Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

Hu, Jian Zhi; Sears, Jesse A.; Hoyt, David W.; Mehta, Hardeep S.; Peden, Charles H. F.

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Title: Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

Abstract

A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.

Inventors:: Hu, Jian Zhi; Sears, Jr., Jesse A.; Hoyt, David W.; Mehta, Hardeep S.; Peden, Charles H. F.

Issue Date:: Tue Nov 24 00:00:00 EST 2015

Research Org.:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1226816

Patent Number(s):: 9194920

Application Number:: 13/648,751

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Classifications (CPCs):: G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

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G - PHYSICS G01 - MEASURING G01R - MEASURING ELECTRIC VARIABLES
G01R33/307 - {specially adapted for moving the sample relative to the MR system, e.g. spinning mechanisms, flow cells or means for positioning the sample inside a spectrometer}
G01R33/46 - NMR spectroscopy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T436/24 - Nuclear magnetic resonance, electron spin resonance or other spin effects or mass spectrometry

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DOE Contract Number:: AC05-76RL01830

Resource Type:: Patent

Resource Relation:: Patent File Date: 2012 Oct 10

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations.  United States: N. p., 2015. 
        Web.

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                    Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., & Peden, Charles H. F. Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations.  United States.

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                    Hu, Jian Zhi, Sears, Jr., Jesse A., Hoyt, David W., Mehta, Hardeep S., and Peden, Charles H. F. Tue .  
        "Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations".  United States.  https://www.osti.gov/servlets/purl/1226816.

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@article{osti_1226816,

  title        = {Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations},

  author       = {Hu, Jian Zhi and Sears, Jr., Jesse A. and Hoyt, David W. and Mehta, Hardeep S. and Peden, Charles H. F.},

  abstractNote = {A continuous-flow (CF) magic angle sample spinning (CF-MAS) NMR rotor and probe are described for investigating reaction dynamics, stable intermediates/transition states, and mechanisms of catalytic reactions in situ. The rotor includes a sample chamber of a flow-through design with a large sample volume that delivers a flow of reactants through a catalyst bed contained within the sample cell allowing in-situ investigations of reactants and products. Flow through the sample chamber improves diffusion of reactants and products through the catalyst. The large volume of the sample chamber enhances sensitivity permitting in situ .sup.13C CF-MAS studies at natural abundance.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Nov 24 00:00:00 EST 2015},

  month        = {Tue Nov 24 00:00:00 EST 2015}

}

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Works referenced in this record:

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Isbester, Paul K.; Zalusky, Andrew; Lewis, David H.
Catalysis Today, Vol. 49, Issue 4
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A combined MAS nuclear magnetic resonance spectroscopy, in situ FT infrared spectroscopy and catalytic study of the conversion of allyl alcohol over zeolite catalysts
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Sequential Steps of Ammoniation of the Microporous Silicoaluminophosphates H-SAPO-34 and H-SAPO-37 Investigated by In Situ CF MAS NMR Spectroscopy
journal, March 2004

Buchholz, A.; Wang, W.; Xu, M.
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In situ MAS NMR investigations of molecular sieves and zeolite-catalyzed reactions
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Derouane, Eric G.; He, Heyong; Derouane‐Abd Hamid, Sharifah Bee
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In situ flow MAS NMR spectroscopy: State of the art and applications in heterogeneous catalysis
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Hunger, Michael; Horvath, Thomas
Journal of the Chemical Society, Chemical Communications, Issue 14
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Conversion of Propan-2-ol on Zeolites LaNaY and HY Investigated by Gas Chromatography andin SituMAS NMR Spectroscopy under Continuous-Flow Conditions
journal, April 1997

Hunger, Michael; Horvath, Thomas
Journal of Catalysis, Vol. 167, Issue 1
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In situ MAS NMR spectroscopy of surface compounds formed from methanol and from a toluene/methanol mixture on basic zeolite X
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Hunger, Michael; Schenk, Udo; Seiler, Michael
Journal of Molecular Catalysis A: Chemical, Vol. 156, Issue 1-2, p. 153-161
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Alkali Metal Oxides, Peroxides, and Superoxides: A Multinuclear MAS NMR Study
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Krawietz, Thomas R.; Murray, David K.; Haw, James F.
The Journal of Physical Chemistry A, Vol. 102, Issue 45
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Conversion of methanol to hydrocarbons on zeolite HZSM‐5 investigated by in situ MAS NMR spectroscopy under flow conditions and on‐line gas chromatography
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Seiler, Michael; Schenk, Udo; Hunger, Michael
Catalysis Letters, Vol. 62, Issue 2/4, p. 139-145
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Application of in situ MAS NMR for elucidation of reaction mechanisms in heterogeneous catalysis
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Characterization of Dispersed Heteropoly Acid on Mesoporous Zeolite Using Solid-State ³¹ P NMR Spin−Lattice Relaxation
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Solid-state lead-207 NMR of lead(II) nitrate: Localized heating effects at high magic angle spinning speeds
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Similar Records

Title: Magic angle spinning nuclear magnetic resonance apparatus and process for high-resolution in situ investigations

Abstract

Citation Formats

NMR probe for heterogeneous catalysis with isolated reagent flow and magic-angle spinning journal, March 1999

A combined MAS nuclear magnetic resonance spectroscopy, in situ FT infrared spectroscopy and catalytic study of the conversion of allyl alcohol over zeolite catalysts journal, January 1995

