Methods for providing bond activation catalysts and related catalysts, systems, and methods
Abstract
Described herein are catalysts for activation of an R--H bond in a R--H substrate and related catalytic matrices, compositions, methods and systems.
- Inventors:
- Issue Date:
- Research Org.:
- California Institute of Technology (CalTech), Pasadena, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1246922
- Patent Number(s):
- 9308525
- Application Number:
- 14/192,856
- Assignee:
- CALIFORNIA INSTITUTE OF TECHNOLOGY (Pasadena, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- PS02-05ER15944
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2014 Feb 27
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Goddard, III, William A., Cheng, Mu-Jeng, and Fu, Ross. Methods for providing bond activation catalysts and related catalysts, systems, and methods. United States: N. p., 2016.
Web.
Goddard, III, William A., Cheng, Mu-Jeng, & Fu, Ross. Methods for providing bond activation catalysts and related catalysts, systems, and methods. United States.
Goddard, III, William A., Cheng, Mu-Jeng, and Fu, Ross. Tue .
"Methods for providing bond activation catalysts and related catalysts, systems, and methods". United States. https://www.osti.gov/servlets/purl/1246922.
@article{osti_1246922,
title = {Methods for providing bond activation catalysts and related catalysts, systems, and methods},
author = {Goddard, III, William A. and Cheng, Mu-Jeng and Fu, Ross},
abstractNote = {Described herein are catalysts for activation of an R--H bond in a R--H substrate and related catalytic matrices, compositions, methods and systems.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Apr 12 00:00:00 EDT 2016},
month = {Tue Apr 12 00:00:00 EDT 2016}
}
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Works referenced in this record:
Gas-Phase Reactions of Cationic Vanadium-Phosphorus Oxide Clusters with C 2 H x ( x= 4, 6): A DFT-Based Analysis of Reactivity Patterns
journal, January 2013
- Dietl, Nicolas; Zhang, Xinhao; van der Linde, Christian
- Chemistry - A European Journal, Vol. 19, Issue 9
The Critical Role of Phosphate in Vanadium Phosphate Oxide for the Catalytic Activation and Functionalization of n -Butane to Maleic Anhydride
journal, March 2013
- Cheng, Mu-Jeng; Goddard, William A.
- Journal of the American Chemical Society, Vol. 135, Issue 12
An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IV/V) Redox Couple
journal, April 2007
- Agarwal, Paresh; Piro, Nicholas A.; Meyer, Karsten
- Angewandte Chemie International Edition, Vol. 46, Issue 17, p. 3111-3114
Niobium and vanadium iminophosphinimide complexes
journal, January 2001
- Brask, Justin K.; Fickes, Michael G.; Sangtrirutnugul, Preeyanuch
- Chemical Communications, Issue 17
Synthesis of (Imido)vanadium(V) Alkyl and Alkylidene Complexes Containing Imidazolidin-2-iminato Ligands: Effect of Imido Ligand on ROMP and 1,2-C–H Bond Activation of Benzene
journal, November 2014
- Nomura, Kotohiro; Bahuleyan, Bijal Kottukkal; Tsutsumi, Ken
- Organometallics, Vol. 33, Issue 22
VPO catalyst for n-butane oxidation to maleic anhydride: A goal achieved, or a still open challenge?
journal, July 2006
- Ballarini, N.; Cavani, F.; Cortelli, C.
- Topics in Catalysis, Vol. 38, Issue 1-3
Mechanistic aspects of maleic anhydride synthesis from C4 hydrocarbons over phosphorus vanadium oxide
journal, January 1988
- Centi, Gabriele; Trifiro, Ferruccio; Ebner, Jerry R.
- Chemical Reviews, Vol. 88, Issue 1
Modelling the active sites in vanadyl pyrophosphate
journal, May 2003
- Thompson, D. J.; Fanning, M. O.; Hodnett, B. K.
- Journal of Molecular Catalysis A: Chemical, Vol. 198, Issue 1-2, p. 125-137
Changes of local electronic structure of perfect (VO)2P2O7(100) surface in response to oxygen vacancy formation: effect of electron trapping
journal, July 2002
- Haras, A.; Duarte, H. A.; Salahub, D. R.
