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Title: Electrochemical cell structure including an ionomeric barrier

Abstract

An apparatus includes an electrochemical half-cell comprising: an electrolyte, an anode; and an ionomeric barrier positioned between the electrolyte and the anode. The anode may comprise a multi-electron vanadium phosphorous alloy, such as VP.sub.x, wherein x is 1-5. The electrochemical half-cell is configured to oxidize the vanadium and phosphorous alloy to release electrons. A method of mitigating corrosion in an electrochemical cell includes disposing an ionomeric barrier in a path of electrolyte or ion flow to an anode and mitigating anion accumulation on the surface of the anode.

Inventors:
;
Issue Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1364412
Patent Number(s):
9685684
Application Number:
13/943,566
Assignee:
National Technology & Engineering Solutions of Sandia, LLC
Patent Classifications (CPCs):
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC04-94AL85000
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Jul 16
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Lambert, Timothy N., and Hibbs, Michael. Electrochemical cell structure including an ionomeric barrier. United States: N. p., 2017. Web.
Lambert, Timothy N., & Hibbs, Michael. Electrochemical cell structure including an ionomeric barrier. United States.
Lambert, Timothy N., and Hibbs, Michael. Tue . "Electrochemical cell structure including an ionomeric barrier". United States. https://www.osti.gov/servlets/purl/1364412.
@article{osti_1364412,
title = {Electrochemical cell structure including an ionomeric barrier},
author = {Lambert, Timothy N. and Hibbs, Michael},
abstractNote = {An apparatus includes an electrochemical half-cell comprising: an electrolyte, an anode; and an ionomeric barrier positioned between the electrolyte and the anode. The anode may comprise a multi-electron vanadium phosphorous alloy, such as VP.sub.x, wherein x is 1-5. The electrochemical half-cell is configured to oxidize the vanadium and phosphorous alloy to release electrons. A method of mitigating corrosion in an electrochemical cell includes disposing an ionomeric barrier in a path of electrolyte or ion flow to an anode and mitigating anion accumulation on the surface of the anode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 20 00:00:00 EDT 2017},
month = {Tue Jun 20 00:00:00 EDT 2017}
}

Works referenced in this record:

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  • Hibbs, Michael R.; Hickner, Michael A.; Coughlin, E. Bryan
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 51, Issue 24, p. 1736-1742
  • https://doi.org/10.1002/polb.23149

Vanadium diphosphides as negative electrodes for secondary Li-ion batteries
journal, October 2007


Reversible air electrodes integrated with an anion-exchange membrane for secondary air batteries
journal, January 2011