Method of improving adhesion of carbon fibers with a polymeric matrix

Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

Advanced Search OptionsAdvanced Search queries use a traditional Term Search. For more info, see our FAQ.

All Fields:

Patent Title:

Abstract:

Assignee:

Inventor(s):

Patent Number:

Patent Classification (CPC):

All Classifications
A - human necessities
A01 - agriculture
A21 - baking
A22 - butchering
A23 - foods or foodstuffs
A24 - tobacco
A41 - wearing apparel
A42 - headwear
A43 - footwear
A44 - haberdashery
A45 - hand or travelling articles
A46 - brushware
A47 - furniture
A61 - medical or veterinary science
A62 - life-saving
A63 - sports
A99 - subject matter not otherwise provided for in this section
B - performing operations
B01 - physical or chemical processes or apparatus in general
B02 - crushing, pulverising, or disintegrating
B03 - separation of solid materials using liquids or using pneumatic tables or jigs
B04 - centrifugal apparatus or machines for carrying-out physical or chemical processes
B05 - spraying or atomising in general
B06 - generating or transmitting mechanical vibrations in general
B07 - separating solids from solids
B08 - cleaning
B09 - disposal of solid waste
B21 - mechanical metal-working without essentially removing material
B22 - casting
B23 - machine tools
B24 - grinding
B25 - hand tools
B26 - hand cutting tools
B27 - working or preserving wood or similar material
B28 - working cement, clay, or stone
B29 - working of plastics
B30 - presses
B31 - making articles of paper, cardboard or material worked in a manner analogous to paper
B32 - layered products
B33 - additive manufacturing technology
B41 - printing
B42 - bookbinding
B43 - writing or drawing implements
B44 - decorative arts
B60 - vehicles in general
B61 - railways
B62 - land vehicles for travelling otherwise than on rails
B63 - ships or other waterborne vessels
B64 - aircraft
B65 - conveying
B66 - hoisting
B67 - opening, closing {or cleaning} bottles, jars or similar containers
B68 - saddlery
B81 - microstructural technology
B82 - nanotechnology
B99 - subject matter not otherwise provided for in this section
C - chemistry
C01 - inorganic chemistry
C02 - treatment of water, waste water, sewage, or sludge
C03 - glass
C04 - cements
C05 - fertilisers
C06 - explosives
C07 - organic chemistry
C08 - organic macromolecular compounds
C09 - dyes
C10 - petroleum, gas or coke industries
C11 - animal or vegetable oils, fats, fatty substances or waxes
C12 - biochemistry
C13 - sugar industry
C14 - skins
C21 - metallurgy of iron
C22 - metallurgy
C23 - coating metallic material
C25 - electrolytic or electrophoretic processes
C30 - crystal growth
C40 - combinatorial technology
C99 - subject matter not otherwise provided for in this section
D - textiles
D01 - natural or man-made threads or fibres
D02 - yarns
D03 - weaving
D04 - braiding
D05 - sewing
D06 - treatment of textiles or the like
D07 - ropes
D10 - indexing scheme associated with sublasses of section d, relating to textiles
D21 - paper-making
D99 - subject matter not otherwise provided for in this section
E - fixed constructions
E01 - construction of roads, railways, or bridges
E02 - hydraulic engineering
E03 - water supply
E04 - building
E05 - locks
E06 - doors, windows, shutters, or roller blinds in general
E21 - earth drilling
E99 - subject matter not otherwise provided for in this section
F - mechanical engineering
F01 - machines or engines in general
F02 - combustion engines
F03 - machines or engines for liquids
F04 - positive - displacement machines for liquids
F05 - indexing schemes relating to engines or pumps in various subclasses of classes f01-f04
F15 - fluid-pressure actuators
F16 - engineering elements and units
F17 - storing or distributing gases or liquids
F21 - lighting
F22 - steam generation
F23 - combustion apparatus
F24 - heating
F25 - refrigeration or cooling
F26 - drying
F27 - furnaces
F28 - heat exchange in general
F41 - weapons
F42 - ammunition
F99 - subject matter not otherwise provided for in this section
G - physics
G01 - measuring
G02 - optics
G03 - photography
G04 - horology
G05 - controlling
G06 - computing
G07 - checking-devices
G08 - signalling
G09 - education
G10 - musical instruments
G11 - information storage
G12 - instrument details
G16 - information and communication technology [ict] specially adapted for specific application fields
G21 - nuclear physics
G99 - subject matter not otherwise provided for in this section
H - electricity
H01 - basic electric elements
H02 - generation
H03 - basic electronic circuitry
H04 - electric communication technique
H05 - electric techniques not otherwise provided for
H99 - subject matter not otherwise provided for in this section
Y - new / cross sectional technologies
Y02 - technologies or applications for mitigation or adaptation against climate change
Y04 - information or communication technologies having an impact on other technology areas
Y10 - technical subjects covered by former uspc

More Options ...

