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Title: Nickel hydroxide positive electrode for alkaline rechargeable battery

Abstract

Certain nickel hydroxide active cathode materials for use in alkaline rechargeable batteries are capable of transferring >1.3 electrons per Ni atom under reversible electrochemical conditions. The specific capacity of the nickel hydroxide active materials is for example .gtoreq.325 mAh/g. The cathode active materials exhibit an additional discharge plateau near 0.8 V vs. a metal hydride (MH) anode. Ni in an oxidation state of less than 2, such as Ni.sup.1+, is able to participate in electrochemical reactions when using the present cathode active materials. It is possible that up to 2.3 electrons, up to 2.5 electrons or more may be transferred per Ni atom under electrochemical conditions.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
BASF Corporation, Florham Park, NJ (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1422741
Patent Number(s):
9899676
Application Number:
14/614,838
Assignee:
BASF Corporation (Florham Park, NJ)
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AR0000386
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Feb 05
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Young, Kwo, Wang, Lixin, Mays, William, Reichman, Benjamin, Chao-Ian, Hu, Wong, Diana, and Nei, Jean. Nickel hydroxide positive electrode for alkaline rechargeable battery. United States: N. p., 2018. Web.
Young, Kwo, Wang, Lixin, Mays, William, Reichman, Benjamin, Chao-Ian, Hu, Wong, Diana, & Nei, Jean. Nickel hydroxide positive electrode for alkaline rechargeable battery. United States.
Young, Kwo, Wang, Lixin, Mays, William, Reichman, Benjamin, Chao-Ian, Hu, Wong, Diana, and Nei, Jean. Tue . "Nickel hydroxide positive electrode for alkaline rechargeable battery". United States. https://www.osti.gov/servlets/purl/1422741.
@article{osti_1422741,
title = {Nickel hydroxide positive electrode for alkaline rechargeable battery},
author = {Young, Kwo and Wang, Lixin and Mays, William and Reichman, Benjamin and Chao-Ian, Hu and Wong, Diana and Nei, Jean},
abstractNote = {Certain nickel hydroxide active cathode materials for use in alkaline rechargeable batteries are capable of transferring >1.3 electrons per Ni atom under reversible electrochemical conditions. The specific capacity of the nickel hydroxide active materials is for example .gtoreq.325 mAh/g. The cathode active materials exhibit an additional discharge plateau near 0.8 V vs. a metal hydride (MH) anode. Ni in an oxidation state of less than 2, such as Ni.sup.1+, is able to participate in electrochemical reactions when using the present cathode active materials. It is possible that up to 2.3 electrons, up to 2.5 electrons or more may be transferred per Ni atom under electrochemical conditions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 20 00:00:00 EST 2018},
month = {Tue Feb 20 00:00:00 EST 2018}
}

Works referenced in this record:

Composite positive electrode material and method for making same
patent-application, September 2001


Beta to gamma phase cycleable electrochemically active nickel hydroxide material
patent, May 1999


Electrochemical and Spectroscopic Evidence on the Participation of Quadrivalent Nickel in the Nickel Hydroxide Redox Reaction
journal, January 1989


Phase Stability of Nickel Hydroxides and Oxyhydroxides
journal, January 2006


Active materials for the positive electrode in alkaline storage batteries
patent, March 2000


Structurally modified nickel hydroxide material and method for making same
patent, July 2000