Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods
Abstract
A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.
- Inventors:
- Issue Date:
- Research Org.:
- PolyPlus Battery Company, Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1496211
- Patent Number(s):
- 10147968
- Application Number:
- 14/954,816
- Assignee:
- PolyPlus Battery Company, Berkeley, CA
- Patent Classifications (CPCs):
-
C - CHEMISTRY C03 - GLASS C03B - MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
C - CHEMISTRY C03 - GLASS C03C - CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS
- DOE Contract Number:
- AR0000349; AR0000772
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Nov 30
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Visco, Steven J., Nimon, Yevgeniy S., and De Jonghe, Lutgard C. Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods. United States: N. p., 2018.
Web.
Visco, Steven J., Nimon, Yevgeniy S., & De Jonghe, Lutgard C. Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods. United States.
Visco, Steven J., Nimon, Yevgeniy S., and De Jonghe, Lutgard C. Tue .
"Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods". United States. https://www.osti.gov/servlets/purl/1496211.
@article{osti_1496211,
title = {Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods},
author = {Visco, Steven J. and Nimon, Yevgeniy S. and De Jonghe, Lutgard C.},
abstractNote = {A standalone lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 04 00:00:00 EST 2018},
month = {Tue Dec 04 00:00:00 EST 2018}
}
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Works referenced in this record:
Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries
journal, November 2004
- Hayashi, A.
- Solid State Ionics, Vol. 175, Issue 1-4
Ionically conductive membranes for protection of active metal anodes and battery cells
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/824574; 20080057386
Alkaline cation conductive vitreous composition and a method of preparing such a composition
patent, May 1982
- Malugani, Jean-Pierre; Robert, Guy
- US Patent Document 4,331,750
Hydrogels for aqueous lithium/air battery cells
patent, March 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,389,147
Lithium battery having a protected lithium electrode and an ionic liquid catholyte
patent, September 2014
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,828,580
Electrochemical device component with protected alkali metal electrode
patent, December 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,858,223
Protected Lithium Electrodes Having a Porous Electrolyte Interlayer and Associated Battery Cells
patent-application, December 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 15/150231; 20160351879
Solid State Electrolyte Layer, Electrode Active Material Layer, All Solid State Lithium Battery, Manufacturing Method for Solid State Electrolyte Layer, And Manufacturing Method for Electrode Active Material Layer
patent-application, March 2011
- Hama, Shigenori; Kawamoto, Koji; Wakasugi, Satoshi
- US Patent Application 12/891242; 20110076570
Cathodes and reservoirs for aqueous lithium/air battery cells
patent, June 2013
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,455,131
Plating metal negative electrodes under protective coatings
patent, April 2004
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,723,140
Preparation and Conductivity Measurements of SiS[sub 2]-Li[sub 2]S-LiBr Lithium Ion Conductive Glasses
journal, January 1985
- Sahami, Saeed
- Journal of The Electrochemical Society, Vol. 132, Issue 4
Stabilized anode for lithium-polymer batteries
patent, July 1997
- Skotheim, Terje A.
- US Patent Document 5,648,187
Lithium ion conducting solid electrolytes prepared from Li2S, elemental P and S
journal, October 2006
- Mizuno, F.; Ohtomo, T.; Hayashi, A.
- Solid State Ionics, Vol. 177, Issue 26-32
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, March 1997
- Bates, John B.
- US Patent Document 5,612,152
Cyclic voltammetry studies of the lithiumthioborate glass—indium interface
journal, November 1989
- Rudolph, B.; Burckhardt, W.; Staikov, G.
- Electrochimica Acta, Vol. 34, Issue 11
Preparation and conductivity measurements of SiS2Li2S glasses doped with LiBr and LiCl
journal, January 1986
- Kennedy, J.; Sahami, S.; Shea, S.
- Solid State Ionics, Vol. 18-19
Protected Lithium Electrodes with Protective Membrane Having a Garnet Like Structure and Lithium Battery Cells Thereof
patent-application, July 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 14/994011; 20160197326
ChemInform Abstract: Preparation and Structure of Lithium-Ion-Conducting Mixed-Anion Glasses in the System LiBO2-LiBS2.
journal, December 1988
- Tatsumisago, M.; Yoneda, K.; Minami, T.
