Recompressed exfoliated graphite articles
Abstract
This invention provides an electrically conductive, less anisotropic, recompressed exfoliated graphite article comprising a mixture of (a) expanded or exfoliated graphite flakes; and (b) particles of non-expandable graphite or carbon, wherein the non-expandable graphite or carbon particles are in the amount of between about 3% and about 70% by weight based on the total weight of the particles and the expanded graphite flakes combined; wherein the mixture is compressed to form the article having an apparent bulk density of from about 0.1 g/cm.sup.3 to about 2.0 g/cm.sup.3. The article exhibits a thickness-direction conductivity typically greater than 50 S/cm, more typically greater than 100 S/cm, and most typically greater than 200 S/cm. The article, when used in a thin foil or sheet form, can be a useful component in a sheet molding compound plate used as a fuel cell separator or flow field plate. The article may also be used as a current collector for a battery, supercapacitor, or any other electrochemical cell.
- Inventors:
- Issue Date:
- Research Org.:
- Nanotek Instruments, Inc. (Dayton, OH)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1089409
- Patent Number(s):
- 8501307
- Application Number:
- 11/899,009
- Assignee:
- Nanotek Instruments, Inc. (Dayton, OH)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01B - CABLES
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Zhamu, Aruna, Shi, Jinjun, Guo, Jiusheng, and Jang, Bor Z. Recompressed exfoliated graphite articles. United States: N. p., 2013.
Web.
Zhamu, Aruna, Shi, Jinjun, Guo, Jiusheng, & Jang, Bor Z. Recompressed exfoliated graphite articles. United States.
Zhamu, Aruna, Shi, Jinjun, Guo, Jiusheng, and Jang, Bor Z. Tue .
"Recompressed exfoliated graphite articles". United States. https://www.osti.gov/servlets/purl/1089409.
@article{osti_1089409,
title = {Recompressed exfoliated graphite articles},
author = {Zhamu, Aruna and Shi, Jinjun and Guo, Jiusheng and Jang, Bor Z},
abstractNote = {This invention provides an electrically conductive, less anisotropic, recompressed exfoliated graphite article comprising a mixture of (a) expanded or exfoliated graphite flakes; and (b) particles of non-expandable graphite or carbon, wherein the non-expandable graphite or carbon particles are in the amount of between about 3% and about 70% by weight based on the total weight of the particles and the expanded graphite flakes combined; wherein the mixture is compressed to form the article having an apparent bulk density of from about 0.1 g/cm.sup.3 to about 2.0 g/cm.sup.3. The article exhibits a thickness-direction conductivity typically greater than 50 S/cm, more typically greater than 100 S/cm, and most typically greater than 200 S/cm. The article, when used in a thin foil or sheet form, can be a useful component in a sheet molding compound plate used as a fuel cell separator or flow field plate. The article may also be used as a current collector for a battery, supercapacitor, or any other electrochemical cell.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 06 00:00:00 EDT 2013},
month = {Tue Aug 06 00:00:00 EDT 2013}
}
Works referenced in this record:
Method for producing composite objects using expanded graphite and vermiculite
patent-application, January 2007
- Da Silva, Serge; Gros, Pierre; Leguen, Cedric
- US Patent Application 10/574803; 20070015267
Housing for electrical or electronic equipment
patent, July 1985
- Atkinson, Alan W.; Hurst, David; Somerfield, Kenneth T.
- US Patent Document 4,530,949
Laminated fluid flow field assembly for electrochemical fuel cells
patent, April 1994
- Washington, Kirk B.; Wilkinson, David P.; Voss, Henry H.
- US Patent Document 5,300,370
Conductive composite material and fuel cell electrode using same
patent-application, February 2004
- Jousse, Franck; Salas, Jean-Felix; Marsacq, Didier
- US Patent Application 10/333940; 20040028993
Bipolar plate/diffuser for a proton exchange membrane fuel cell
patent, March 2000
- Besmann, Theodore M.; Burchell, Timothy D.