- Surface Science, Vol. 513, Issue 2, p. 367-380
Role of mixed-valence state in vanadium phosphates catalysts
journal, May 1997
- Robert, V.; Borshch, S. A.; Bigot, B.
- Journal of Molecular Catalysis A: Chemical, Vol. 119, Issue 1-3, p. 327-333
Formation of maleic anhydride on a vanadyl pyrophosphate surface: a theoretical study of the mechanism
journal, March 1991
- Schioett, Birgit; Joergensen, Karl Anker; Hoffmann, Roald
- The Journal of Physical Chemistry, Vol. 95, Issue 6, p. 2297-2307
Temporal Analysis of Products (TAP)—A Unique Catalyst Evaluation System with Submillisecond Time Resolution
journal, February 1988
- Gleaves, J. T.; Ebner, J. R.; Kuechler, T. C.
- Catalysis Reviews, Vol. 30, Issue 1
On the Mechanism of n-Butane Oxidation to Maleic Anhydride on VPO Catalysts
journal, February 1994
- Zhanglin, Y.; Forissier, M.; Sneeden, R. P.
- Journal of Catalysis, Vol. 145, Issue 2
A molecular level mechanism ofn-butane oxidation to maleic anhydride over vanadyl pyrophosphate
journal, May 1994
- Agaskar, Pradyot A.; De Caul, Lorenzo; Grasselli, Robert K.
- Catalysis Letters, Vol. 23, Issue 3-4
Differing Reactions of Functionalized Hydrocarbons with Cp*M(NO)(alkyl)(η 3 -allyl) Complexes of Molybdenum and Tungsten
journal, February 2011
- Tran, Tommy; Chow, Catherine; Zimmerman, Amanda C.
- Organometallics, Vol. 30, Issue 4
Bond Dissociation Energies of Organic Molecules
journal, April 2003
- Blanksby, Stephen J.; Ellison, G. Barney
- Accounts of Chemical Research, Vol. 36, Issue 4
Dynamic processes on vanadium phosphorous oxides for selective alkane oxidation
journal, December 1996
- Volta, Jean-Claude
- Catalysis Today, Vol. 32, Issue 1-4
Role of the product in the transformation of a catalyst to its active state
journal, March 1994
- Hutchings, Graham J.; Desmartin-Chomel, Arnold; Olier, René
- Nature, Vol. 368, Issue 6466
Preparation of Vanadium–Phosphorus Mixed Oxide (P/V=1) Catalysts and Their Application to Oxidation of Butane to Maleic Anhydride
journal, August 1985
- Shimoda, Tomoaki; Okuhara, Toshio; Misono, Makoto
- Bulletin of the Chemical Society of Japan, Vol. 58, Issue 8
Structural Changes of Surface Layer of Vanadyl Pyrophosphate Catalysts by Oxidation−Reduction and Their Relationships with Selective Oxidation of n -Butane
journal, February 1998
- Koyano, Gaku; Okuhara, Toshio; Misono, Makoto
- Journal of the American Chemical Society, Vol. 120, Issue 4
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Improved tangent estimate in the nudged elastic band method for finding minimum energy paths and saddle points
journal, December 2000
- Henkelman, Graeme; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22
A climbing image nudged elastic band method for finding saddle points and minimum energy paths
journal, December 2000
- Henkelman, Graeme; Uberuaga, Blas P.; Jónsson, Hannes
- The Journal of Chemical Physics, Vol. 113, Issue 22, p. 9901-9904
Single Crystal Growth of the High Pressure Phase of (VO)2P2O7 at 3 GPa
journal, August 2000
- Saito, T.; Terashima, T.; Azuma, M.
- Journal of Solid State Chemistry, Vol. 153, Issue 1
Synchrotron-radiation study of the two-leg spin-ladder (VO)2P2O7 at 120 K
journal, December 2001
- Geupel, Sandra; Pilz, Katrin; Smaalen, Sander van
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 58, Issue 1, p. i9-i13
Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006
- Grimme, Stefan
- Journal of Computational Chemistry, Vol. 27, Issue 15, p. 1787-1799
Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules
journal, March 1972
- Hehre, W. J.; Ditchfield, R.; Pople, J. A.