- ChemInform, Vol. 19, Issue 51
Aqueous Electrolyte Lithium Sulfur Batteries
patent-application, October 2014
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 14/334573; 20140322584
Vitreous phosphorus oxide-sulfide solid lithium electrolyte
patent, July 1986
- Akridge, James R.
- US Patent Document 4,599,284
Lithium Battery with Hermetically Sealed Anode
patent-application, June 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgar
- US Patent Application 14/181423; 20140162108
Solid State Battery
patent-application, April 2012
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 13/336459; 20120094188
Lithium anodes for electrochemical cells
patent, July 2007
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 7,247,408
Active metal/aqueous electrochemical cells and systems
patent, January 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,645,543
Method for forming encapsulated lithium electrodes having glass protective layers
patent, August 2002
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,432,584
Lithium sulfur batteries and electrolytes and sulfur cathodes thereof
patent, May 2017
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Document 9,660,265
Glass–ceramic Li2S–P2S5 electrolytes prepared by a single step ball billing process and their application for all-solid-state lithium–ion batteries
journal, September 2009
- Trevey, James; Jang, Jum Suk; Jung, Yoon Seok
- Electrochemistry Communications, Vol. 11, Issue 9
Vitreous Solid Electrolyte Sheets of Li Ion Conducting Sulfur-based Glass and Associated Structures, Cells and Methods
patent-application, June 2016
- Visco, Steven J.; NImon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/954812; 20160190640
Method of Producing Solid Sulfide Electrolyte Material and Solid Sulfide Electrolyte Material
patent-application, April 2014
- Sugiura, Koichi; Kawamoto, Koji; Koyama, Takayuki
- US Patent Application 14/117784; 20140093785
Aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,575
Electrolyte compositions for aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,574
Electrode structures for aqueous electrolyte lithium sulfur batteries
patent, September 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,828,573
Glassy materials based on Li2S for all-solid-state lithium secondary batteries
journal, November 2004
- Tatsumisago, M.
- Solid State Ionics, Vol. 175, Issue 1-4
Method of making an electrolyte for an electrochemical cell
patent, April 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,512,147
Lithium ion-conductive solid electrolyte and method for producing the same
patent, September 1999
- Takada, Kazunori; Iwamoto, Kazuya; Kondo, Shigeo
- US Patent Document 5,958,281
Quaternary vitreous solid lithium cation conductive electrolyte
patent, April 1986
- Akridge, James R.
- US Patent Document 4,585,714
Sulfide Solid Electrolyte Glass, Method for Producing Sulfide Solid Electrolyte Glass, and Lithium Solid State Battery
patent-application, June 2013
- Kato, Yuki; Kawamoto, Koji; Hama, Shigenori
- US Patent Application 13/811052; 20130164632
Active metal/aqueous electrochemical cells and systems
patent, February 2010
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 7,666,233
Lithium ion-conductive solid electrolyte containing lithium titanium phosphate
patent, January 1991
- Adachi, Ginya; Imanaka, Nobuhito; Aono, Hiromichi
- US Patent Document 4,985,317
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, November 2002
- Fu, Jie
- US Patent Document 6,485,622
Process for Producing Sulfide-based Solid Electrolyte
patent-application, May 2011
- Hama, Shigenori; Hayashi, Mitsuhiko
- US Patent Application 13/001708; 20110108642
Lithium anodes for electrochemical cells
patent, May 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,733,924
Lithium Ion Conductive Sulfide-Based Solid Electrolyte and All-Solid Lithium Battery Using Same
patent-application, June 2009
- Seino, Yoshikatsu; Nakagawa, Masaru; Senga, Minoru
- US Patent Application 12/096481; 20090159839
Sulfide Solid Electrolyte Material
patent-application, February 2012
- Tatsumisago, Masahiro; Hayashi, Akitoshi; Hama, Shigenori
- US Patent Application 13/203379; 20120034529
Electrochemical cell including a solid electrolyte made from a cation conductive vitreous compound
patent, April 1984
- Duchange, Jean-Pierre; Gabano, Jean-Paul
- US Patent Document 4,444,857
New lithium ion conductors based on Li2S-SiS2 system
journal, July 1992
- Kondo, S.; Takada, K.; Yamamura, Y.