- US Patent Document 6,037,073
Flexible graphite composite for use in the form of a fuel cell flow field plate
patent, March 2000
- Mercuri, Robert Angelo; Gough, Jeffrey John
- US Patent Document 6,037,074
Graphite article having predetermined anisotropic characteristics and process therefor
patent-application, November 2002
- Mercuri, Robert Angelo; Norley, Julian; Smalc, Martin David
- US Patent Application 09/826229; 20020164483
Reinforced flexible graphite sheet
patent, March 1988
- Fukuda, Hiroyuki; Shigeta, Masatomo; Kaji, Hisatsugu
- US Patent Document 4,729,910
Bipolar plate/diffuser for a proton exchange membrane fuel cell
patent, January 2001
- Besmann, Theodore M.; Burchell, Timothy D.
- US Patent Document 6,171,720
Fuel cell separator, process for production thereof, and polymer electrolyte fuel cell
patent, September 2005
- Saito, Kazuo; Hagiwara, Atsushi; Miyazawa, Atsushi
- US Patent Document 6,939,638
Highly conductive thermoplastic composites for rapid production of fuel cell bipolar plates
patent-application, November 2004
- Huang, Jianhua; Baird, Donald G.; McGrath, James F.
- US Patent Application 10/779804; 20040229993
Impregnated bodies made of expanded graphite, process for producing such bodies and sealing elements, fuel cell components and heat-conducting elements formed of the bodies
patent, June 2004
- Öttinger, Oswin; Bacher, Jürgen; Langer, Werner
- US Patent Document 6,746,771
Conductive composite material and electrode for fuel cell using said material formed by thermo-compression
patent, December 2006
- Baurens, Pierre; Bourgeoisat, Eric; Jousse, Franck
- US Patent Document 7,147,960
Exfoliated graphite fibers and associated method
patent, April 1990
- Chung, Deborah D. L.
- US Patent Document 4,915,925
Separator for fuel cell, process for production thereof, and solid polymer type fuel cell using said separator
patent, April 2005
- Saito, Kazuo; Hagiwara, Atsushi
- US Patent Document 6,881,512
Low-density graphite-polymer electrical conductors
patent, November 1987
- Chung, Deborah D. L.
- US Patent Document 4,704,231
Flexible graphite composite
patent, March 1999
- Mercuri, Robert Angelo; Capp, Joseph Paul; Gough, Jeffrey John
- US Patent Document 5,885,728
Conductive resin molding
patent-application, June 2005
- Egami, Masaki; Shimazu, Eiichirou
- US Patent Application 10/508426; 20050116376
Flexible graphite article and method of manufacture
patent, August 2002
- Mercuri, Robert Angelo; Capp, Joseph Paul; Warddrip, Michael Lee
- US Patent Document 6,432,336
Methacrylate impregnated carbonaceous parts
patent-application, November 2001
- Fong, Paul Po Hang; Sexsmith, Michael P.; Brown, David
- US Patent Application 09/896178; 20010046560
Composite bipolar plate for electrochemical cells
patent, June 2001
- Wilson, Mahlon S.; Busick, Deanna N.
- US Patent Document 6,248,467
Flexible graphite article and method of manufacture
patent, March 2004
- Mercuri, Robert Angelo; Capp, Joseph Paul; Warddrip, Michael Lee
- US Patent Document 6,706,400
Highly conductive nano-scaled graphene plate nanocomposites and products
patent-application, July 2007
- Song, Lulu; Guo, Jiusheng; Zhamu, Aruna
- US Patent Application 11/328880; 20070158618
Method of fabricating an embossed fluid flow field plate
patent, June 1996
- Wilkinson, David P.; Lamont, Gordon; Voss, Henry H.
- US Patent Document 5,527,363
Vermicular expanded graphite composite material
patent, May 1981
- Caines, Ronald S.
- US Patent Document 4,265,952
Composites of in-situ exfoliated graphite
patent, August 1990
- Chung, Deborah D. L.
- US Patent Document 4,946,892
Battery cathode including a mixture of manganese dioxide with carbon particles of expanded and non-expanded graphite
patent, September 2002
- Davis, Stuart M.; Huang, Qingyu; Miller, John S.
- US Patent Document 6,451,486