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Title: Electrochemical ion separation in molten salts

Abstract

A purification method that uses ion-selective ceramics to electrochemically filter waste products from a molten salt. The electrochemical method uses ion-conducting ceramics that are selective for the molten salt cations desired in the final purified melt, and selective against any contaminant ions. The method can be integrated into a slightly modified version of the electrochemical framework currently used in pyroprocessing of nuclear wastes.

Inventors:
; ; ; ; ; ;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1414407
Patent Number(s):
9847149
Application Number:
15/054,766
Assignee:
National Technology & Engineering Solutions of Sandia, LLC (Albuquerque, NM)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Feb 26
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Spoerke, Erik David, Ihlefeld, Jon, Waldrip, Karen, Wheeler, Jill S., Brown-Shaklee, Harlan James, Small, Leo J., and Wheeler, David R. Electrochemical ion separation in molten salts. United States: N. p., 2017. Web.
Spoerke, Erik David, Ihlefeld, Jon, Waldrip, Karen, Wheeler, Jill S., Brown-Shaklee, Harlan James, Small, Leo J., & Wheeler, David R. Electrochemical ion separation in molten salts. United States.
Spoerke, Erik David, Ihlefeld, Jon, Waldrip, Karen, Wheeler, Jill S., Brown-Shaklee, Harlan James, Small, Leo J., and Wheeler, David R. Tue . "Electrochemical ion separation in molten salts". United States. https://www.osti.gov/servlets/purl/1414407.
@article{osti_1414407,
title = {Electrochemical ion separation in molten salts},
author = {Spoerke, Erik David and Ihlefeld, Jon and Waldrip, Karen and Wheeler, Jill S. and Brown-Shaklee, Harlan James and Small, Leo J. and Wheeler, David R.},
abstractNote = {A purification method that uses ion-selective ceramics to electrochemically filter waste products from a molten salt. The electrochemical method uses ion-conducting ceramics that are selective for the molten salt cations desired in the final purified melt, and selective against any contaminant ions. The method can be integrated into a slightly modified version of the electrochemical framework currently used in pyroprocessing of nuclear wastes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 19 00:00:00 EST 2017},
month = {Tue Dec 19 00:00:00 EST 2017}
}

Works referenced in this record:

Method for electrochemically producing an alkali metal from an aqueous solution
patent, August 2004


Apparatus and system for refining sodium
patent-application, June 2002


Solid electrolyte thermoelectrochemical system
patent-application, June 2006


Ion Conductor Having a Garnet Structure
patent-application, August 2010


Apparatus and Method of Producing Metal in a Nasicon Electrolytic Cell
patent-application, January 2014