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Title: Enhancing hydrogen spillover and storage

Abstract

Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.

Inventors:
; ;
Issue Date:
Research Org.:
Univ. of Michigan, Ann Arbor, MI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1083202
Patent Number(s):
8372369
Application Number:
13/090,618
Assignee:
The Regents of The University of Michigan (Ann Arbor, MI)
Patent Classifications (CPCs):
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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DOE Contract Number:  
FC36-05GO15078
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
08 HYDROGEN

Citation Formats

Yang, Ralph T, Li, Yingwei, and Lachawiec, Jr., Anthony J. Enhancing hydrogen spillover and storage. United States: N. p., 2013. Web.
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Yang, Ralph T, Li, Yingwei, & Lachawiec, Jr., Anthony J. Enhancing hydrogen spillover and storage. United States.
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Yang, Ralph T, Li, Yingwei, and Lachawiec, Jr., Anthony J. Tue . "Enhancing hydrogen spillover and storage". United States. https://www.osti.gov/servlets/purl/1083202.
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@article{osti_1083202,
title = {Enhancing hydrogen spillover and storage},
author = {Yang, Ralph T and Li, Yingwei and Lachawiec, Jr., Anthony J},
abstractNote = {Methods for enhancing hydrogen spillover and storage are disclosed. One embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the hydrogen receptor to ultrasonication as doping occurs. Another embodiment of the method includes doping a hydrogen receptor with metal particles, and exposing the doped hydrogen receptor to a plasma treatment.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 12 00:00:00 EST 2013},
month = {Tue Feb 12 00:00:00 EST 2013}
}
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The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.</div><div class="small clearfix text-muted" style="margin-top:15px;"> <div class="pure-menu pure-menu-horizontal pull-right" style="width:unset;"> <ul class="pure-menu-list"> <li class="pure-menu-item"><span class="item-info-ftlink"><a class="misc fulltext-link" style="background-color:#f9f9f9;" href="https://www.osti.gov/servlets/purl/1082137" title="Link to document media" target="_blank" rel="noopener noreferrer" data-ostiid="1082137" data-category="downloads" data-action="full text click via search pages" data-product-type="Patent" data-product-subtype="">Full Text Available</a></span></li> </ul> </div> </div> </div> <div class="clearfix"></div> </div> </li> <li> <div class="article item document" itemprop="itemListElement" itemscope itemtype="http://schema.org/WebPage"><meta itemprop="position" content="2" /><div class="item-info"> <h2 class="title" itemprop="name headline"> <a href="/doepatents/biblio/1083306" itemprop="url">Metal salt catalysts for enhancing hydrogen spillover</a> </h2> <div class="metadata"> <small class="text-muted" style="text-transform:uppercase;display:block;line-height:2.5em;">Patent</small><span class="authors"> Yang, Ralph T; Wang, Yuhe<span class="text-muted pubdata"></span> </span> </div> <div class="abstract">A composition for hydrogen storage includes a receptor, a hydrogen dissociating metal doped on the receptor, and a metal salt doped on the receptor. The hydrogen dissociating metal is configured to spill over hydrogen to the receptor, and the metal salt is configured to increase a rate of the spill over of the hydrogen to the receptor.</div><div class="small clearfix text-muted" style="margin-top:15px;"> <div class="pure-menu pure-menu-horizontal pull-right" style="width:unset;"> <ul class="pure-menu-list"> <li class="pure-menu-item"><span class="item-info-ftlink"><a class="misc fulltext-link" style="background-color:#f9f9f9;" href="https://www.osti.gov/servlets/purl/1083306" title="Link to document media" target="_blank" rel="noopener noreferrer" data-ostiid="1083306" data-category="downloads" data-action="full text click via search pages" data-product-type="Patent" data-product-subtype="">Full Text Available</a></span></li> </ul> </div> </div> </div> <div class="clearfix"></div> </div> </li> <li> <div class="article item document" itemprop="itemListElement" itemscope itemtype="http://schema.org/WebPage"><meta itemprop="position" content="3" /><div class="item-info"> <h2 class="title" itemprop="name headline"> <a href="/doepatents/biblio/984455" itemprop="url">Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion</a> </h2> <div class="metadata"> <small class="text-muted" style="text-transform:uppercase;display:block;line-height:2.5em;">Patent</small><span class="authors"> Lessing, Paul A [Idaho