- Solid State Ionics, Vol. 53-56
Lithium anodes for electrochemical cells
patent, September 2004
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Document 6,797,428
High-Performance All-Solid Lithium Battery
patent-application, October 2007
- Seimo, Yoshikatsu; Takada, Kazunori
- US Patent Application 11/628030; 20070248888
Lithium ion conductive solid electrolyte and production process thereof
patent-application, October 2007
- Inda, Yasushi
- US Patent Application 11/727489; 20070231704
Plating metal negative electrodes under protective coatings
patent, June 2002
- Chu, May-Ying; Visco, Steven J.; De Jonghe, Lutgard C.
- US Patent Document 6,402,795
Preparation and ionic conductivity of Li7P3S11−z glass-ceramic electrolytes
journal, October 2010
- Hayashi, Akitoshi; Minami, Keiichi; Ujiie, Satoshi
- Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49, p. 2670-2673
Ionically conductive glasses based on SiS2
journal, August 1989
- Kennedy, J. H.
- Materials Chemistry and Physics, Vol. 23, Issue 1-2
High energy density aqueous lithium/air-battery cells
patent, March 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,673,477
Cell containing alkali metal anode, cathode and alkali metal-metal-chalcogenide compound solid electrolyte
patent, June 1980
- Jacobson, Allan J.; Silbernagel, Bernard G.
- US Patent Document 4,208,474
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, September 2015
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 9,123,941
Solid State Battery and Method of Producing the Same
patent-application, February 2010
- Kimura, Kenji; Tatsumisago, Masahiro; Hayashi, Akitoshi
- US Patent Application 12/532546; 20100040952
Method for forming encapsulated lithium electrodes having glass protective layers
patent, April 2001
- Visco, Steven J.; Tsang, Floris Y.
- US Patent Document 6,214,061
Preparation and characterization of lithium ion-conducting oxysulfide glasses
journal, November 2000
- Minami, T.
- Solid State Ionics, Vol. 136-137, Issue 1-2
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,302
Sulfide Solid Electrolyte
patent-application, July 2012
- Tatsumisago, Masahiro; Hayashi, Akitoshi; Hama, Shigenori
- US Patent Application 13/389129; 20120189918
A thin-film solid-state microbattery
journal, April 1993
- Jones, Steven D.; Akridge, James R.
- Journal of Power Sources, Vol. 44, Issue 1-3
Electrical properties of lithium conductive silicon sulfide glasses prepared by twin roller quenching
journal, January 1986
- Pradel, A.; Ribes, M.
- Solid State Ionics, Vol. 18-19
Preparation and characterization of lithium ion conducting Li2S–P2S5–GeS2 glasses and glass-ceramics
journal, October 2010
- Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49
Electric cells and gas sensors using alkali ion conductive glass ceramic
patent, November 2001
- Fu, Jie
- US Patent Document 6,315,881
Thin film battery and method for making same
patent, August 1994
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,338,625
Ionically conductive sulfide-based lithium glasses
journal, August 1990
- Kennedy, John H.; Zhang, Zhengming; Eckert, Hellmut
- Journal of Non-Crystalline Solids, Vol. 123, Issue 1-3
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries
journal, June 2014
- Cao, Can; Li, Zhuo-Bin; Wang, Xiao-Liang
- Frontiers in Energy Research, Vol. 2
Substantially impervious lithium super ion conducting membranes
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,652,686
Compliant Seal Structures for Protected Active Metal Anodes
patent-application, January 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 14/811550; 20160028053
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
journal, July 2013
- Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Scientific Reports, Vol. 3, Issue 1
Complex Plane and 7Li NMR Studies of Arsenic Sulfide-Based Lithium Glasses
journal, January 1985
- Visco, Steven J.
- Journal of The Electrochemical Society, Vol. 132, Issue 7
Fast Li+ Ion Conduction in Li2O-Al2O3-TiO2-SiO2-P2O2 Glass-Ceramics
journal, July 1997
- Fu, Jie
- Journal of the American Ceramic Society, Vol. 80, Issue 7, p. 1901-1903
Substantially impervious lithium super ion conducting membranes
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,334,075
Catholytes for aqueous lithium/air battery cells
patent, February 2014
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,658,304
Solid electrolyte, method for preparing the same, and battery using the same
patent, September 2007
- Park, Young-sin; Lee, Jong-heun; Jin, Young-gu
- US Patent Document 7,273,682
Compliant seal structures for protected active metal anodes
patent, September 2015
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 9,130,198
Improved stability for the SiS2-P2S5-Li2S-LiI glass system
journal, September 1988
- Kennedy, John H.; Zhang, Zhengming
- Solid State Ionics, Vol. 28-30
Method for making an electrochemical cell
patent, October 1996
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,567,210
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, October 2007
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,282,295
Lithium battery with hermetically sealed anode
patent, April 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,691,444
Battery Unit
patent-application, March 2010
- Kimura, Kenji; Tatsumisago, Masahiro; Hayashi, Akitoshi
- US Patent Application 12/550447; 20100075209
Sulfide Solid Electrolyte Material and Lithium Solid State Battery
patent-application, June 2013
- Ohtomo, Takamasa; Kawamoto, Koji; Hama, Higenori
- US Patent Application 13/818495; 20130164631
Electrical properties of new glasses based on the Li2S–SiS2 system
journal, October 1999
- Bartholomew, Roger F.; Young, Dianna M.; Ellison, Adam J. G.