- The Journal of Chemical Physics, Vol. 56, Issue 5, p. 2257-2261
Self‐consistent molecular orbital methods. XXIII. A polarization‐type basis set for second‐row elements
journal, October 1982
- Francl, Michelle M.; Pietro, William J.; Hehre, Warren J.
- The Journal of Chemical Physics, Vol. 77, Issue 7, p. 3654-3665
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
journal, January 1985
- Hay, P. Jeffrey; Wadt, Willard R.
- The Journal of Chemical Physics, Vol. 82, Issue 1, p. 299-310
Surface acidity of vanadyl pyrophosphate, active phase in n-butane selective oxidation
journal, March 1986
- Busca, Guido; Centi, Gabriele; Trifiro, Ferruccio
- The Journal of Physical Chemistry, Vol. 90, Issue 7, p. 1337-1344
Reactivity of Lattice Oxygens Present in V 2 O 5 (010): A Periodic First-Principles Investigation
journal, February 1999
- Yin, Xilin; Han, Huanmei; Endou, Akira
- The Journal of Physical Chemistry B, Vol. 103, Issue 8
Reactivity of the Oxygen Sites in the V 2 O 5 /TiO 2 Anatase Catalyst
journal, October 2004
- Calatayud, Mònica; Minot, Christian
- The Journal of Physical Chemistry B, Vol. 108, Issue 40
Activation of Vanadium Phosphorus Oxide Catalysts for Alkane Oxidation. The Influence of the Oxidation State on Catalyst Selectivity
journal, December 1994
- Schuurman, Yves; Gleaves, John T.
- Industrial & Engineering Chemistry Research, Vol. 33, Issue 12
Desirable catalyst properties in selective oxidation reactions
journal, June 1986
- Kung, Harold H.
- Industrial & Engineering Chemistry Product Research and Development, Vol. 25, Issue 2
TPD study of labile oxygen on a (VO)2P2O7 catalyst active in n-butane partial oxidation
journal, April 1998
- Joly, J. P.; Méhier, C.; Béré, K. E.
- Applied Catalysis A: General, Vol. 169, Issue 1, p. 55-63
The Electronic Structure of the Vanadyl Ion
journal, February 1962
- Ballhausen, C. J.; Gray, Harry B.
- Inorganic Chemistry, Vol. 1, Issue 1
Trans-dioxo Manganese(V) Porphyrins
journal, October 2007
- Jin, Ning; Ibrahim, Mohammed; Spiro, Thomas G.
- Journal of the American Chemical Society, Vol. 129, Issue 41
In situ Raman spectroscopy studies of bulk and surface metal oxide phases during oxidation reactions
journal, December 1996
- Wachs, Israel E.; Jehng, Jih-Mirn; Deo, Goutam
- Catalysis Today, Vol. 32, Issue 1-4, p. 47-55
Fundamental Studies of Butane Oxidation over Model-Supported Vanadium Oxide Catalysts: Molecular Structure-Reactivity Relationships
journal, August 1997
- Wachs, Israel E.; Jehng, Jih-Mirn; Deo, Goutam
- Journal of Catalysis, Vol. 170, Issue 1
The Kinetic Significance of V5+ in n-Butane Oxidation Catalyzed by Vanadium Phosphates
journal, January 1997
- Coulston, G. W.
- Science, Vol. 275, Issue 5297
In Situ Laser Raman Spectroscopy Studies of VPO Catalyst Transformations
journal, November 1999
- Xue, Zhi-Yang; Schrader, Glenn L.
- The Journal of Physical Chemistry B, Vol. 103, Issue 44
Evolution of the active surface of the vanadyl pyrophosphate catalysts
journal, January 1995
- Guliants, V. V.; Benziger, J. B.; Sundaresan, S.
- Catalysis Letters, Vol. 32, Issue 3-4
Role of Ceria in Oxidative Dehydrogenation on Supported Vanadia Catalysts
journal, February 2010
- Ganduglia-Pirovano, Maria Veronica; Popa, Cristina; Sauer, Joachim
- Journal of the American Chemical Society, Vol. 132, Issue 7
Methane Partial Oxidation by Unsupported and Silica Supported Iron Phosphate Catalysts
journal, January 1999
- Alptekin, Gokhan O.; Herring, Andrew M.; Williamson, D. L.