Sequential Steps of Ammoniation of the Microporous Silicoaluminophosphates H-SAPO-34 and H-SAPO-37 Investigated by In Situ CF MAS NMR Spectroscopy journal, March 2004

In situ MAS NMR investigations of molecular sieves and zeolite-catalyzed reactions journal, January 1999

In situ flow MAS NMR spectroscopy: State of the art and applications in heterogeneous catalysis journal, October 2008

A new MAS NMR probe for in situ investigations of hydrocarbon conversion on solid catalysts under continuous-flow conditions journal, January 1995

Conversion of Propan-2-ol on Zeolites LaNaY and HY Investigated by Gas Chromatography andin SituMAS NMR Spectroscopy under Continuous-Flow Conditions journal, April 1997

In situ MAS NMR spectroscopy of surface compounds formed from methanol and from a toluene/methanol mixture on basic zeolite X journal, May 2000

Alkali Metal Oxides, Peroxides, and Superoxides: A Multinuclear MAS NMR Study journal, November 1998

Conversion of methanol to hydrocarbons on zeolite HZSM‐5 investigated by in situ MAS NMR spectroscopy under flow conditions and on‐line gas chromatography journal, January 1999

Application of in situ MAS NMR for elucidation of reaction mechanisms in heterogeneous catalysis journal, November 1999

In Situ NMR Investigations of Heterogeneous Catalysis with Samples Prepared under Standard Reaction Conditions journal, April 1998

Sealed capsules for convenient acquisition of variable-temperature controlled-atmosphere magic-angle-spinning NMR spectra of solids journal, July 1986

The development and applications of CAVERN methods for in situ NMR studies of reactions on solid acids journal, January 1997

Characterization of Dispersed Heteropoly Acid on Mesoporous Zeolite Using Solid-State 31 P NMR Spin−Lattice Relaxation journal, July 2009

Solid-state lead-207 NMR of lead(II) nitrate: Localized heating effects at high magic angle spinning speeds journal, October 1995

Chemistry with ADF journal, January 2001

Synthesis, characterization, and catalytic function of novel highly dispersed tungsten oxide catalysts on mesoporous silica journal, April 2006

NMR spectra of the BnAA′Bn′ type: Studies of but-2-ene and related compounds journal, October 1968

The Nuclear Magnetic Resonance Spectrum of 2-Butanol journal, December 1966

Evaluation of various DFT protocols for computing 1 H and 13 C chemical shifts to distinguish stereoisomers: diastereomeric 2-, 3-, and 4-methylcyclohexanols as a test set journal, May 2007

NMR probe for heterogeneous catalysis with isolated reagent flow and magic-angle spinning
journal, March 1999

A combined MAS nuclear magnetic resonance spectroscopy, in situ FT infrared spectroscopy and catalytic study of the conversion of allyl alcohol over zeolite catalysts
journal, January 1995

Sequential Steps of Ammoniation of the Microporous Silicoaluminophosphates H-SAPO-34 and H-SAPO-37 Investigated by In Situ CF MAS NMR Spectroscopy
journal, March 2004

In situ MAS NMR investigations of molecular sieves and zeolite-catalyzed reactions
journal, January 1999

In situ flow MAS NMR spectroscopy: State of the art and applications in heterogeneous catalysis
journal, October 2008

A new MAS NMR probe for in situ investigations of hydrocarbon conversion on solid catalysts under continuous-flow conditions
journal, January 1995

Conversion of Propan-2-ol on Zeolites LaNaY and HY Investigated by Gas Chromatography andin SituMAS NMR Spectroscopy under Continuous-Flow Conditions
journal, April 1997

In situ MAS NMR spectroscopy of surface compounds formed from methanol and from a toluene/methanol mixture on basic zeolite X
journal, May 2000

Alkali Metal Oxides, Peroxides, and Superoxides: A Multinuclear MAS NMR Study
journal, November 1998

Conversion of methanol to hydrocarbons on zeolite HZSM‐5 investigated by in situ MAS NMR spectroscopy under flow conditions and on‐line gas chromatography
journal, January 1999

Application of in situ MAS NMR for elucidation of reaction mechanisms in heterogeneous catalysis
journal, November 1999

In Situ NMR Investigations of Heterogeneous Catalysis with Samples Prepared under Standard Reaction Conditions
journal, April 1998

Sealed capsules for convenient acquisition of variable-temperature controlled-atmosphere magic-angle-spinning NMR spectra of solids
journal, July 1986

The development and applications of CAVERN methods for in situ NMR studies of reactions on solid acids
journal, January 1997

Characterization of Dispersed Heteropoly Acid on Mesoporous Zeolite Using Solid-State ³¹ P NMR Spin−Lattice Relaxation
journal, July 2009

Solid-state lead-207 NMR of lead(II) nitrate: Localized heating effects at high magic angle spinning speeds
journal, October 1995

Chemistry with ADF
journal, January 2001

Synthesis, characterization, and catalytic function of novel highly dispersed tungsten oxide catalysts on mesoporous silica
journal, April 2006

NMR spectra of the BnAA′Bn′ type: Studies of but-2-ene and related compounds
journal, October 1968

The Nuclear Magnetic Resonance Spectrum of 2-Butanol
journal, December 1966

Evaluation of various DFT protocols for computing ¹ H and ¹³ C chemical shifts to distinguish stereoisomers: diastereomeric 2-, 3-, and 4-methylcyclohexanols as a test set
journal, May 2007