Method for synthesis of high quality graphene
Abstract
A method is described herein for the providing of high quality graphene layers on silicon carbide wafers in a thermal process. With two wafers facing each other in close proximity, in a first vacuum heating stage, while maintained at a vacuum of around 10.sup.-6 Torr, the wafer temperature is raised to about 1500.degree. C., whereby silicon evaporates from the wafer leaving a carbon rich surface, the evaporated silicon trapped in the gap between the wafers, such that the higher vapor pressure of silicon above each of the wafers suppresses further silicon evaporation. As the temperature of the wafers is raised to about 1530.degree. C. or more, the carbon atoms self assemble themselves into graphene.
- Inventors:
-
- Piedmont, CA
- Berkeley, CA
- Albany, CA
- Beneditkbeuern, DE
- Oakland, CA
- Issue Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1039209
- Patent Number(s):
- 8142754
- Application Number:
- 13/043,329
- Assignee:
- The Regents of the University of California (Oakland, CA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01B - NON-METALLIC ELEMENTS
- DOE Contract Number:
- AC02-05CH11231
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Lanzara, Alessandra, Schmid, Andreas K, Yu, Xiaozhu, Hwang, Choonkyu, Kohl, Annemarie, and Jozwiak, Chris M. Method for synthesis of high quality graphene. United States: N. p., 2012.
Web.
Lanzara, Alessandra, Schmid, Andreas K, Yu, Xiaozhu, Hwang, Choonkyu, Kohl, Annemarie, & Jozwiak, Chris M. Method for synthesis of high quality graphene. United States.
Lanzara, Alessandra, Schmid, Andreas K, Yu, Xiaozhu, Hwang, Choonkyu, Kohl, Annemarie, and Jozwiak, Chris M. Tue .
"Method for synthesis of high quality graphene". United States. https://www.osti.gov/servlets/purl/1039209.
@article{osti_1039209,
title = {Method for synthesis of high quality graphene},
author = {Lanzara, Alessandra and Schmid, Andreas K and Yu, Xiaozhu and Hwang, Choonkyu and Kohl, Annemarie and Jozwiak, Chris M},
abstractNote = {A method is described herein for the providing of high quality graphene layers on silicon carbide wafers in a thermal process. With two wafers facing each other in close proximity, in a first vacuum heating stage, while maintained at a vacuum of around 10.sup.-6 Torr, the wafer temperature is raised to about 1500.degree. C., whereby silicon evaporates from the wafer leaving a carbon rich surface, the evaporated silicon trapped in the gap between the wafers, such that the higher vapor pressure of silicon above each of the wafers suppresses further silicon evaporation. As the temperature of the wafers is raised to about 1530.degree. C. or more, the carbon atoms self assemble themselves into graphene.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 27 00:00:00 EDT 2012},
month = {Tue Mar 27 00:00:00 EDT 2012}
}
Works referenced in this record:
Thermodynamics and Kinetics of Graphene Growth on SiC(0001)
journal, March 2009
- Tromp, R. M.; Hannon, J. B.
- Physical Review Letters, Vol. 102, Issue 10
Self-doping effects in epitaxially grown graphene
journal, December 2008
- Siegel, D. A.; Zhou, S. Y.; El Gabaly, F.
- Applied Physics Letters, Vol. 93, Issue 24
Band Structure of Graphite
journal, January 1958
- Slonczewski, J. C.; Weiss, P. R.
- Physical Review, Vol. 109, Issue 2
Room-Temperature Quantum Hall Effect in Graphene
journal, March 2007
- Novoselov, K. S.; Jiang, Z.; Zhang, Y.
- Science, Vol. 315, Issue 5817
Growth of 6H and 4H–SiC by sublimation epitaxy
journal, February 1999
- Syväjärvi, M.; Yakimova, R.; Tuominen, M.
- Journal of Crystal Growth, Vol. 197, Issue 1-2
Two-dimensional gas of massless Dirac fermions in graphene
journal, November 2005
- Novoselov, K. S.; Geim, A. K.; Morozov, S. V.