Title: Method of improving adhesion of carbon fibers with a polymeric matrix

Inventors:: Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

Issue Date:: Tue Jun 14 00:00:00 EDT 2016

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1257250

Patent Number(s):: 9365685

Application Number:: 13/406,732

Assignee:: UT-BATTELLE, LLC (Oak Ridge, TN)

Patent Classifications (CPCs):: C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS

Show more

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08J - WORKING-UP
C08J2333/04 - esters
C08J2363/00 - Characterised by the use of epoxy resins
C08J2463/00 - Characterised by the use of epoxy resins
C08J5/06 - using pretreated fibrous materials

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08L - COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
C08L63/10 - Epoxy resins modified by unsaturated compounds

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/249948 - Fiber is precoated
Y10T428/2918 - including free carbon or carbide or therewith [not as steel]

Show less

DOE Contract Number:: AC05-00OR22725

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Feb 28

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Vautard, Frederic, Ozcan, Soydan, and Paulauskas, Felix Leonard. Method of improving adhesion of carbon fibers with a polymeric matrix.  United States: N. p., 2016. 
        Web.

Copy to clipboard


                    Vautard, Frederic, Ozcan, Soydan, & Paulauskas, Felix Leonard. Method of improving adhesion of carbon fibers with a polymeric matrix.  United States.

Copy to clipboard


                    Vautard, Frederic, Ozcan, Soydan, and Paulauskas, Felix Leonard. Tue .  
        "Method of improving adhesion of carbon fibers with a polymeric matrix".  United States.  https://www.osti.gov/servlets/purl/1257250.

Copy to clipboard


                    
@article{osti_1257250,

  title        = {Method of improving adhesion of carbon fibers with a polymeric matrix},

  author       = {Vautard, Frederic and Ozcan, Soydan and Paulauskas, Felix Leonard},

  abstractNote = {},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Jun 14 00:00:00 EDT 2016},

  month        = {Tue Jun 14 00:00:00 EDT 2016}

}

Copy to clipboard

Patent:

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Plasma-graft polymerization of a monomer with double bonds onto the surface of carbon fiber and its adhesion to a vinyl ester resin
journal, September 2003

Yamada, Kenji; Yamane, Hirokazu; Kumada, Kiyoshi
Journal of Applied Polymer Science, Vol. 90, Issue 9, p. 2415-2419
https://doi.org/10.1002/app.12897

Plasma etching and plasma polymerization coating of carbon fibers. Part 1. Interfacial adhesion study
journal, January 2002

Kang, H. M.; Kim, N. I.; Yoon, T. H.
Journal of Adhesion Science and Technology, Vol. 16, Issue 13, p. 1809-1823
https://doi.org/10.1163/156856102320396157

Enhanced interfacial adhesion of carbon fibers to vinyl ester resin using poly(arylene ether phosphine oxide) coatings as adhesion promoters
journal, January 2000

Kim, Ick-Cheun; Yoon, Tae-Ho
Journal of Adhesion Science and Technology, Vol. 14, Issue 4, p. 545-559
https://doi.org/10.1163/156856100742735

Designed Interphase Regions in Carbon Fiber Reinforced Vinyl Ester Matrix Composites
journal, December 1999

Robertson, M. A. F.; Bump, M. B.; Verghese, K. E.
The Journal of Adhesion, Vol. 71, Issue 4, p. 395-416
https://doi.org/10.1080/00218469908014550

Fatigue performance of carbon fibre/vinyl ester composites: the effect of two dissimilar polymeric sizing agents
journal, July 1998

Broyles, N. S.; Verghese, K. N. E.; Davis, S. V.
Polymer, Vol. 39, Issue 15, p. 3417-3424
https://doi.org/10.1016/S0032-3861(97)10078-7

