbon Dioxide into Useful Materials
patent-application, June 2010


Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins
patent, March 2004


Observation of surface structural changes of Pt octahedron nanoparticles and its effect in electrocatalysis oxidation of methanol
journal, March 2009


Size Effects in Electronic and Catalytic Properties of Unsupported Palladium Nanoparticles in Electrooxidation of Formic Acid
journal, July 2006


Structure of Chemisorbed Sulfur on a Pt(111) Electrode
journal, January 1997


Use of recirculated exhaust gas in a burner-based exhaust generation system for reduced fuel consumption and for cooling
patent-application, October 2006


Pentaerythritol Purification Process
patent, December 1973


Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis
journal, August 1999


Electrochemical organic synthesis
patent, October 1984


Electrochemical carbon dioxide sensor
patent-application, May 2006


Multi-gas microsensor assembly
patent-application, November 2010


Method and device for producing formic acid formates and use of said formates
patent, April 2008


Shape dependent electrocatalysis
journal, January 2011


Humidity-sensitive properties of new polyelectrolytes based on the copolymers containing phosphonium salt and phosphine function
journal, May 2003


Electrochemical Reduction Of Carbon Dioxide Using Gas Diffusion Electrodes Loaded With Fine Catalysts
conference, January 2009


Interaction of sulfate ions with monocrystalline silver electrodes
journal, March 1998


Palladium-Catalyzed Reppe Carbonylation
journal, November 2001


Fixation of CO2 by Electrocatalytic Reduction and Electropolymerization in Ionic Liquid–H2O Solution
journal, March 2008


Electrochemical activation of carbon dioxide for synthesis of dimethyl carbonate in an ionic liquid
journal, April 2009


Selective ethylene formation by pulse-mode electrochemical reduction of carbon dioxide using copper and copper-oxide electrodes
journal, July 2006


Quaternized poly(methyl methacrylate-co-butyl acrylate-co-vinylbenzyl chloride) membrane for alkaline fuel cells
journal, June 2010


Production of potassium formate
patent, February 2005


Lutetium Monophthalocyanine and Diphthalocyanine Complexes and Lithium Naphthalocyanine as Catalysts for Electrochemical CO2 Reduction
journal, January 2003


Commercially Available Salts as Building Blocks for New Ionic Liquids
book, August 2003


Catalysis with Transition Metal Nanoparticles in Colloidal Solution:  Nanoparticle Shape Dependence and Stability
journal, July 2005


Electrochemical reduction of CO2 to hydrocarbons to store renewable electrical energy and upgrade biogas
journal, April 2007


Method for preparing formic acid
patent, August 2002


Electrochemical reduction of carbon dioxide at a series of platinum single crystal electrodes
journal, August 2000


Curable Compositions and Membranes
patent-application, December 2014


Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex
journal, July 2006


CO electrooxidation on carbon supported platinum nanoparticles: Effect of aggregation
journal, June 2010


Purification of Carbon Dioxide from a Mixture of Gases
patent-application, May 2011


The electrochemical reduction of CO2 to CH4 and C2H4 at Cu/Nafion electrodes (solid polymer electrolyte structures)
journal, January 1988


Mathematical Modeling of a Cation-Exchange Membrane Containing Two Cations
journal, January 2008


Production of sodium diformate
patent, November 2009


Electrochemical reduction of CO2 in methanol with aid of CuO and Cu2O
journal, November 2009


A new homogeneous electrocatalyst for the reduction of carbon dioxide to methanol at low overpotential
journal, July 1994


Membrane divided aqueous-nonaqueous system for electrochemical cells
patent, November 1990


Platinum Metal Catalysts of High-Index Surfaces: From Single-Crystal Planes to Electrochemically Shape-Controlled Nanoparticles
journal, November 2008


Improved yields of oxalate, glyoxylate and glycolate from the electrochemical reduction of carbon dioxide in methanol
journal, January 1997


The Effect of the Particle Size on the Kinetics of CO Electrooxidation on High Surface Area Pt Catalysts
journal, May 2005

  • Arenz, Matthias; Mayrhofer, Karl J. J.; Stamenkovic, Vojislav
  • Journal of the American Chemical Society, Vol. 127, Issue 18, p. 6819-6829
  • https://doi.org/10.1021/ja043602h

Thick-Film Carbon Dioxide Sensor via Anodic Adsorbate Stripping Technique and Its Structural Dependence
journal, September 2009