- Journal of Non-Crystalline Solids, Vol. 256-257, p. 242-247
Alkali ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, May 2007
- Fu, Jie
- US Patent Document 7,211,532
Compliant seal structures for protected active metal anodes
patent, November 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 7,824,806
Electrolyte for an electrochemical cell
patent, January 1997
- Bates, John B.; Dudney, Nancy J.
- US Patent Document 5,597,660
In situ formed ionically conductive membranes for protection of active metal anodes and battery cells
patent, February 2012
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,114,171
Solid state batteries using vitreous solid electrolytes
journal, January 1986
- Akridge, J.; Vourlis, H.
- Solid State Ionics, Vol. 18-19
Active metal / aqueous electrochemical cells and systems
patent, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,048,571
Compliant seal structures for protected active metal anodes
patent, November 2011
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,048,570
Ionically conductive composites for protection of active metal anodes
patent, October 2007
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,282,296
Method for Producing Solid Electrolyte Material-containing Sheet
patent-application, July 2012
- Nakamoto, Hirofumi; Ueno, Yukiyoshi; Hama, Shigenori
- US Patent Application 12/673131; 20120177997
Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof
patent-application, July 2015
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Application 14/657695; 20150214555
Protected lithium electrodes having tape cast ceramic and glass-ceramic membranes
patent, September 2015
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 9,136,568
Preparation and Structure of Lithium-Ion-Conducting Mixed-Anion Glasses in the System LiBO2-LiBS2
journal, September 1988
- Tatsumisago, Masahiro; Yoneda, Kazuya; Minami, Tsutomu
- Journal of the American Ceramic Society, Vol. 71, Issue 9
Lithium cell having a solid electrolyte constituted by a conductive vitreous compound
patent, October 1984
- Gabano, Jean-Paul; Duchange, Jean-Pierre
- US Patent Document 4,478,920
Lithium ion conductive glass-ceramics and electric cells and gas sensors using the same
patent, February 2000
- Fu, Jie
- US Patent Document 6,030,909
Protected active metal electrode and battery cell with ionically conductive protective architecture
patent, October 2012
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,293,398
Advanced Lithium Ion Batteries Based on Solid State Protected Lithium Electrodes
patent-application, December 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Application 15/149012; 20160351878
Mechanochemical synthesis of lithium ion conducting glasses and glass–ceramics in the system Li2S–P–S
journal, October 2005
- Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi
- Solid State Ionics, Vol. 176, Issue 31-34
Ionically conductive membranes for protection of active metal anodes and battery cells
patent, June 2008
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,390,591
Lithium ion conductive solid electrolyte and method for manufacturing the same
patent-application, April 2007
- Inda, Yasushi
- US Patent Application 11/453919; 20070087269
Rechargeable lithium battery for use in applications requiring a low to high power output
patent, October 1996
- Bates, John B.
- US Patent Document 5,569,520
Fast Li+ ion transport in iodine-thioborate glasses
journal, August 1984
- Burckhardt, W.; Makyta, M.; Levasseur, A.
- Materials Research Bulletin, Vol. 19, Issue 8
Composite solid electrolyte for protection of active metal anodes
patent, May 2012
- Visco, Steven J.; DeJonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,182,943
Crystalline solid lithium cation conductive electrolyte
patent, August 1984
- Akridge, James R.
- US Patent Document 4,465,745
Protective composite battery separator and electrochemical device component with red phosphorus
patent, November 2010
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 7,838,144
Vitreous solid lithium cation conductive electrolyte
patent, August 1984
- Akridge, James R.