Radiation Curable Non-Gelled Michael Addition Reaction Products
patent, October 1974

Gaske, Joseph E.
US Patent Document 3844916
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/3844916

Sizing agent for carbon fibers
patent, November 1988

Saito, Makoto; Toki, Hiroshi; Miyazaki, Makoto
US Patent Document 4,781,947
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/4781947

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation
patent, August 1994

Grosse-Puppendahl, Thomas; Baron, Christian; Schmidt, Friedrich Georg
US Patent Document 5,338,789
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5338789

Epoxy acrylate resins and their uses
patent, October 1997

Motoshima, Toshihiro; Karasawa, Akio; Takuma, Keisuke
US Patent Document 5,677,398
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5677398

Aqueous, radiation-curable coating compositions
patent, January 2000

Reich, Wolfgang; Enenkel, Peter; Keil, Edmund
US Patent Document 6,011,078
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6011078

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent
patent, January 2000

McGrail, Patrick Terence; Jenkins, Stephen Derek; Carter, Jeffrey Thomas
US Patent Document 6,013,730
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6013730

Improving adhesion of acrylate resins
patent, December 2002

Reich, Wolfgang; Enenkel, Peter; Keil, Edmund
US Patent Document 6,500,878
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6500878

Covalently compatible in-mold coating compositions for use with epoxy
patent, October 2008

Mack, Patrick E.; Smith, Mitchell
US Patent Document 7,431,789
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7431789

Sizing Composition for Glass Yarns, The Glass Yarns Thus Obtained and Composite Materials Comprising Said Yarns
patent-application, June 2005

Moireau, Patrick
US Patent Application 10/496791; 20050119395
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050119395

Method for Enhancing Adherence of Carbon Fibers with Respect to an Organic Matrix
patent-application, October 2008

Defoort, Brigitte; Ponsaud, Philippe; Coqueret, Xavier
US Patent Application 12/065983; 20080255332
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20080255332

Adhesion Promoting Layer for Composite Assemblies
patent-application, March 2010

Harrington, Chris
12/598569; 20100068497
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100068497

Process for Improving the Adhesion of Carbon Fibers with Regard to an Organic Matrix
patent-application, April 2010

Schultz, Jacques; Nardin, Michel; Vautard, Frederic
US Patent Application 12/518354; 20100092695
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100092695

Similar Records in DOE Patents and OSTI.GOV collections:

Method of improving adhesion of carbon fibers with a polymeric matrix

Patent Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

A method of making a carbon fiber having on its surface a partially cured sizing agent, the method comprising covalently binding on the surface of said carbon fiber a sizing agent comprised of an epoxy resin, and partially curing said sizing agent by contact thereof with a curing agent such that at least a portion of epoxide groups remain uncrosslinked on said surface, which corresponds to a curing degree of epoxide groups of no more than about 0.6, and further comprising reacting at least a portion of said epoxide groups with a bifunctional molecule that contains first and second reactivemore » « less
Full Text Available
Method of improving adhesion of carbon fibers with a polymeric matrix

Patent Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

A method of making a solid composite containing carbon fibers embedded in a polymeric matrix, the method comprising admixing carbon fibers with a polymer precursor resin, and curing the polymer precursor resin to form a cured polymeric matrix that contains said carbon fibers embedded therein, wherein said carbon fibers have covalently bonded on their surfaces a partially cured epoxy-containing or amine-containing sizing agent, wherein at least a portion of epoxide groups or amine groups in the sizing agent are available as uncrosslinked epoxide groups or amine groups, which corresponds to a curing degree of epoxide groups or amine groups ofmore » no more than about 0.6. « less
Full Text Available
Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in a polymeric matrix

Patent Vautard, Frederic; Ozcan, Soydan

A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised ofmore » « less
Full Text Available
Multifunctional curing agents and their use in improving strength of composites containing carbon fibers embedded in polymeric matrix

Patent Vautard, Frederic; Ozcan, Soydan

A functionalized carbon fiber having covalently bound on its surface a sizing agent containing epoxy groups, at least some of which are engaged in covalent bonds with crosslinking molecules, wherein each of said crosslinking molecules possesses at least two epoxy-reactive groups and at least one free functional group reactive with functional groups of a polymer matrix in which the carbon fiber is to be incorporated, wherein at least a portion of said crosslinking molecules are engaged, via at least two of their epoxy-reactive groups, in crosslinking bonds between at least two epoxy groups of the sizing agent. Composites comprised ofmore » « less
Full Text Available
Solid composites containing polymeric matrix with carbon fibers embedded therein

