Cyclo[n]pyrroles and methods thereto
Abstract
The present invention provides an oxidative coupling procedure that allows efficient synthesis of novel cyclo[n]pyrrole macrocycles. Therefore, the present invention provides cyclo[n]pyrroles where n is 6, 7, 8, 9, 10, 11, or 12, and derivatives, multimers, isomers, and ion and neutral molecule complexes thereof as new compositions of matter. A protonated form of cyclo[n]pyrrole displays a gap of up to 700 nm between strong Soret and Q-like absorption bands in the electronic spectrum, demonstrating no significant ground state absorption in the visible portion of the electronic spectrum. Uses of cyclo[n]pyrroles as separation media, nonlinear optical materials, information storage media and infrared filters are provided.
- Inventors:
- Issue Date:
- Research Org.:
- Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1175615
- Patent Number(s):
- 6984734
- Application Number:
- 10/373,949
- Assignee:
- University Of Texas
- Patent Classifications (CPCs):
-
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- DOE Contract Number:
- FG 03-01ER-115186
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Sessler, Jonathan L., Seidel, Daniel, Bolze, Frederic R., and Koehler, Thomas. Cyclo[n]pyrroles and methods thereto. United States: N. p., 2006.
Web.
Sessler, Jonathan L., Seidel, Daniel, Bolze, Frederic R., & Koehler, Thomas. Cyclo[n]pyrroles and methods thereto. United States.
Sessler, Jonathan L., Seidel, Daniel, Bolze, Frederic R., and Koehler, Thomas. Tue .
"Cyclo[n]pyrroles and methods thereto". United States. https://www.osti.gov/servlets/purl/1175615.
@article{osti_1175615,
title = {Cyclo[n]pyrroles and methods thereto},
author = {Sessler, Jonathan L. and Seidel, Daniel and Bolze, Frederic R. and Koehler, Thomas},
abstractNote = {The present invention provides an oxidative coupling procedure that allows efficient synthesis of novel cyclo[n]pyrrole macrocycles. Therefore, the present invention provides cyclo[n]pyrroles where n is 6, 7, 8, 9, 10, 11, or 12, and derivatives, multimers, isomers, and ion and neutral molecule complexes thereof as new compositions of matter. A protonated form of cyclo[n]pyrrole displays a gap of up to 700 nm between strong Soret and Q-like absorption bands in the electronic spectrum, demonstrating no significant ground state absorption in the visible portion of the electronic spectrum. Uses of cyclo[n]pyrroles as separation media, nonlinear optical materials, information storage media and infrared filters are provided.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 10 00:00:00 EST 2006},
month = {Tue Jan 10 00:00:00 EST 2006}
}
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