Methods for forming particles from single source precursors
Abstract
Single source precursors are subjected to carbon dioxide to form particles of material. The carbon dioxide may be in a supercritical state. Single source precursors also may be subjected to supercritical fluids other than supercritical carbon dioxide to form particles of material. The methods may be used to form nanoparticles. In some embodiments, the methods are used to form chalcopyrite materials. Devices such as, for example, semiconductor devices may be fabricated that include such particles. Methods of forming semiconductor devices include subjecting single source precursors to carbon dioxide to form particles of semiconductor material, and establishing electrical contact between the particles and an electrode.
- Inventors:
-
- Idaho Falls, ID
- Pocatello, ID
- Issue Date:
- Research Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1024113
- Patent Number(s):
- 8003070
- Application Number:
- 12/047,956
- Assignee:
- Battelle Energy Alliance, LLC (Idaho Falls, ID)
- Patent Classifications (CPCs):
-
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01L - SEMICONDUCTOR DEVICES
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- DOE Contract Number:
- AC07-05ID14517
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Fox, Robert V, Rodriguez, Rene G, and Pak, Joshua. Methods for forming particles from single source precursors. United States: N. p., 2011.
Web.
Fox, Robert V, Rodriguez, Rene G, & Pak, Joshua. Methods for forming particles from single source precursors. United States.
Fox, Robert V, Rodriguez, Rene G, and Pak, Joshua. Tue .
"Methods for forming particles from single source precursors". United States. https://www.osti.gov/servlets/purl/1024113.
@article{osti_1024113,
title = {Methods for forming particles from single source precursors},
author = {Fox, Robert V and Rodriguez, Rene G and Pak, Joshua},
abstractNote = {Single source precursors are subjected to carbon dioxide to form particles of material. The carbon dioxide may be in a supercritical state. Single source precursors also may be subjected to supercritical fluids other than supercritical carbon dioxide to form particles of material. The methods may be used to form nanoparticles. In some embodiments, the methods are used to form chalcopyrite materials. Devices such as, for example, semiconductor devices may be fabricated that include such particles. Methods of forming semiconductor devices include subjecting single source precursors to carbon dioxide to form particles of semiconductor material, and establishing electrical contact between the particles and an electrode.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 23 00:00:00 EDT 2011},
month = {Tue Aug 23 00:00:00 EDT 2011}
}
Works referenced in this record:
Synthesis of Cu−In−S Ternary Nanocrystals with Tunable Structure and Composition
journal, April 2008
- Pan, Daocheng; An, Lijia; Sun, Zhongming
- Journal of the American Chemical Society, Vol. 130, Issue 17
Microwave-Assisted Polyol Synthesis of CuInTe 2 and CuInSe 2 Nanoparticles
journal, November 2003
- Grisaru, Haviv; Palchik, Oleg; Gedanken, Aharon
- Inorganic Chemistry, Vol. 42, Issue 22
Microwave enhanced synthesis of N-propargyl derivatives of imidazole
journal, June 2006
- Perozo-Rondón, Elizabeth; Costarrosa, Laureano; Martín-Aranda, Rosa M.
- Applied Surface Science, Vol. 252, Issue 17, p. 6067-6070
Microwave-assisted solvent extraction and gas chromatography ion trap mass spectrometry procedure for the determination of persistent organochlorine pesticides (POPs) in marine sediment
journal, May 2006
- Carro, Nieves; García, Isabel; Ignacio, María
- Analytical and Bioanalytical Chemistry, Vol. 385, Issue 5
Green chemistry: Efficient epoxides ring-opening with 1-butanol under microwave irradiation
journal, June 2006
- García-Vidal, Jesús A.; Durán-Valle, Carlos J.; Ferrera-Escudero, Santiago
- Applied Surface Science, Vol. 252, Issue 17, p. 6064-6066
Microwave-Assisted Chemical Reactions
journal, December 2003
- Nüchter, M.; Müller, U.; Ondruschka, B.
- Chemical Engineering & Technology, Vol. 26, Issue 12, p. 1207-1216
Synthesis and Characterization of Indium Oxide Nanoparticles
journal, June 2001
- Murali, Amith; Barve, Anirudha; Leppert, Valerie J.
- Nano Letters, Vol. 1, Issue 6
Rapid synthesis and size control of CuInS2 semi-conductor nanoparticles using microwave irradiation
journal, October 2007
- Gardner, Joseph S.; Shurdha, Endrit; Wang, Chongmin
- Journal of Nanoparticle Research, Vol. 10, Issue 4
Physico-chemical characterisation of Cu(In,Al)Se2 thin film for solar cells obtained by a selenisation process
journal, June 2005
- Halgand, E.; Bernède, J. C.; Marsillac, S.