- US Patent Document 4,465,746
Protected lithium electrodes based on sintered ceramic or glass ceramic membranes
patent, July 2014
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 8,778,522
Superionic conduction in Li 2 S - P 2 S 5 - LiI - glasses
journal, October 1981
- Mercier, René; Malugani, Jean-Pierre; Fahys, Bernard
- Solid State Ionics, Vol. 5
Protected Active Metal Electrode and Battery Cell Structures with Non-Aqueous Interlayer Architecture
patent-application, January 2016
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Application 14/809083; 20160028063
All-solid-state lithium secondary batteries using the 75Li2S·25P2S5 glass and the 70Li2S·30P2S5 glass–ceramic as solid electrolytes
journal, July 2013
- Ohtomo, Takamasa; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Journal of Power Sources, Vol. 233
Positive-Electrode Active Material Particle for All-Solid Battery and Method for Production Thereof
patent-application, March 2014
- Uchiyama, Takayuki
- US Patent Application 14/116253; 20140072875
Battery Cells with Lithium Ion Conducting Tape-cast Ceramic, Glass and Glass-ceramic Membranes
patent-application, November 2015
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Application 14/815672; 20150340720
Mechanochemical synthesis of amorphous solid electrolytes using SiS2 and various lithium compounds
journal, November 2004
- Hayashi, A.
- Solid State Ionics, Vol. 175, Issue 1-4
Electrical and electrochemical properties of Li2S–P2S5–P2O5 glass–ceramic electrolytes
journal, August 2005
- Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi
- Journal of Power Sources, Vol. 146, Issue 1-2, p. 715-718
Solid State Battery
patent-application, May 2018
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 15/726302; 20180131040
Solid-state Laminate Electrode Assemblies and Methods of Making
patent-application, November 2017
- Visco, Steven J.; Nimon, Vitaliy; Ian, Wogan
- US Patent Application 15/592102; 20170331156
Thin-film rechargeable lithium batteries
journal, March 1995
- Bates, J. B.; Dudney, N. J.; Lubben, D. C.
- Journal of Power Sources, Vol. 54, Issue 1, p. 58-62
Electrical properties of amorphous lithium electrolyte thin films
journal, July 1992
- Bates, J. B.; Dudney, N. J.; Gruzalski, G. R.
- Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654
Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries
journal, March 2013
- Tatsumisago, Masahiro; Nagao, Motohiro; Hayashi, Akitoshi
- Journal of Asian Ceramic Societies, Vol. 1, Issue 1
Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof
patent-application, December 2017
- Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy
- US Patent Application 15/582343; 20170365853
Protective lithium ion conducting ceramic coating for lithium metal anodes and associate method
patent, May 1994
- Bates, John B.
- US Patent Document 5,314,765
Stabilized anode for lithium-polymer batteries
patent, October 1999
- Skotheim, Terje A.; Soloveichik, Grigorii Lev; Gavrilov, Alexei B.
- US Patent Document 5,961,672
Preparation of Li2S-P2S5 Amorphous Solid Electrolytes by Mechanical Milling
journal, February 2001
- Hayashi, Akitoshi; Hama, Shigenori; Morimoto, Hideyuki
- Journal of the American Ceramic Society, Vol. 84, Issue 2
Methods of Making and Inspecting a Web of Vitreous Lithium Sulfide Separator Sheet and LIthium Electrode Assemblies
patent-application, August 2017
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Application 15/380989; 20170229731
Electrode Active Material Layer, All Solid State battery, Manufacturing Method for Electrode Active Material Layer, and Manufacturing Method for All Solid State Battery
patent-application, March 2011
- Kamiya, Masato; Ueno, Yukiyoshi; Hama, Shigenori
- US Patent Application 12/877382; 20110065007
Substituted lithium orthosilicates and solid electrolytes therefrom
patent, August 1977
- Shannon, Robert D.; Taylor, Barry Edward
- US Patent Document 4,042,482
Protected lithium electrodes having a polymer electrolyte interlayer and battery cells thereof
patent, August 2013
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 8,501,339
Active metal/aqueous electrochemical cells and systems
patent, June 2012
- Visco, Steven J.; Nimon, Yevgeniy S.
