Electrolytes for magnesium electrochemical cells
Abstract
An electrochemical cell includes a high voltage cathode configured to operate at 1.5 volts or greater; an anode including Mg.sup.0; and an electrolyte including an ether solvent and a magnesium salt; wherein: a concentration of the magnesium salt in the ether is 1 M or greater.
- Inventors:
- Issue Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1368190
- Patent Number(s):
- 9698448
- Application Number:
- 14/690,961
- Assignee:
- UCHICAGO ARGONNE, LLC
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC02-06CH11357
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2015 Apr 20
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Burrell, Anthony K., Sa, Niya, Proffit, Danielle Lee, Lipson, Albert, Liao, Chen, Vaughey, John T., and Ingram, Brian J. Electrolytes for magnesium electrochemical cells. United States: N. p., 2017.
Web.
Burrell, Anthony K., Sa, Niya, Proffit, Danielle Lee, Lipson, Albert, Liao, Chen, Vaughey, John T., & Ingram, Brian J. Electrolytes for magnesium electrochemical cells. United States.
Burrell, Anthony K., Sa, Niya, Proffit, Danielle Lee, Lipson, Albert, Liao, Chen, Vaughey, John T., and Ingram, Brian J. Tue .
"Electrolytes for magnesium electrochemical cells". United States. https://www.osti.gov/servlets/purl/1368190.
@article{osti_1368190,
title = {Electrolytes for magnesium electrochemical cells},
author = {Burrell, Anthony K. and Sa, Niya and Proffit, Danielle Lee and Lipson, Albert and Liao, Chen and Vaughey, John T. and Ingram, Brian J.},
abstractNote = {An electrochemical cell includes a high voltage cathode configured to operate at 1.5 volts or greater; an anode including Mg.sup.0; and an electrolyte including an ether solvent and a magnesium salt; wherein: a concentration of the magnesium salt in the ether is 1 M or greater.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 04 00:00:00 EDT 2017},
month = {Tue Jul 04 00:00:00 EDT 2017}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
High Voltage Rechargeable Magnesium Batteries Having A Non-Aqueous Electrolyte
patent-application, September 2013
- Doe, Robert Ellis; Lane, George Hamilton
- US Patent Application 13/803321; 20130252112
Layered Materials With Improved Magnesium Intercalation For Rechargeable Magnesium Ion Cells
patent-application, October 2013
- Doe, Robert Ellis; Downie, Craig Michael; Fischer, Christopher
- US Patent Application 13/794551; 20130260238
Electrolyte For Magnesium Secondary Battery And Preparation Method Thereof
patent-application, May 2014
- Chung, Kyung Yoon; Cho, Bryung Won; Lee, Joong Kee
- US Patent Application 13/870439; 20140141324
Non-Aqueous Electrolyte For Rechargeable Magnesium Ion Cell
patent-application, August 2014
- Jilek, Robert; Eaglesham, David; Doe, Robert
- US Patent Application 14/143898; 20140220450
Electrolyte Solution, Method Of Preparing The Same, And Magnesium Battery Including The Electrolyte Solution
patent-application, May 2015
- Roy, Basab; Kim, Dong-young; Lim, Youn-hee
- US Patent Application 14/254998; 20150140450
Prototype systems for rechargeable magnesium batteries
journal, October 2000
- Aurbach, D.; Lu, Z.; Schechter, A.
- Nature, Vol. 407, Issue 6805, p. 724-727
Effect of Electrolytic Properties of a Magnesium Organohaloaluminate Electrolyte on Magnesium Deposition
journal, December 2013
- Benmayza, Aadil; Ramanathan, Mayandi; Arthur, Timothy S.
- The Journal of Physical Chemistry C, Vol. 117, Issue 51, p. 26881-26888
Solid-State Rechargeable Magnesium Batteries
journal, April 2003
- Chusid, O.; Gofer, Y.; Gizbar, H.
- Advanced Materials, Vol. 15, Issue 78, p. 627-630
Novel, electrolyte solutions comprising fully inorganic salts with high anodic stability for rechargeable magnesium batteries
journal, January 2014
- Doe, Robert E.; Han, Ruoban; Hwang, Jaehee
- Chemical Communications, Vol. 50, Issue 2, p. 243-245
In Situ X-Ray Absorption Spectroscopy Characterization of V2O5 Xerogel Cathodes upon Lithium Intercalation
journal, January 1999
- Giorgetti, Marco; Passerini, Stefano; Smyrl, William H.
