High performance, durable polymers including poly(phenylene)

Fujimoto, Cy; Pratt, Harry; Anderson, Travis Mark

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Title: High performance, durable polymers including poly(phenylene)

Abstract

The present invention relates to functionalized polymers including a poly(phenylene) structure. In some embodiments, the polymers and copolymers of the invention include a highly localized concentration of acidic moieties, which facilitate proton transport and conduction through networks formed from these polymers. In addition, the polymers can include functional moieties, such as electron-withdrawing moieties, to protect the polymeric backbone, thereby extending its durability. Such enhanced proton transport and durability can be beneficial for any high performance platform that employs proton exchange polymeric membranes, such as in fuel cells or flow batteries.

Inventors:: Fujimoto, Cy; Pratt, Harry; Anderson, Travis Mark

Issue Date:: Tue Feb 28 00:00:00 EST 2017

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1345386

Patent Number(s):: 9580541

Application Number:: 14/933,981

Assignee:: Sandia Corporation

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

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C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G2261/148 - Side-chains having aromatic units
C08G2261/312 - Non-condensed aromatic systems, e.g. benzene
C08G2261/46 - Diels-Alder reactions
C08G2261/80 - Functional group cleavage, e.g. removal of side-chains or protective groups
C08G61/10 - only aromatic carbon atoms, e.g. polyphenylenes

Show less

DOE Contract Number:: AC04-94AL85000

Resource Type:: Patent

Resource Relation:: Patent File Date: 2015 Nov 05

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 25 ENERGY STORAGE

Citation Formats


                    Fujimoto, Cy, Pratt, Harry, and Anderson, Travis Mark. High performance, durable polymers including poly(phenylene).  United States: N. p., 2017. 
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                    Fujimoto, Cy, Pratt, Harry, & Anderson, Travis Mark. High performance, durable polymers including poly(phenylene).  United States.

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                    Fujimoto, Cy, Pratt, Harry, and Anderson, Travis Mark. Tue .  
        "High performance, durable polymers including poly(phenylene)".  United States.  https://www.osti.gov/servlets/purl/1345386.

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@article{osti_1345386,

  title        = {High performance, durable polymers including poly(phenylene)},

  author       = {Fujimoto, Cy and Pratt, Harry and Anderson, Travis Mark},

  abstractNote = {The present invention relates to functionalized polymers including a poly(phenylene) structure. In some embodiments, the polymers and copolymers of the invention include a highly localized concentration of acidic moieties, which facilitate proton transport and conduction through networks formed from these polymers. In addition, the polymers can include functional moieties, such as electron-withdrawing moieties, to protect the polymeric backbone, thereby extending its durability. Such enhanced proton transport and durability can be beneficial for any high performance platform that employs proton exchange polymeric membranes, such as in fuel cells or flow batteries.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Feb 28 00:00:00 EST 2017},

  month        = {Tue Feb 28 00:00:00 EST 2017}

}

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Similar Records

Title: High performance, durable polymers including poly(phenylene)

Abstract

Citation Formats

Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology patent, April 2006

Sulfonated polyphenylene polymers patent, November 2007

Anion-conducting polymer, composition, and membrane patent, September 2009

Epoxy-crosslinked sulfonated poly (phenylene) copolymer proton exchange membranes patent, October 2010

Anion-conducting polymer, composition, and membrane patent, December 2010

Hybrid membrane—PSA system for separating oxygen from air patent, January 2011

Poly(phenylene)-based anion exchange membrane patent, February 2011

Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes patent, February 2012

Advanced membrane electrode assemblies for fuel cells patent, July 2012

Anion exchange polymer electrolytes patent, July 2013

Anion exchange polymer electrolytes patent, September 2013

Functionalization of poly(phenylene) by the attachment of sidechains patent, August 2014

Anion exchange polymer electrolytes patent, June 2015

Poly(arylene)-based anion exchange polymer electrolytes patent, June 2015

Ionomer for alkaline fuel cell patent-application, September 2012

Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells journal, December 2012

Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s journal, July 2012

Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization: Synthesis and Physical Properties of a Novel Polyelectrolyte journal, June 2005

Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells journal, November 2009

Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations journal, August 2012

Transport in sulfonated poly(phenylene)s: Proton conductivity, permeability, and the state of water journal, May 2006

Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells journal, September 2013

Palladium-Catalyzed Phosphonation of Polyphenylsulfone journal, February 2003

Polymer Electrolyte Membranes Derived from New Sulfone Monomers with Pendent Sulfonic Acid Groups journal, December 2010

Synthesis and properties of sulfonated poly(phenylene sulfone)s without ether linkage by Diels–Alder reaction for PEMFC application journal, February 2014

Factors enabling high mobility of protons and water in perfluorosulfonate membranes under low hydration conditions journal, February 2014

Anion exchange membranes for alkaline fuel cells: A review journal, July 2011

Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application journal, November 2006

Carboxylated and Sulfonated Poly(arylene- co -arylene sulfone)s: Thermostable Polyelectrolytes for Fuel Cell Applications journal, September 2002

Structurally-Defined, Sulfo-Phenylated, Oligophenylenes and Polyphenylenes journal, September 2015

Evaluation of hydrogen and methanol fuel cell performance of sulfonated diels alder poly(phenylene) membranes journal, January 2010

Evaluation of Diels–Alder poly(phenylene) anion exchange membranes in all-vanadium redox flow batteries journal, June 2014

Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology
patent, April 2006

Sulfonated polyphenylene polymers
patent, November 2007

Anion-conducting polymer, composition, and membrane
patent, September 2009

Epoxy-crosslinked sulfonated poly (phenylene) copolymer proton exchange membranes
patent, October 2010

Anion-conducting polymer, composition, and membrane
patent, December 2010

Hybrid membrane—PSA system for separating oxygen from air
patent, January 2011

Poly(phenylene)-based anion exchange membrane
patent, February 2011

Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes
patent, February 2012

Advanced membrane electrode assemblies for fuel cells
patent, July 2012

Anion exchange polymer electrolytes
patent, July 2013

Anion exchange polymer electrolytes
patent, September 2013

Functionalization of poly(phenylene) by the attachment of sidechains
patent, August 2014

Anion exchange polymer electrolytes
patent, June 2015

Poly(arylene)-based anion exchange polymer electrolytes
patent, June 2015

Ionomer for alkaline fuel cell
patent-application, September 2012

Backbone stability of quaternized polyaromatics for alkaline membrane fuel cells
journal, December 2012

Vanadium redox flow battery efficiency and durability studies of sulfonated Diels Alder poly(phenylene)s
journal, July 2012

Ionomeric Poly(phenylene) Prepared by Diels−Alder Polymerization: Synthesis and Physical Properties of a Novel Polyelectrolyte
journal, June 2005

Synthesis and Characterization of Poly(phenylene)-Based Anion Exchange Membranes for Alkaline Fuel Cells
journal, November 2009

Alkaline stability of poly(phenylene)-based anion exchange membranes with various cations
journal, August 2012

Transport in sulfonated poly(phenylene)s: Proton conductivity, permeability, and the state of water
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Resonance Stabilized Perfluorinated Ionomers for Alkaline Membrane Fuel Cells
journal, September 2013

Palladium-Catalyzed Phosphonation of Polyphenylsulfone
journal, February 2003

Polymer Electrolyte Membranes Derived from New Sulfone Monomers with Pendent Sulfonic Acid Groups
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Synthesis and properties of sulfonated poly(phenylene sulfone)s without ether linkage by Diels–Alder reaction for PEMFC application
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Factors enabling high mobility of protons and water in perfluorosulfonate membranes under low hydration conditions
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Anion exchange membranes for alkaline fuel cells: A review
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Phosphonated and sulfonated polyhphenylsulfone membranes for fuel cell application
journal, November 2006

Carboxylated and Sulfonated Poly(arylene- co -arylene sulfone)s: Thermostable Polyelectrolytes for Fuel Cell Applications
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