Preparation of formic acid from carbon monoxide and water
patent, August 1994


Catalyst for preparing hydrocarbon
patent, January 2007


Electrochemical reduction of carbon dioxide to ethylene with high Faradaic efficiency at a Cu electrode in CsOH/methanol
journal, September 1999


Chiral ionic liquids improved the asymmetric cycloaddition of CO2 to epoxides
journal, January 2009


Decomposition and Reforming of Formic Acid on Supported Au Catalysts: Production of CO-Free H2
journal, July 2011


Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980


Acidic gas sensors and method of using same
patent, December 1991


Electrochemical Reduction of Carbon Dioxide at Various Metal Electrodes in Aqueous Potassium Hydrogen Carbonate Solution
journal, September 1990


Electro-reduction of carbon dioxide to formate on lead electrode in aqueous medium
journal, September 2008


Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products
patent-application, October 2006


Electrochemical Reduction of Carbon Dioxide on Various Metal Electrodes in Low-Temperature Aqueous KHCO3 Media
journal, January 1990


Electrode catalyst for electrolytic reduction of carbon dioxide gas
patent, February 1994


Effects of tetrabutylammonium hydrogen sulfate as an electrolyte additive on the electrochemical behavior of lead acid battery
journal, April 2008


Method for production of formic acid
patent, March 2004


Catalyst mixtures
patent, February 2015


Synthesis of Tetrahexahedral Platinum Nanocrystals with High-Index Facets and High Electro-Oxidation Activity
journal, May 2007


Electrochemical reduction of CO2 at copper single crystal Cu(S)-[n(111)×(111)] and Cu(S)-[n(110)×(100)] electrodes
journal, September 2002


The Electrochemical Reduction of Hydrogen Sulfide on Platinum in Several Room Temperature Ionic Liquids
journal, April 2008


Comparative EQCM study on electrooxidation of carbon oxides adsorption products on noble metals and their alloys. Polycrystalline Pd-based systems
journal, August 2007


Preparation of formic acid
patent, April 1993


Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3
journal, January 1997


Particle Size Effects for Oxygen Reduction on Highly Dispersed Platinum in Acid Electrolytes
journal, January 1990


Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates
patent, November 2013


Means and method for reducing carbon dioxide to a product
patent, June 1987


Method for the production of formic acid
patent, September 2008


Chemically modified electrodes for the catalytic reduction of CO.sub.2
patent, July 1988


Gas fixation solar cell using gas diffusion semiconductor electrode
patent, December 1980


Conversion of Carbon Dioxide to Organic Products
patent-application, July 2010


Monolayers of choline chloride can enhance desired electrochemical reactions and inhibit undesirable ones
journal, April 2013


Electrochemical membrane reactor for the reduction of carbondioxide to formate
journal, November 2006


Electrochemical reduction of CO2 on single crystal electrodes of silver Ag(111), Ag(100) and Ag(110)
journal, December 1997


Linked strategy for the production of fuels via formose reaction
journal, February 2013


A Robust Ionic Liquid as Reaction Medium and Efficient Organocatalyst for Carbon Dioxide Fixation
journal, February 2008


Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights
journal, August 2010

  • Barton Cole, Emily; Lakkaraju, Prasad S.; Rampulla, David M.
  • Journal of the American Chemical Society, Vol. 132, Issue 33, p. 11539-11551
  • https://doi.org/10.1021/ja1023496

The electrolytic reduction of carbon dioxide to formic acid
journal, September 1971


Electrochemical Production of Urea from NOx and Carbon Dioxide
patent-application, May 2011


The effect of quaternary ammonium salts on the anodic oxidation of ethanol
journal, February 1985


Electrochemical reduction of carbon dioxide on kinked stepped surfaces of platinum inside the stereographic triangle
journal, January 2003


Ethylene oxide catalyst
patent, October 1987


Electrocatalytic reduction of carbon dioxide by a polymeric film of rhenium tricarbonyl dipyridylamine
journal, August 2009


Electrolysis cell and method of use
patent, May 1990


Selective formation of ethylene from CO2 by catalytic electrolysis at a three-phase interface
journal, December 2004


Dependence of CO oxidation on Pt nanoparticle shape: a shape-selective approach to the synthesis of PEMFC catalysts
journal, January 2008


Supported choline chloride/urea as a heterogeneous catalyst for chemical fixation of carbon dioxide to cyclic carbonates
journal, January 2007