Title: Method of producing imines

Abstract

A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.

Inventors:

Sithambaram, Shanthakumar ^[1]; Son, Young-Chan ^[1]; Suib, Steven L ^[1]

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+ Show Inventor Affiliations

1. Storrs, CT

Issue Date:

2008-04-08

Research Org.:

The University of Connecticut (Farmington, CT)

Sponsoring Org.:

USDOE

OSTI Identifier:

985687

Patent Number(s):

7355075

Application Number:

11/424,688

Assignee:

The University of Connecticut (Farmington, CT)

Patent Classifications (CPCs):

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C251/16 - containing six-membered aromatic rings
C07C251/08 - being acyclic
C07C2601/14 - The ring being saturated
C07C251/24 - having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
C07C2601/08 - the ring being saturated
C07C251/18 - having carbon atoms of imino groups bound to carbon atoms of rings other than six-membered aromatic rings

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

C07D241/06 - having one or two double bonds between ring members or between ring members and non-ring members

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

C07C249/02 - of compounds containing imino groups

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

C07D333/22 - Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom

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DOE Contract Number:  

FG02-86ER13662

Resource Type:

Patent

Country of Publication:

United States

Language:

English

Subject:

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY