Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods

Marks, Tobin J; Rodriguez, Brandon A; Delferro, Massimiliano

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Title: Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods

Abstract

A catalyst composition comprising a neutral bimetallic diphenoxydiiminate complex of group 10 metals or Ni, Pd or Pt is disclosed. The compositions can be used for the preparation of homo- and co-polymers of olefinic monomer compounds.

Inventors:

Marks, Tobin J ^[1]; Rodriguez, Brandon A ^[1]; Delferro, Massimiliano ^[2]

Evanston, IL
Chicago, IL

Issue Date:: Tue Aug 07 00:00:00 EDT 2012

Research Org.:: Northwestern University (Evanston, IL)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1063988

Patent Number(s):: 8236907

Application Number:: 12/574,397

Assignee:: Northwestern University (Evanston, IL)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
C07F15/04 - Nickel compounds

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C08F10/02 - Ethene
C08F210/02 - Ethene
C08F232/00 - Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
C08F2410/03 - Multinuclear procatalyst, i.e. containing two or more metals, being different or not
C08F2500/03 - Narrow molecular weight distribution
C08F4/80 - selected from iron group metals or platinum group metals

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DOE Contract Number:: FG02-86ER13511

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Marks, Tobin J, Rodriguez, Brandon A, and Delferro, Massimiliano. Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods.  United States: N. p., 2012. 
        Web.

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                    Marks, Tobin J, Rodriguez, Brandon A, & Delferro, Massimiliano. Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods.  United States.

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                    Marks, Tobin J, Rodriguez, Brandon A, and Delferro, Massimiliano. Tue .  
        "Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods".  United States.  https://www.osti.gov/servlets/purl/1063988.

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@article{osti_1063988,

  title        = {Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods},

  author       = {Marks, Tobin J and Rodriguez, Brandon A and Delferro, Massimiliano},

  abstractNote = {A catalyst composition comprising a neutral bimetallic diphenoxydiiminate complex of group 10 metals or Ni, Pd or Pt is disclosed. The compositions can be used for the preparation of homo- and co-polymers of olefinic monomer compounds.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {Tue Aug 07 00:00:00 EDT 2012},

  month        = {Tue Aug 07 00:00:00 EDT 2012}

}

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Works referenced in this record:

Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
journal, January 2000

Younkin, T. R.
Science, Vol. 287, Issue 5452
https://doi.org/10.1126/science.287.5452.460

Late-Metal Catalysts for Ethylene Homo- and Copolymerization
journal, April 2000

Ittel, Steven D.; Johnson, Lynda K.; Brookhart, Maurice
Chemical Reviews, Vol. 100, Issue 4
https://doi.org/10.1021/cr9804644

Nuclearity and cooperativity effects in binuclear catalysts and cocatalysts for olefin polymerization
journal, October 2006

Li, H.; Marks, T. J.
Proceedings of the National Academy of Sciences, Vol. 103, Issue 42
https://doi.org/10.1073/pnas.0603396103

Advances in Non-Metallocene Olefin Polymerization Catalysis
journal, January 2003

Gibson, Vernon C.; Spitzmesser, Stefan K.
Chemical Reviews, Vol. 103, Issue 1
https://doi.org/10.1021/cr980461r

Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization
journal, April 2009

Rodriguez, Brandon A.; Delferro, Massimiliano; Marks, Tobin J.
Journal of the American Chemical Society, Vol. 131, Issue 16
https://doi.org/10.1021/ja900257k

Linear functionalized polyethylene prepared with highly active neutral Ni(II) complexes
journal, August 2002

Connor, Eric F.; Younkin, Todd R.; Henderson, Jason I.
Journal of Polymer Science Part A: Polymer Chemistry, Vol. 40, Issue 16
https://doi.org/10.1002/pola.10370

Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts
journal, January 2008

Salata, Michael R.; Marks, Tobin J.
Journal of the American Chemical Society, Vol. 130, Issue 1
https://doi.org/10.1021/ja076857e

Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization
journal, July 1998

Wang, Chunming; Friedrich, Stefan; Younkin, Todd R.
Organometallics, Vol. 17, Issue 15
https://doi.org/10.1021/om980176y

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Similar Records

Title: Neutral bimetallic transition metal phenoxyiminato catalysts and related polymerization methods

Abstract

Citation Formats

Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms journal, January 2000

Late-Metal Catalysts for Ethylene Homo- and Copolymerization journal, April 2000

Nuclearity and cooperativity effects in binuclear catalysts and cocatalysts for olefin polymerization journal, October 2006

Advances in Non-Metallocene Olefin Polymerization Catalysis journal, January 2003

Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization journal, April 2009

Linear functionalized polyethylene prepared with highly active neutral Ni(II) complexes journal, August 2002

Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts journal, January 2008

Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization journal, July 1998

Neutral, Single-Component Nickel (II) Polyolefin Catalysts That Tolerate Heteroatoms
journal, January 2000

Late-Metal Catalysts for Ethylene Homo- and Copolymerization
journal, April 2000

Nuclearity and cooperativity effects in binuclear catalysts and cocatalysts for olefin polymerization
journal, October 2006

Advances in Non-Metallocene Olefin Polymerization Catalysis
journal, January 2003

Bimetallic Effects for Enhanced Polar Comonomer Enchainment Selectivity in Catalytic Ethylene Polymerization
journal, April 2009

Linear functionalized polyethylene prepared with highly active neutral Ni(II) complexes
journal, August 2002

Synthesis, Characterization, and Marked Polymerization Selectivity Characteristics of Binuclear Phenoxyiminato Organozirconium Catalysts
journal, January 2008

Neutral Nickel(II)-Based Catalysts for Ethylene Polymerization
journal, July 1998