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Title: Hydrogen production using ammonia borane

Abstract

Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.

Inventors:
; ; ;
Issue Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1111472
Patent Number(s):
8613902
Application Number:
12/416,835
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
DOE Contract Number:  
AC52-06NA25396
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN

Citation Formats

Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, and Shrestha, Roshan P. Hydrogen production using ammonia borane. United States: N. p., 2013. Web.
Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, & Shrestha, Roshan P. Hydrogen production using ammonia borane. United States.
Hamilton, Charles W, Baker, R. Thomas, Semelsberger, Troy A, and Shrestha, Roshan P. Tue . "Hydrogen production using ammonia borane". United States. https://www.osti.gov/servlets/purl/1111472.
@article{osti_1111472,
title = {Hydrogen production using ammonia borane},
author = {Hamilton, Charles W and Baker, R. Thomas and Semelsberger, Troy A and Shrestha, Roshan P},
abstractNote = {Hydrogen ("H.sub.2") is produced when ammonia borane reacts with a catalyst complex of the formula L.sub.nM-X wherein M is a base metal such as iron, X is an anionic nitrogen- or phosphorus-based ligand or hydride, and L is a neutral ancillary ligand that is a neutral monodentate or polydentate ligand.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Dec 24 00:00:00 EST 2013},
month = {Tue Dec 24 00:00:00 EST 2013}
}

Works referenced in this record:

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Process for preparing optically active cyclohexanol derivatives
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Acid Initiation of Ammonia–Borane Dehydrogenation for Hydrogen Storage
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Thermal decomposition of B–N–H compounds investigated by using combined thermoanalytical methods
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4-methoxybiphenyl hydrazone derivatives
patent, March 2004


Base Metal Catalyzed Dehydrogenation of Ammonia−Borane for Chemical Hydrogen Storage
journal, February 2007


Transition Metal-Catalyzed Formation of Boron−Nitrogen Bonds:  Catalytic Dehydrocoupling of Amine-Borane Adducts to Form Aminoboranes and Borazines
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The Metal−Ligand Bifunctional Catalysis:  A Theoretical Study on the Ruthenium(II)-Catalyzed Hydrogen Transfer between Alcohols and Carbonyl Compounds
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Hydrogen storage material and related processes
patent, July 2010


Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes
journal, October 2008


Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane
journal, January 2009