Falls, ID]<span class="text-muted pubdata"></span> </span> </div> <div class="abstract">An electrochemically active hydrogen diffusion barrier which comprises an anode layer, a cathode layer, and an intermediate electrolyte layer, which is conductive to protons and substantially impermeable to hydrogen. A catalytic metal present in or adjacent to the anode layer catalyzes an electrochemical reaction that converts any hydrogen that diffuses through the electrolyte layer to protons and electrons. The protons and electrons are transported to the cathode layer and reacted to form hydrogen. The hydrogen diffusion barrier is applied to a polymeric substrate used in a storage tank to store hydrogen under high pressure. A storage tank equipped with the<a href='#' onclick='$(this).hide().next().show().next().show();return false;' style='margin-left:10px; background-color:#f9f9f9;' class="more-less-link">more »</a> <span style='display:none;'> electrochemically active hydrogen diffusion barrier, a method of fabricating the storage tank, and a method of preventing hydrogen from diffusing out of a storage tank are also disclosed.</span> <a href='#' onclick='$(this).hide().prev().hide().prev().show();return false;' style='margin-left:10px;display:none;' class="more-less-link">« less</a></div><div class="small clearfix text-muted" style="margin-top:15px;"> <div class="pure-menu pure-menu-horizontal pull-right" style="width:unset;"> <ul class="pure-menu-list"> <li class="pure-menu-item"><span class="item-info-ftlink"><a class="misc fulltext-link" style="background-color:#f9f9f9;" href="https://www.osti.gov/servlets/purl/984455" title="Link to document media" target="_blank" rel="noopener noreferrer" data-ostiid="984455" data-category="downloads" data-action="full text click via search pages" data-product-type="Patent" data-product-subtype="">Full Text Available</a></span></li> </ul> </div> </div> </div> <div class="clearfix"></div> </div> </li> <li> <div class="article item document" itemprop="itemListElement" itemscope itemtype="http://schema.org/WebPage"><meta itemprop="position" content="4" /><div class="item-info"> <h2 class="title" itemprop="name headline"> <a href="/doepatents/biblio/1175012" itemprop="url">Polymeric hydrogen diffusion barrier, high-pressure storage tank so equipped, method of fabricating a storage tank and method of preventing hydrogen diffusion</a> </h2> <div class="metadata"> <small class="text-muted" style="text-transform:uppercase;display:block;line-height:2.5em;">Patent</small><span class="authors"> Lessing, Paul A.<span class="text-muted pubdata"></span> </span> </div> <div class="abstract">An electrochemically active hydrogen diffusion barrier which comprises an anode layer, a cathode layer, and an intermediate electrolyte layer, which is conductive to protons and substantially impermeable to hydrogen. A catalytic metal present in or adjacent to the anode layer catalyzes an electrochemical reaction that converts any hydrogen that diffuses through the electrolyte layer to protons and electrons. The protons and electrons are transported to the cathode layer and reacted to form hydrogen. The hydrogen diffusion barrier is applied to a polymeric substrate used in a storage tank to store hydrogen under high pressure. A storage tank equipped with the<a href='#' onclick='$(this).hide().next().show().next().show();return false;' style='margin-left:10px; background-color:#f9f9f9;' class="more-less-link">more »</a> <span style='display:none;'> electrochemically active hydrogen diffusion barrier, a method of fabricating the storage tank, and a method of preventing hydrogen from diffusing out of a storage tank are also disclosed.</span> <a href='#' onclick='$(this).hide().prev().hide().prev().show();return false;' style='margin-left:10px;display:none;' class="more-less-link">« less</a></div><div class="small clearfix text-muted" style="margin-top:15px;"> <div class="pure-menu pure-menu-horizontal pull-right" style="width:unset;"> <ul class="pure-menu-list"> <li class="pure-menu-item"><span class="item-info-ftlink"><a class="misc fulltext-link" style="background-color:#f9f9f9;" href="https://www.osti.gov/servlets/purl/1175012" title="Link to document media" target="_blank" rel="noopener noreferrer" data-ostiid="1175012" data-category="downloads" data-action="full text click via search pages" data-product-type="Patent" data-product-subtype="">Full Text Available</a></span></li> </ul> </div> </div> </div> <div class="clearfix"></div> </div> </li> </ul> </aside> </div> </section> </div> <div class="col-sm-3 order-sm-3"> <ul class="nav nav-stacked"> <li class="active"><a class="tab-nav disabled" data-tab="related" style="color: #636c72 !important; 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