Patent Vautard, Frederic; Ozcan, Soydan; Paulauskas, Felix Leonard

A functionalized carbon fiber having covalently bound on its surface a partially cured epoxy or amine-containing sizing agent, wherein at least a portion of epoxide or amine groups in the sizing agent are available as uncrosslinked epoxide or amine groups, which corresponds to a curing degree of epoxide or amine groups of no more than about 0.6. Composites comprised of these functionalized carbon fibers embedded in a polymeric matrix are also described. Methods for producing the functionalized carbon fibers and composites thereof are also described.
Full Text Available

Similar Records

Title: Method of improving adhesion of carbon fibers with a polymeric matrix

Citation Formats

Plasma-graft polymerization of a monomer with double bonds onto the surface of carbon fiber and its adhesion to a vinyl ester resin journal, September 2003

Plasma etching and plasma polymerization coating of carbon fibers. Part 1. Interfacial adhesion study journal, January 2002

Enhanced interfacial adhesion of carbon fibers to vinyl ester resin using poly(arylene ether phosphine oxide) coatings as adhesion promoters journal, January 2000

Designed Interphase Regions in Carbon Fiber Reinforced Vinyl Ester Matrix Composites journal, December 1999

Fatigue performance of carbon fibre/vinyl ester composites: the effect of two dissimilar polymeric sizing agents journal, July 1998

Radiation Curable Non-Gelled Michael Addition Reaction Products patent, October 1974

Sizing agent for carbon fibers patent, November 1988

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation patent, August 1994

Epoxy acrylate resins and their uses patent, October 1997

Aqueous, radiation-curable coating compositions patent, January 2000

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent patent, January 2000

Improving adhesion of acrylate resins patent, December 2002

Covalently compatible in-mold coating compositions for use with epoxy patent, October 2008

Sizing Composition for Glass Yarns, The Glass Yarns Thus Obtained and Composite Materials Comprising Said Yarns patent-application, June 2005

Method for Enhancing Adherence of Carbon Fibers with Respect to an Organic Matrix patent-application, October 2008

Adhesion Promoting Layer for Composite Assemblies patent-application, March 2010

Process for Improving the Adhesion of Carbon Fibers with Regard to an Organic Matrix patent-application, April 2010

Plasma-graft polymerization of a monomer with double bonds onto the surface of carbon fiber and its adhesion to a vinyl ester resin
journal, September 2003

Plasma etching and plasma polymerization coating of carbon fibers. Part 1. Interfacial adhesion study
journal, January 2002

Enhanced interfacial adhesion of carbon fibers to vinyl ester resin using poly(arylene ether phosphine oxide) coatings as adhesion promoters
journal, January 2000

Designed Interphase Regions in Carbon Fiber Reinforced Vinyl Ester Matrix Composites
journal, December 1999

Fatigue performance of carbon fibre/vinyl ester composites: the effect of two dissimilar polymeric sizing agents
journal, July 1998

Radiation Curable Non-Gelled Michael Addition Reaction Products
patent, October 1974

Sizing agent for carbon fibers
patent, November 1988

Fiber-reinforced polyphenylene ether molding compositions and process for their preparation
patent, August 1994

Epoxy acrylate resins and their uses
patent, October 1997

Aqueous, radiation-curable coating compositions
patent, January 2000

At least trifunctional epoxy resin reacted with solid rubber mixed with epoxy resin and curing agent
patent, January 2000

Improving adhesion of acrylate resins
patent, December 2002

Covalently compatible in-mold coating compositions for use with epoxy
patent, October 2008

Sizing Composition for Glass Yarns, The Glass Yarns Thus Obtained and Composite Materials Comprising Said Yarns
patent-application, June 2005

Method for Enhancing Adherence of Carbon Fibers with Respect to an Organic Matrix
patent-application, October 2008

Adhesion Promoting Layer for Composite Assemblies
patent-application, March 2010

Process for Improving the Adhesion of Carbon Fibers with Regard to an Organic Matrix
patent-application, April 2010