- Nature, Vol. 438, Issue 7065, p. 197-200
Towards wafer-size graphene layers by atmospheric pressure graphitization of silicon carbide
journal, February 2009
- Emtsev, Konstantin V.; Bostwick, Aaron; Horn, Karsten
- Nature Materials, Vol. 8, Issue 3
Substrate-induced bandgap opening in epitaxial graphene
journal, September 2007
- Zhou, S. Y.; Gweon, G. -H.; Fedorov, A. V.
- Nature Materials, Vol. 6, Issue 10
Synthesis and characterization of atomically thin graphite films on a silicon carbide substrate
journal, September 2006
- Rollings, E.; Gweon, G. -H.; Zhou, S. Y.
- Journal of Physics and Chemistry of Solids, Vol. 67, Issue 9-10
Homogeneous large-area graphene layer growth on -SiC(0001)
journal, December 2008
- Virojanadara, C.; Syväjarvi, M.; Yakimova, R.
- Physical Review B, Vol. 78, Issue 24
Quasiparticle dynamics in graphene
journal, December 2006
- Bostwick, Aaron; Ohta, Taisuke; Seyller, Thomas
- Nature Physics, Vol. 3, Issue 1
Step-bunching in 6H-SiC growth by sublimation epitaxy
journal, November 1999
- Syväjärvi, M.; Yakimova, R.; Janzén, E.
- Journal of Physics: Condensed Matter, Vol. 11, Issue 49
Interlayer Interaction and Electronic Screening in Multilayer Graphene Investigated with Angle-Resolved Photoemission Spectroscopy
journal, May 2007
- Ohta, Taisuke; Bostwick, Aaron; McChesney, J. L.
- Physical Review Letters, Vol. 98, Issue 20
Pit formation during graphene synthesis on SiC(0001): In situ electron microscopy
journal, June 2008
- Hannon, J. B.; Tromp, R. M.
- Physical Review B, Vol. 77, Issue 24
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
Ultraflat graphene
journal, November 2009
- Lui, Chun Hung; Liu, Li; Mak, Kin Fai
- Nature, Vol. 462, Issue 7271
Detection of individual gas molecules adsorbed on graphene
journal, July 2007
- Schedin, F.; Geim, A. K.; Morozov, S. V.
- Nature Materials, Vol. 6, Issue 9, p. 652-655
Angle-resolved photoemission studies of the cuprate superconductors
journal, April 2003
- Damascelli, Andrea; Hussain, Zahid; Shen, Zhi-Xun
- Reviews of Modern Physics, Vol. 75, Issue 2
Large-scale pattern growth of graphene films for stretchable transparent electrodes
journal, January 2009
- Kim, Keun Soo; Zhao, Yue; Jang, Houk
- Nature, Vol. 457, Issue 7230
Giant Intrinsic Carrier Mobilities in Graphene and Its Bilayer
journal, January 2008
- Morozov, S. V.; Novoselov, K. S.; Katsnelson, M. I.
- Physical Review Letters, Vol. 100, Issue 1, Article No. 016602
Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004
- Novoselov, K. S.
- Science, Vol. 306, Issue 5696, p. 666-669
Ultrathin Epitaxial Graphite: 2D Electron Gas Properties and a Route toward Graphene-based Nanoelectronics
journal, December 2004
- Berger, Claire; Song, Zhimin; Li, Tianbo
- The Journal of Physical Chemistry B, Vol. 108, Issue 52, p. 19912-19916
Spin qubits in graphene quantum dots
journal, February 2007
- Trauzettel, Björn; Bulaev, Denis V.; Loss, Daniel
- Nature Physics, Vol. 3, Issue 3
Growth mechanism for epitaxial graphene on vicinal surfaces: A scanning tunneling microscopy study
journal, July 2009
- Hupalo, M.; Conrad, E. H.; Tringides, M. C.
- Physical Review B, Vol. 80, Issue 4