- Thin Solid Films, Vol. 480-481, p. 443-446
Preparation of Ultrafine Chalcopyrite Nanoparticles via the Photochemical Decomposition of Molecular Single-Source Precursors
journal, June 2006
- Nairn, Justin J.; Shapiro, Pamela J.; Twamley, Brendan
- Nano Letters, Vol. 6, Issue 6
A New Facile Route for the Preparation of Single-Source Precursors for Bulk, Thin-Film, and Nanocrystallite I−III−VI Semiconductors
journal, December 2003
- Banger, Kulbinder K.; Jin, Michael H. -C.; Harris, Jerry D.
- Inorganic Chemistry, Vol. 42, Issue 24
Optimization of Microwave Digestion for Mercury Determination in Marine Biological Samples by Cold Vapour Atomic Absorption Spectrometry
journal, April 2006
- Cardellicchio, Nicola; di Leo, Antonella; Giandomenico, Santina
- Annali di Chimica, Vol. 96, Issue 3-4
Pulsed-Spray Radiofrequency Plasma Enhanced Chemical Vapor Deposition of CuInS2 Thin Films
journal, April 2006
- Rodriguez, Rene G.; Pulsipher, Daniel J. V.; Lau, Lisa D.
- Plasma Chemistry and Plasma Processing, Vol. 26, Issue 2
Facile modulation of single source precursors: the synthesis and characterization of single source precursors for deposition of ternary chalcopyrite materials
journal, February 2002
- Banger, K. K.; Harris, J. D.; Cowen, J. E.
- Thin Solid Films, Vol. 403-404, p. 390-395
Hybrid Nanorod-Polymer Solar Cells
journal, March 2002
- Huynh, W. U.; Dittmer, Janke J.; Alivisatos, A. Paul
- Science, Vol. 295, Issue 5564, p. 2425-2427
Ultrasmall Metal Oxide Particles: Preparation, Photophysical Characterization, and Photocatalytic Properties
journal, January 1993
- Bahnemann, Detlef W.
- Israel Journal of Chemistry, Vol. 33, Issue 1
Synthesis of Monodispersed Wurtzite Structure CuInSe 2 Nanocrystals and Their Application in High-Performance Organic−Inorganic Hybrid Photodetectors
journal, September 2010
- Wang, Jian-Jun; Wang, Yong-Qing; Cao, Fei-Fei
- Journal of the American Chemical Society, Vol. 132, Issue 35
Increasing the Efficiency of Ideal Solar Cells by Photon Induced Transitions at Intermediate Levels
journal, June 1997
- Luque, Antonio; Martí, Antonio
- Physical Review Letters, Vol. 78, Issue 26
One-Pot Synthesis of Copper−Indium Sulfide Nanocrystal Heterostructures with Acorn, Bottle, and Larva Shapes
journal, March 2006
- Choi, Sang-Hyun; Kim, Eung-Gyu; Hyeon, Taeghwan
- Journal of the American Chemical Society, Vol. 128, Issue 8
Microwave assisted synthesis – a critical technology overview
journal, January 2004
- Nüchter, M.; Ondruschka, B.; Bonrath, W.
- Green Chem., Vol. 6, Issue 3
Optimisation of microwave assisted digestion of sediments and determination of Sn and Hg
journal, April 2006
- Navarro, P.; Raposo, J. C.; Arana, G.
- Analytica Chimica Acta, Vol. 566, Issue 1, p. 37-44
Synthesis of CuInSe<sub>2</sub> and CuInGaSe<sub>2</sub> Nanoparticles by Solvothermal Route
journal, March 2004
- Kim, Ki Hyun; Chun, Young Gab; Park, Byung Ok
- Materials Science Forum, Vol. 449-452
Applications of microwave dielectric heating in environment-related heterogeneous gas-phase catalytic systems
journal, August 2006
- Zhang, Xunli; Hayward, David O.
- Inorganica Chimica Acta, Vol. 359, Issue 11, p. 3421-3433
Microwave-Enhanced Reaction Rates for Nanoparticle Synthesis
journal, November 2005
- Gerbec, Jeffrey A.; Magana, Donny; Washington, Aaron
- Journal of the American Chemical Society, Vol. 127, Issue 45
Phase Transformation of Biphasic Cu 2 S−CuInS 2 to Monophasic CuInS 2 Nanorods
journal, April 2009
- Connor, Stephen T.; Hsu, Ching-Mei; Weil, Benjamin D.
