Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

Gordon, John Howard

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Title: Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

Abstract

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Inventors:: Gordon, John Howard

Issue Date:: Tue Sep 09 00:00:00 EDT 2014

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1157628

Patent Number(s):: 8828220

Application Number:: 12/916,984

Assignee:: Ceramatec, Inc. (Salt Lake City, UT)

Patent Classifications (CPCs):: C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25C - PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS

Show more

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2300/1025 - Natural gas
C10G2300/1081 - Alkanes
C10G2300/1088 - Olefins
C10G2300/202 - Heteroatoms content, i.e. S, N, O, P
C10G2300/205 - Metal content
C10G29/04 - Metals, or metals deposited on a carrier
C10G50/00 - Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation

C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25C - PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS
C25C1/22 - of metals not provided for in groups C25C1/02 - C25C1/20

Show less

DOE Contract Number:: FE0000408

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 02 PETROLEUM

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                    Gordon, John Howard. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons.  United States: N. p., 2014. 
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                    Gordon, John Howard. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons.  United States.

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                    Gordon, John Howard. Tue .  
        "Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons".  United States.  https://www.osti.gov/servlets/purl/1157628.

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@article{osti_1157628,

  title        = {Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons},

  author       = {Gordon, John Howard},

  abstractNote = {A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Sep 09 00:00:00 EDT 2014},

  month        = {Tue Sep 09 00:00:00 EDT 2014}

}

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Works referencing / citing this record:

Upgrading platform using alkali metals
patent, January 2017

Gordon, John Howard
US Patent Document 9,546,325
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9546325

Method of preventing corrosion of oil pipelines, storage structures and piping
patent, December 2016

Gordon, John Howard
US Patent Document 9,512,368
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9512368

Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
patent, September 2016

Gordon, John Howard; Alvare, Javier
US Patent Document 9,441,170
URL: https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9441170

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Similar Records

Title: Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

Abstract

Citation Formats

Electrolytic Process and Cell patent, July 1924

Nuclear Alkylation of Certain Aromatic Hydrocarbons with Alkali Metals as Catalysts patent, May 1958

Treatment of Alkylation Feed Stock with Sodium, Potassium, or Lithium Hydroxide Solution patent, February 1970

Process for the Desulfurization of Petroleum Oil Fractions patent, January 1974

Alkali Metal Desulfurization Process For Petroleum Oil Stocks Using Low Pressure Hydrogen patent, January 1974

Process for the Desulfurization of Petroleum Oil Stocks patent, January 1974

Alkali Metal Desulfurization Process for Petroleum Oil Stocks patent, February 1974

Process for upgrading a hydrocarbon fraction patent, June 1976

Combined disulfurization and conversion with alkali metals patent, February 1978

Upgrading hydrocarbonaceous oils with an aqueous liquid patent, January 1984

Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation patent, July 1994

Continuous in-situ combination process for upgrading heavy oil patent, December 1997

Process for the alkylation of aromatics patent, May 1998

Methods for adding value to heavy oil utilizing a soluble metal catalyst patent, August 1999

Continuous in-situ combination process for upgrading heavy oil patent, August 1999

Process for desulfurization of petroleum feeds utilizing sodium metal patent, April 2001

Apparatus and system for securing cargo patent, August 2001

Low temperature alkali metal electrolysis patent, April 2002

Zeolite/alumina catalyst support compositions and method of making the same patent, July 2002

Desulfurization with improved sorbent regeneration patent, October 2003

Continuous process for the synthesis of nano-scale precious metal particles patent, March 2004

Surface-modified mixed oxides containing precious metal and titanium, for the selective oxidation of hydrocarbons patent, May 2004

Low temperature alkali metal electrolysis patent, September 2004

Process for the recovery of materials from a desulfurization reaction patent, March 2011

Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides patent, January 2012

Process for reducing the acidity of oil patent-application, September 2002

Desulfurization of petroleum streams using metallic sodium patent-application, July 2005

Process For The Recovery Of Materials From A Desulfurization Reaction patent-application, July 2005

Emulsion neutralization of high total acid number (TAN) crude oil patent-application, March 2006

Method of removing sulfur from sulfur-containing hydrocarbon streams patent-application, June 2006

Porous composite materials having micro and meso/macroporosity patent-application, April 2007

Process For The Reduction/Removal Of The Concentration Of Hydrogen Sulfide Contained In Natural Gas patent-application, February 2008

Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides patent-application, May 2009

Integrated System and Method for Producing Fuel Composition From Biomass patent-application, October 2009

Apparatus and Method For Reducing an Alkali Metal Electrochemically at a Temperature Below the Metal's Melting Temperature patent-application, April 2010

Process for producing a high stability desulfurized heavy oils stream patent-application, June 2010

Immobilized Fluid Membranes For Gas Separation patent-application, November 2010

Electrochemical Cell Comprising Ionically Conductive Membrane And Porous Multiphase Electrode patent-application, November 2010

Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics patent-application, December 2010

Production of Aromatics from Methane patent-application, March 2011

Process For Catalytic Hydrotreatment Of A Pyrolysis Oil patent-application, May 2011

