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Title: Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream

Abstract

The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.

Inventors:
; ; ;
Issue Date:
Research Org.:
National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1087886
Patent Number(s):
8486301
Application Number:
13/028,303
Assignee:
U.S. Department of Energy (Washington, DC)
Patent Classifications (CPCs):
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Berry, David A, Shekhawat, Dushyant, Smith, Mark, and Haynes, Daniel. Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream. United States: N. p., 2013. Web.
Berry, David A, Shekhawat, Dushyant, Smith, Mark, & Haynes, Daniel. Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream. United States.
Berry, David A, Shekhawat, Dushyant, Smith, Mark, and Haynes, Daniel. Tue . "Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream". United States. https://www.osti.gov/servlets/purl/1087886.
@article{osti_1087886,
title = {Method of preparing and utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream},
author = {Berry, David A and Shekhawat, Dushyant and Smith, Mark and Haynes, Daniel},
abstractNote = {The disclosure relates to a method of utilizing a catalyst system for an oxidation process on a gaseous hydrocarbon stream with a mitigation of carbon accumulation. The system is comprised of a catalytically active phase deposited onto an oxygen conducting phase, with or without supplemental support. The catalytically active phase has a specified crystal structure where at least one catalytically active metal is a cation within the crystal structure and coordinated with oxygen atoms within the crystal structure. The catalyst system employs an optimum coverage ratio for a given set of oxidation conditions, based on a specified hydrocarbon conversion and a carbon deposition limit. Specific embodiments of the catalyst system are disclosed.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 16 00:00:00 EDT 2013},
month = {Tue Jul 16 00:00:00 EDT 2013}
}

Works referenced in this record:

Microscopic Insights into Methane Activation and Related Processes on Pt/Ceria Model Catalysts
journal, May 2010


Methods of reforming hydrocarbon fuels using hexaaluminate catalysts
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Carbon deposited on Ni/CeZrO isooctane autothermal reforming catalysts
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Pyrochlore-type catalysts for the reforming of hydrocarbon fuels
patent, March 2012


Carbon Deposition and Catalytic Deactivation during CO2 Reforming of CH4 over Co/γ-Al2O3 Catalysts
journal, January 2002


Method for steam reforming hydrocarbons using a sulfur-tolerant catalyst
patent, May 2001


Synthesis gas conversion with perovskite catalysts
patent, September 1989