- Journal of the American Chemical Society, Vol. 131, Issue 13
A High-Yield Synthesis of Chalcopyrite CuIn Nanoparticles with Exceptional Size Control
journal, January 2009
- Sun, Chivin; Gardner, Joseph S.; Shurdha, Endrit
- Journal of Nanomaterials, Vol. 2009
Microwave-assisted alkaline digestion combined with microwave-assisted distillation for the determination of iodide and total iodine in edible seaweed by catalytic spectrophotometry
journal, June 2005
- Gamallo-Lorenzo, Diego; Barciela-Alonso, María del Carmen; Moreda-Piñeiro, Antonio
- Analytica Chimica Acta, Vol. 542, Issue 2, p. 287-295
Synthesis of Metastable Wurtzite CuInSe 2 Nanocrystals
journal, March 2010
- Norako, Michelle E.; Brutchey, Richard L.
- Chemistry of Materials, Vol. 22, Issue 5
Synthesis and Characterization of Nanostructured Wurtzite CuInS 2 : A New Cation Disordered Polymorph of CuInS 2
journal, February 2009
- Qi, Yunxia; Liu, Qiangchun; Tang, Kaibin
- The Journal of Physical Chemistry C, Vol. 113, Issue 10
A facile route to the synthesis of CuInS2 nanoparticles
journal, August 2006
- P. Dutta, Dimple; Sharma, Garima
- Materials Letters, Vol. 60, Issue 19, p. 2395-2398
Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties
journal, January 1991
- Wang, Ying; Herron, N.
- The Journal of Physical Chemistry, Vol. 95, Issue 2, p. 525-532
Synthesis and Characterization of the First Liquid Single-Source Precursors for the Deposition of Ternary Chalcopyrite (CuInS 2 ) Thin Film Materials
journal, November 2001
- Banger, Kulbinder K.; Cowen, Jonathan; Hepp, Aloysius F.
- Chemistry of Materials, Vol. 13, Issue 11
Changes in carrier dynamics induced by proton irradiation in quantum dots
journal, March 2002
- Marcinkevičius, S.; Leon, R.; Čechavičius, B.
- Physica B: Condensed Matter, Vol. 314, Issue 1-4, p. 203-206
Synthesis of CuInS 2 Nanocubes by a Wet Chemical Process
journal, September 2005
- Wei, Qinglian; Mu, Jin
- Journal of Dispersion Science and Technology, Vol. 26, Issue 5
Synthesis of mixed copper-indium chalcogenolates. Single-source precursors for the photovoltaic materials CuInQ2 (Q = S, Se)
journal, February 1993
- Hirpo, Wakgari; Dhingra, Sandeep; Sutorik, Anthony C.
- Journal of the American Chemical Society, Vol. 115, Issue 4, p. 1597-1599
Surface structure of CuGaSe2 (001)
journal, June 2005
- Deniozou, Th.; Esser, N.; Siebentritt, S.
- Thin Solid Films, Vol. 480-481, p. 382-387
An efficient synthesis of 4,4′,5,5′-tetraiododibenzo-24-crown-8 and its highly conjugated derivatives
journal, January 2006
- Pak, Joshua J.; Mayo, Jaime L.; Shurdha, Endrit
- Tetrahedron Letters, Vol. 47, Issue 2
Preparation and characterization of CuInS2 thin films completely converted from CuInSe2 by sulfurization
journal, June 2005
- Liu, C. P.; Tseng, B. H.
- Thin Solid Films, Vol. 480-481, p. 50-54
Semiconductor Nanoparticles on Solid Substrates: Film Structure, Intermolecular Interactions, and Polyelectrolyte Effects
journal, September 2002
- Tang, Zhiyong; Wang, Ying; Kotov, Nicholas A.
- Langmuir, Vol. 18, Issue 18
Synthesis and Characterization of Colloidal CuInS 2 Nanoparticles from a Molecular Single-Source Precursor
journal, August 2004
- Castro, Stephanie L.; Bailey, Sheila G.; Raffaelle, Ryne P.
- The Journal of Physical Chemistry B, Vol. 108, Issue 33
Nanocrystalline Chalcopyrite Materials (CuInS 2 and CuInSe 2 ) via Low-Temperature Pyrolysis of Molecular Single-Source Precursors
journal, August 2003
- Castro, Stephanie L.; Bailey, Sheila G.; Raffaelle, Ryne P.
- Chemistry of Materials, Vol. 15, Issue 16
Comparison of three optimized digestion methods for rapid determination of chemical oxygen demand: Closed microwaves, open microwaves and ultrasound irradiation
journal, March 2006
- Domini, Claudia E.; Hidalgo, Montserrat; Marken, Frank
- Analytica Chimica Acta, Vol. 561, Issue 1-2, p. 210-217
Microwave Assisted Preparation of CdSe, PbSe, and Cu 2 - x Se Nanoparticles
journal, August 2000
- Zhu, Junjie; Palchik, O.; Chen, Siguang
- The Journal of Physical Chemistry B, Vol. 104, Issue 31