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Title: Zeolites for separation of ethanol and water

Abstract

A process for separating ethanol from a mixture including ethanol and water comprises contacting the mixture with a sorbent or membrane including one or more zeolites having a high adsorption selectivity toward ethanol over water, wherein at least a fraction of the ethanol from the mixture is adsorbed by the sorbent or membrane and an unadsorbed portion of the mixture forms a raffinate having a lower concentration of ethanol than the mixture. The process further includes releasing adsorbed ethanol from the sorbent or membrane as a retentate or a permeant to produce an ethanol extract having a higher concentration of ethanol than the mixture.

Inventors:
; ;
Issue Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1469338
Patent Number(s):
10039999
Application Number:
15/327,722
Assignee:
Siepmann, Joern Ilja
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
DOE Contract Number:  
FG02-12ER16362; SC0008688
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Jul 22
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS

Citation Formats

Siepmann, Joern Ilja, Bai, Peng, and Tsapatsis, Michael. Zeolites for separation of ethanol and water. United States: N. p., 2018. Web.
Siepmann, Joern Ilja, Bai, Peng, & Tsapatsis, Michael. Zeolites for separation of ethanol and water. United States.
Siepmann, Joern Ilja, Bai, Peng, and Tsapatsis, Michael. Tue . "Zeolites for separation of ethanol and water". United States. https://www.osti.gov/servlets/purl/1469338.
@article{osti_1469338,
title = {Zeolites for separation of ethanol and water},
author = {Siepmann, Joern Ilja and Bai, Peng and Tsapatsis, Michael},
abstractNote = {A process for separating ethanol from a mixture including ethanol and water comprises contacting the mixture with a sorbent or membrane including one or more zeolites having a high adsorption selectivity toward ethanol over water, wherein at least a fraction of the ethanol from the mixture is adsorbed by the sorbent or membrane and an unadsorbed portion of the mixture forms a raffinate having a lower concentration of ethanol than the mixture. The process further includes releasing adsorbed ethanol from the sorbent or membrane as a retentate or a permeant to produce an ethanol extract having a higher concentration of ethanol than the mixture.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 07 00:00:00 EDT 2018},
month = {Tue Aug 07 00:00:00 EDT 2018}
}

Works referenced in this record:

Membrane for liquid mixture separation
patent, September 1996


Preparation of laser deposited oriented films and membranes
patent, September 2001


Process for Production of Zeolite Film
patent-application, September 2008


Method of Separating Liquid Mixture
patent-application, September 2008


High Performance Mixed Matrix Membranes Incorporating at Least Two Kinds of Molecular Sieves
patent-application, May 2009


Mixed Matrix Membranes Containing Ion-Exchanged Molecular Sieves
patent-application, January 2010


Microporous UZM-5 Inorganic Zeolite Membranes for Gas, Vapor, and Liquid Separations
patent-application, September 2012