Process for production of a metal hydride
Abstract
A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.
- Inventors:
- Issue Date:
- Research Org.:
- Rohm and Haas Company, Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1150093
- Patent Number(s):
- 8802051
- Application Number:
- 13/053,350
- Assignee:
- Rohm and Haas Company (Philadelphia, PA); Dow Global Technologies LLC (Midland, MI)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- FC36-05GO15053
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, and Molzahn, David Craig. Process for production of a metal hydride. United States: N. p., 2014.
Web.
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, & Molzahn, David Craig. Process for production of a metal hydride. United States.
Allen, Nathan Tait, Butterick, III, Robert, Chin, Arthur Achhing, Millar, Dean Michael, and Molzahn, David Craig. Tue .
"Process for production of a metal hydride". United States. https://www.osti.gov/servlets/purl/1150093.
@article{osti_1150093,
title = {Process for production of a metal hydride},
author = {Allen, Nathan Tait and Butterick, III, Robert and Chin, Arthur Achhing and Millar, Dean Michael and Molzahn, David Craig},
abstractNote = {A process for production of a metal hydride compound MH.sub.x, wherein x is one or two and M is an alkali metal, Be or Mg. The process comprises combining a compound of formula (R.sup.1O).sub.xM with aluminum, hydrogen and at least one metal selected from among titanium, zirconium, hafnium, niobium, vanadium, tantalum and iron to produce a compound of formula MH.sub.x. R.sup.1 is phenyl or phenyl substituted by at least one alkyl or alkoxy group. A mole ratio of aluminum to (R.sup.1O).sub.xM is from 0.1:1 to 1:1. The catalyst is present at a level of at least 200 ppm based on weight of aluminum.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 12 00:00:00 EDT 2014},
month = {Tue Aug 12 00:00:00 EDT 2014}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Process for production of sodium borohydride from sodium aluminum hydride with recycle of byproducts
patent, July 2007
- Ashby, Eugene C.
- US Patent Document 7,247,286
Method of preparing potassium hydride
patent, April 1982
- Chiu, Kuen-Wai; Strickler, John R.
- US Patent Document 4,327,071
Process for the production and purification of sodium hydride
patent-application, December 2004
- Heller, Jorg; Gerlach, Hans-Peter; De Vries, Hans
- US Patent Application 10/485329; 20040258613
Process for the production of magnesium hydrides
patent, September 1990
- Bogdanovic, Borislav
- US Patent Document 4,957,727