Process For De-Acidifying Hydrocarbons patent-application, June 2011

Bio-Oil Upgrading Process patent-application, December 2012

Upgrading Platform Using Alkali Metals patent-application, February 2013

Process For Desulfurizing Petroleum Feedstocks patent-application, June 2013

Method of Preventing Corrosion of Oil Pipelines, Storage Structures and Piping patent-application, June 2013

Desulphurization of gasoline by metallic sodium journal, July 1976

Hydrodesulfurization and Hydrodenitrogenation book, January 2002

Upgrading platform using alkali metals patent, January 2017

Method of preventing corrosion of oil pipelines, storage structures and piping patent, December 2016

Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane patent, September 2016

Electrolytic Process and Cell
patent, July 1924

Nuclear Alkylation of Certain Aromatic Hydrocarbons with Alkali Metals as Catalysts
patent, May 1958

Treatment of Alkylation Feed Stock with Sodium, Potassium, or Lithium Hydroxide Solution
patent, February 1970

Process for the Desulfurization of Petroleum Oil Fractions
patent, January 1974

Alkali Metal Desulfurization Process For Petroleum Oil Stocks Using Low Pressure Hydrogen
patent, January 1974

Process for the Desulfurization of Petroleum Oil Stocks
patent, January 1974

Alkali Metal Desulfurization Process for Petroleum Oil Stocks
patent, February 1974

Process for upgrading a hydrocarbon fraction
patent, June 1976

Combined disulfurization and conversion with alkali metals
patent, February 1978

Upgrading hydrocarbonaceous oils with an aqueous liquid
patent, January 1984

Upgrading of low value hydrocarbons using a hydrogen donor and microwave radiation
patent, July 1994

Continuous in-situ combination process for upgrading heavy oil
patent, December 1997

Process for the alkylation of aromatics
patent, May 1998

Methods for adding value to heavy oil utilizing a soluble metal catalyst
patent, August 1999

Continuous in-situ combination process for upgrading heavy oil
patent, August 1999

Process for desulfurization of petroleum feeds utilizing sodium metal
patent, April 2001

Apparatus and system for securing cargo
patent, August 2001

Low temperature alkali metal electrolysis
patent, April 2002

Zeolite/alumina catalyst support compositions and method of making the same
patent, July 2002

Desulfurization with improved sorbent regeneration
patent, October 2003

Continuous process for the synthesis of nano-scale precious metal particles
patent, March 2004

Surface-modified mixed oxides containing precious metal and titanium, for the selective oxidation of hydrocarbons
patent, May 2004

Low temperature alkali metal electrolysis
patent, September 2004

Process for the recovery of materials from a desulfurization reaction
patent, March 2011

Process for recovering alkali metals and sulfur from alkali metal sulfides and polysulfides
patent, January 2012

Process for reducing the acidity of oil
patent-application, September 2002

Desulfurization of petroleum streams using metallic sodium
patent-application, July 2005

Process For The Recovery Of Materials From A Desulfurization Reaction
patent-application, July 2005

Emulsion neutralization of high total acid number (TAN) crude oil
patent-application, March 2006

Method of removing sulfur from sulfur-containing hydrocarbon streams
patent-application, June 2006

Porous composite materials having micro and meso/macroporosity
patent-application, April 2007

Process For The Reduction/Removal Of The Concentration Of Hydrogen Sulfide Contained In Natural Gas
patent-application, February 2008

Process For Recovering Alkali Metals and Sulfur From Alkali Metal Sulfides and Polysulfides
patent-application, May 2009

Integrated System and Method for Producing Fuel Composition From Biomass
patent-application, October 2009

Apparatus and Method For Reducing an Alkali Metal Electrochemically at a Temperature Below the Metal's Melting Temperature
patent-application, April 2010

Process for producing a high stability desulfurized heavy oils stream
patent-application, June 2010

Immobilized Fluid Membranes For Gas Separation
patent-application, November 2010

Electrochemical Cell Comprising Ionically Conductive Membrane And Porous Multiphase Electrode
patent-application, November 2010

Zeolite Membranes for Separation of Mixtures Containing Water, Alcohols, or Organics
patent-application, December 2010

Production of Aromatics from Methane
patent-application, March 2011

Process For Catalytic Hydrotreatment Of A Pyrolysis Oil
patent-application, May 2011

Process For De-Acidifying Hydrocarbons
patent-application, June 2011

Bio-Oil Upgrading Process
patent-application, December 2012

Upgrading Platform Using Alkali Metals
patent-application, February 2013

Process For Desulfurizing Petroleum Feedstocks
patent-application, June 2013

Method of Preventing Corrosion of Oil Pipelines, Storage Structures and Piping
patent-application, June 2013

Desulphurization of gasoline by metallic sodium
journal, July 1976

Hydrodesulfurization and Hydrodenitrogenation
book, January 2002

Upgrading platform using alkali metals
patent, January 2017

Method of preventing corrosion of oil pipelines, storage structures and piping
patent, December 2016

Device and method for upgrading petroleum feedstocks and petroleum refinery streams using an alkali metal conductive membrane
patent, September 2016