- Journal of The Electrochemical Society, Vol. 146, Issue 7, p. 2387-2392
Magnesium(II) Bis(trifluoromethane sulfonyl) Imide-Based Electrolytes with Wide Electrochemical Windows for Rechargeable Magnesium Batteries
journal, March 2014
- Ha, Se-Young; Lee, Yong-Won; Woo, Sang Won
- ACS Applied Materials & Interfaces, Vol. 6, Issue 6, p. 4063-4073
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013
- Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
- APL Materials, Vol. 1, Issue 1
The effects of cations and anions on the ionic conductivity of poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene] doped with lithium and magnesium salts of trifluoromethanesulfonate and bis(trifluoromethanesulfonyl)imidate
journal, December 2010
- Lee, David K.; Allcock, Harry R.
- Solid State Ionics, Vol. 181, Issue 39-40
The electrodeposition of magnesium using solutions of organomagnesium halides, amidomagnesium halides and magnesium organoborates
journal, September 2000
- Liebenow, C.; Yang, Z.; Lobitz, P.
- Electrochemistry Communications, Vol. 2, Issue 9
Study of the electrochemical deposition of Mg in the atomic level: Why it prefers the non-dendritic morphology
journal, August 2012
- Ling, Chen; Banerjee, Debasish; Matsui, Masaki
- Electrochimica Acta, Vol. 76
On the electrochemical behavior of magnesium electrodes in polar aprotic electrolyte solutions
journal, May 1999
- Lu, Z.; Schechter, A.; Moshkovich, M.
- Journal of Electroanalytical Chemistry, Vol. 466, Issue 2, p. 203-217
Study on electrochemically deposited Mg metal
journal, August 2011
- Matsui, Masaki
- Journal of Power Sources, Vol. 196, Issue 16
Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms
journal, January 2014
- McOwen, Dennis W.; Seo, Daniel M.; Borodin, Oleg
- Energy Environ. Sci., Vol. 7, Issue 1
Magnesium Borohydride: From Hydrogen Storage to Magnesium Battery
journal, August 2012
- Mohtadi, Rana; Matsui, Masaki; Arthur, Timothy S.
- Angewandte Chemie International Edition, Vol. 51, Issue 39, p. 9780-9783
Electrochemical Insertion of Magnesium into Hydrated Vanadium Bronzes
journal, January 1995
- Novák, Petr; Scheifele, Werner; Joho, Felix
- Journal of The Electrochemical Society, Vol. 142, Issue 8, p. 2544-2550
Magnesium insertion electrodes for rechargeable nonaqueous batteries — a competitive alternative to lithium?
journal, September 1999
- Novák, Petr; Imhof, Roman; Haas, Otto
- Electrochimica Acta, Vol. 45, Issue 1-2, p. 351-367
In situ Scanning Electron Microscopy (SEM) observation of interfaces within plastic lithium batteries
journal, November 1998
- Orsini, F.; Du Pasquier, A.; Beaudoin, B.
- Journal of Power Sources, Vol. 76, Issue 1
Hollandite-type TiO2: a new negative electrode material for sodium-ion batteries
journal, January 2014
- Pérez-Flores, J. C.; Baehtz, C.; Kuhn, A.
- Journal of Materials Chemistry A, Vol. 2, Issue 6, p. 1825-1833
The Coupling between Stability and Ion Pair Formation in Magnesium Electrolytes from First-Principles Quantum Mechanics and Classical Molecular Dynamics
journal, February 2015
- Rajput, Nav Nidhi; Qu, Xiaohui; Sa, Niya
- Journal of the American Chemical Society, Vol. 137, Issue 9, p. 3411-3420
Passive films on magnesium anodes in primary batteries
journal, March 1988
- Ratnakumar, B. V.
- Journal of Applied Electrochemistry, Vol. 18, Issue 2, p. 268-279
The challenge of developing rechargeable magnesium batteries
journal, May 2014
- Shterenberg, Ivgeni; Salama, Michael; Gofer, Yossi
- MRS Bulletin, Vol. 39, Issue 5
Vanadium K edge XANES of synthetic and natural basaltic glasses and application to microscale oxygen barometry
journal, May 2005
- Sutton, S. R.; Karner, J.; Papike, J.
- Geochimica et Cosmochimica Acta, Vol. 69, Issue 9
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
-edge absorption spectra of selected vanadium compounds
journal, November 1984
- Wong, J.; Lytle, F. W.; Messmer, R. P.
- Physical Review B, Vol. 30, Issue 10
Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme–Lithium Salt Equimolar Complexes
journal, August 2011
- Yoshida, Kazuki; Nakamura, Megumi; Kazue, Yuichi
- Journal of the American Chemical Society, Vol. 133, Issue 33, p. 13121-13129
Intercalation of Mg in V2O5
journal, September 1987
- Yu, Wen-hai; Wang, Da-zhi; Zhu, Bin
- Solid State Communications, Vol. 63, Issue 11
Electrochemical insertion of magnesium ions into V2O5 from aprotic electrolytes with varied water content
journal, October 2004
- Yu, Long; Zhang, Xiaogang
- Journal of Colloid and Interface Science, Vol. 278, Issue 1