- Journal of Catalysis, Vol. 181, Issue 1
Effects of the method of preparing titanium pyrophosphate catalyst on the structure and catalytic activity in oxidative dehydrogenation of n-butane
journal, September 2003
- Marcu, Ioan-Cezar; Sandulescu, Ioan; Millet, Jean-Marc M.
- Journal of Molecular Catalysis A: Chemical, Vol. 203, Issue 1-2, p. 241-250
Effect of water vapor on the activity and selectivity characteristics of a vanadium phosphate catalyst towards butane oxidation
journal, July 1988
- Arnold, Ernest W.; Sundaresan, Sankaran
- Applied Catalysis, Vol. 41, p. 225-239
Activation of C−H Bonds by Metal Complexes
journal, December 1997
- Shilov, Alexander E.; Shul'pin, Georgiy B.
- Chemical Reviews, Vol. 97, Issue 8
A New Performance of the Reaction of PCl3/AlCl3 with Anisoles − One-Pot and Multi-Step Syntheses of a New Fused-Ring System [1,2,3]Benzoxadiphospholo[2,3-b][1,2,3]benzoxadiphosphole
journal, June 2001
- Baccolini, Graziano; Bazzocchi, Michele; Boga, Carla
- European Journal of Organic Chemistry, Vol. 2001, Issue 12, p. 2229-2233
Methane Activation by Metal-Free Radical Cations: Experimental Insight into the Reaction Intermediate
journal, April 2009
- de Petris, Giulia; Troiani, Anna; Rosi, Marzio
- Chemistry - A European Journal, Vol. 15, Issue 17
The reaction network of the selective oxidation of n-butane on (VO)2P2O7 catalysts: Nature of oxygen containing intermediates
journal, December 1996
- Kubias, B.; Rodemerck, U.; Zanthoff, H. -W.
- Catalysis Today, Vol. 32, Issue 1-4
Fundamental study of the oxidation of butane over vanadyl pyrophosphate
journal, August 1985
- Pepera, Marc A.; Callahan, James L.; Desmond, Michael J.
- Journal of the American Chemical Society, Vol. 107, Issue 17
Understanding C-H bond oxidations: H. and H- transfer in the oxidation of toluene by permanganate
journal, September 1995
- Gardner, K.; Mayer, J.
- Science, Vol. 269, Issue 5232
Multifunctionality of Active Centers in (Amm)oxidation Catalysts: From Bi–Mo–Ox to Mo–V–Nb–(Te, Sb)–Ox
journal, August 2003
- Grasselli, Robert K.; Burrington, James D.; Buttrey, Douglas J.
- Topics in Catalysis, Vol. 23, Issue 1/4, p. 5-22
Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization
journal, July 1998
- Wang, Chunming; Friedrich, Stefan; Younkin, Todd R.
- Organometallics, Vol. 17, Issue 15
Improvement of the Structural Model for the M1 Phase Mo–V–Nb–Te–O Propane (Amm)oxidation Catalyst
journal, June 2011
- Li, Xin; Buttrey, Douglas J.; Blom, Douglas A.
- Topics in Catalysis, Vol. 54, Issue 10-12
Pincer ligands with an all-phosphorus donor set: subtle differences between rhodium and palladium
journal, January 2011
- Bauer, Richard C.; Gloaguen, Yann; Lutz, Martin
- Dalton Transactions, Vol. 40, Issue 35
Original phenyl–P(O) bond cleavage at palladium(0): a combined experimental and computational study
journal, January 2011
- Derrah, Eric J.; Ladeira, Sonia; Bouhadir, Ghenwa
- Chemical Communications, Vol. 47, Issue 30
Chelating Assistance of P–C and P–H Bond Activation at Palladium and Nickel: Straightforward Access to Diverse Pincer Complexes from a Diphosphine–Phosphine Oxide
journal, February 2013
- Derrah, Eric J.; Martin, Carmen; Mallet-Ladeira, Sonia
- Organometallics, Vol. 32, Issue 4
Reactivity of a Mononuclear Iridium(I) Species Bearing a Terminal Phosphido Fragment Embedded in a Triphosphorus Ligand
journal, January 2013
- Gloaguen, Yann; Jacobs, Wesley; de Bruin, Bas
- Inorganic Chemistry, Vol. 52, Issue 4
Phosphido Pincer Complexes of Palladium as New Efficient Catalysts for Allylation of Aldehydes
journal, November 2008
- Mazzeo, Mina; Lamberti, Marina; Massa, Antonio
- Organometallics, Vol. 27, Issue 22
Phosphido pincer complexes of platinum: synthesis, structure and reactivity
journal, January 2011
- Mazzeo, Mina; Strianese, Maria; Kühl, Olaf
- Dalton Transactions, Vol. 40, Issue 35
Coordination of an N-Heterocyclic Phosphenium Containing Pincer Ligand to a Co(CO) 2 Fragment Allows Oxidation To Form an Unusual N-Heterocyclic Phosphinito Species
journal, November 2011
- Pan, Baofei; Bezpalko, Mark W.; Foxman, Bruce M.