- US Patent Document 8,202,649
Advanced lithium ion batteries based on solid state protected lithium electrodes
patent, June 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 9,362,538
Ionically conductive composites for protection of active metal anodes
patent-application, March 2008
- Visco, Steven; Nimon, Yevgeniy; Katz, Bruce
- US Patent Application 11/823847; 20080057399
Electrical and electrochemical properties of glass–ceramic electrolytes in the systems Li2S–P2S5–P2S3 and Li2S–P2S5–P2O5
journal, June 2011
- Minami, Keiichi; Hayashi, Akitoshi; Ujiie, Satoshi
- Solid State Ionics, Vol. 192, Issue 1
Lithium anodes for electrochemical cells
patent-application, January 2002
- Skotheim, Terje A.; Sheehan, Christopher J.; Mikhaylik, Yuriy V.
- US Patent Application 09/864890; 20020012846
Polymer adhesive seals for protected anode architectures
patent, March 2012
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,129,052
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5
journal, December 1997
- Fu, J.
- Solid State Ionics, Vol. 104, Issue 3-4
Vitreous materials with ionic conductivity, the preparation of same and the electrochemical applications thereof
patent, April 1985
- Carette, Brigitte; Kone, Ali; Souquet, Jean-Louis
- US Patent Document 4,513,070
Catholytes for aqueous lithium/air battery cells
patent, December 2012
- Visco, Steven J.; De Jonghe, Lutgard C.; Nimon, Yevgeniy S.
- US Patent Document 8,323,820
Mechanochemical synthesis of Li2S–P2S5 glass electrolytes with lithium salts
journal, October 2010
- Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro
- Solid State Ionics, Vol. 181, Issue 33-34
Sulfide Solid Electrolyte Material, Lithium Solid-State Battery and Method for Producing Sulfide Solid Electrolyte Material
patent-application, May 2014
- Ohtomo, Takamasa; Kawamoto, Koji; Hama, Shigenori
- US Patent Application 14/130105; 20140141341
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent, November 2010
- Visco, Steven J.; Katz, Bruce D.; Nimon, Yevgeniy S.
- US Patent Document 7,829,212
Sulfide-based lithium-ion-conducting solid electrolyte glass, all-solid lithium secondary battery, and method for manufacturing all-solid lithium secondary battery
patent, July 2014
- Shinohara, Yuji; Kawase, Takeo; Kondo, Shigeo
- US Patent Document 8,778,543
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5
journal, April 1997
- Fu, Jie
- Solid State Ionics, Vol. 96, Issue 3-4
Membranes in Lithium Ion Batteries
journal, July 2012
- Yang, Min; Hou, Junbo
- Membranes, Vol. 2, Issue 3, p. 367-383
Sulfide Solid Electrolyte Glass, Lithium Solid State Battery and Producing Method of Sulfide Solid Electrolyte Glass
patent-application, October 2013
- Hama, Shigenori; Ohtomo, Takamasa; Kato, Yuki
- US Patent Application 13/814364; 20130288134
Formation of superionic crystals from mechanically milled Li2S–P2S5 glasses
journal, February 2003
- Hayashi, Akitoshi; Hama, Shigenori; Minami, Tsutomu
- Electrochemistry Communications, Vol. 5, Issue 2
Lithium battery cell with protective membrane having a garnet like structure
patent, March 2016
- Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.
- US Patent Document 9,287,573
Fabrication of electrode–electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes
journal, January 2011
- Kitaura, Hirokazu; Hayashi, Akitoshi; Ohtomo, Takamasa
- J. Mater. Chem., Vol. 21, Issue 1
Complex Plane and 7Li NMR Studies of Highly Conductive Sulfide-Based Lithium Glasses
journal, January 1985
- Visco, Steven J.
- Journal of The Electrochemical Society, Vol. 132, Issue 4
Isostatic compression method for producing solid state electrochemical cells
patent, October 1984
- Akridge, James R.; Vourlis, Harry
- US Patent Document 4,477,545
Lithium/sulfur battery with hermetically sealed anode
patent, May 2013
- Visco, Steven J.; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.
- US Patent Document 8,445,136
Electra-optical device including a nitrogen containing electrolyte
patent, October 1995
- Bates, John B.; Dudney, Nancy J.; Gruzalski, Greg R.
- US Patent Document 5,455,126
Protected Lithium Electrodes Having A Porous Electrolyte Interlayer And Associated Battery Cells
patent-application, June 2014
- Visco, Steven; Katz, Bruce; Nimon, Yevgeniy
- US Patent Application 14/156267; 20140170465