Graphene-based battery electrodes having continuous flow paths
Abstract
Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.
- Inventors:
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1136183
- Patent Number(s):
- 8758947
- Application Number:
- 13/004,138
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Zhang, Jiguang, Xiao, Jie, Liu, Jun, Xu, Wu, Li, Xiaolin, and Wang, Deyu. Graphene-based battery electrodes having continuous flow paths. United States: N. p., 2014.
Web.
Zhang, Jiguang, Xiao, Jie, Liu, Jun, Xu, Wu, Li, Xiaolin, & Wang, Deyu. Graphene-based battery electrodes having continuous flow paths. United States.
Zhang, Jiguang, Xiao, Jie, Liu, Jun, Xu, Wu, Li, Xiaolin, and Wang, Deyu. Sat .
"Graphene-based battery electrodes having continuous flow paths". United States. https://www.osti.gov/servlets/purl/1136183.
@article{osti_1136183,
title = {Graphene-based battery electrodes having continuous flow paths},
author = {Zhang, Jiguang and Xiao, Jie and Liu, Jun and Xu, Wu and Li, Xiaolin and Wang, Deyu},
abstractNote = {Some batteries can exhibit greatly improved performance by utilizing electrodes having randomly arranged graphene nanosheets forming a network of channels defining continuous flow paths through the electrode. The network of channels can provide a diffusion pathway for the liquid electrolyte and/or for reactant gases. Metal-air batteries can benefit from such electrodes. In particular Li-air batteries show extremely high capacities, wherein the network of channels allow oxygen to diffuse through the electrode and mesopores in the electrode can store discharge products.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat May 24 00:00:00 EDT 2014},
month = {Sat May 24 00:00:00 EDT 2014}
}
Works referenced in this record:
Electrolyte for metal-oxygen battery and method for its preparation
patent, September 2009
- Read, Jeffrey A.
- US Patent Document 7,585,579
Fluorination of multi-layered carbon nanomaterials
patent, September 2010
- Yazami, Rachid; Hamwi, André
- US Patent Document 7,794,880
Protected active metal electrode and battery cell structures with non-aqueous interlayer architecture
patent-application, August 2005
- Visco, Steven J.; , Bruce D
- US Patent Application 10/824944; 20050175894
Nanocomposite of graphene and metal oxide materials
patent-application, April 2010
- Liu, Jun; Aksay, Ilhan A.; Choi, Daiwon
- US Patent Application 12/460993; 20100081057
Nano graphene reinforced nanocomposite particles for lithium battery electrodes
patent-application, June 2010
- Zhamu, Aruna; Jang, Bor; Shi, Jinjun
- US Patent Application 12/315555; 20100143798
Lithium-Oxygen Electrochemical Cells and Batteries
patent-application, May 2011
- Johnson, Christopher S.; Pol, Vilas G.; Zhang, Zhengcheng
- US Patent Application 12/915580; 20110104576
Enhanced Cyclic Performance and Lithium Storage Capacity of SnO 2 /Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure
journal, January 2009
- Paek, Seung-Min; Yoo, EunJoo; Honma, Itaru
- Nano Letters, Vol. 9, Issue 1
Chemical methods for the production of graphenes
journal, March 2009
- Park, Sungjin; Ruoff, Rodney S.
- Nature Nanotechnology, Vol. 4, Issue 4, p. 217-224
Electrochemical Properties of Graphene Paper Electrodes Used in Lithium Batteries
journal, July 2009
- Wang, Caiyun; Li, Dan; Too, Chee O.
- Chemistry of Materials, Vol. 21, Issue 13