- Organometallics, Vol. 30, Issue 21
Heterolytic addition of E–H bonds across Pt–P bonds in Pt N-heterocyclic phosphenium/phosphido complexes
journal, January 2012
- Pan, Baofei; Bezpalko, Mark W.; Foxman, Bruce M.
- Dalton Transactions, Vol. 41, Issue 30
Phosphine Oxide Anions in the Synthesis of Phosphine Ligands
journal, January 1983
- Wife, Richard L.; Van Oort, Aart B.; Van Doorn, Johannes A.
- Synthesis, Vol. 1983, Issue 01
Coordination compounds of chromium (+3) and vanadium (+3) and (+5) with 2,6-bis(diphenylhydroxymethyl)pyridyl ligand: Synthesis and study of catalytic activity in the polymerization of ethylene
journal, February 2013
- Kurmaev, Dmitry A.; Kolosov, Nicolai A.; Gagieva, Svetlana Ch.
- Inorganica Chimica Acta, Vol. 396, p. 136-143
Bisorganophosphonyl and -Organoarsenyl Derivatives of Heteropolytungstates as Hard Ligands for Early-Transition-Metal and Lanthanide Cations
journal, January 2013
- Villanneau, Richard; Djamâa, Aïcha Ben; Chamoreau, Lise-Marie
- European Journal of Inorganic Chemistry, Vol. 2013, Issue 10-11
The coordination chemistry of unsymmetric N-capped tripodal NO3 ligands with iron(III), oxo-vanadium(V) and dioxo-molybdenum(VI) metal centres
journal, March 2012
- Tong, Lok H.; Wong, Yee-Lok; Lee, Hung Kay
- Inorganica Chimica Acta, Vol. 383, p. 91-97
Asymmetric cyanohydrin synthesis using an aluminium(salan) complex
journal, August 2012
- North, Michael; Stewart, Emma L.; Young, Carl
- Tetrahedron: Asymmetry, Vol. 23, Issue 15-16, p. 1218-1225
Molecular (hyper)polarizabilities computed by pseudospectral methods
journal, March 2005
- Cao, Yixiang; Friesner, Richard A.
- The Journal of Chemical Physics, Vol. 122, Issue 10
Investigation of the Mechanism of n -Butane Oxidation on Vanadium Phosphorus Oxide Catalysts: Evidence from Isotopic Labeling Studies
journal, February 2002
- Chen, Bin; Munson, Eric J.
- Journal of the American Chemical Society, Vol. 124, Issue 8
Nature and mechanism of formation of vanadyl pyrophosphate: Active phase in n-butane selective oxidation
journal, June 1986
- Busca, Guido; Cavani, Fabrizio; Centi, Gabriele
- Journal of Catalysis, Vol. 99, Issue 2, p. 400-414
Catalyst for the production of maleic anhydride
patent, June 1982
- Franz, Gerhard; Nierlich, Franz; Ratajczak, Hans-Josef
- US Patent Document 4,335,018
Catalysts for the production of maleic anhydride by the oxidation of butane
patent, May 1985
- Edwards, Robert C.
- US Patent Document 4,515,904
Process for producing nitriles
patent, January 1994
- Ushikubo, Takashi; Oshima, Kazunori; Kayo, Atsushi
- US Patent Document 5,281,745
Vanadium/Phosphorus Mixed Oxide Catalyst
patent-application, August 2004
- Albonetti, Stefania; Cavani, Fabrizio; Ligi, Simone
- US Patent Application 10/779,684; 2004/0162217 Al