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Title: Method of producing imines

Abstract

A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.

Inventors:
 [1];  [1];  [1]
  1. Storrs, CT
Issue Date:
Research Org.:
The University of Connecticut (Farmington, CT)
Sponsoring Org.:
USDOE
OSTI Identifier:
985687
Patent Number(s):
7355075
Application Number:
11/424,688
Assignee:
The University of Connecticut (Farmington, CT)
Patent Classifications (CPCs):
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS
DOE Contract Number:  
FG02-86ER13662
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Sithambaram, Shanthakumar, Son, Young-Chan, and Suib, Steven L. Method of producing imines. United States: N. p., 2008. Web.
Sithambaram, Shanthakumar, Son, Young-Chan, & Suib, Steven L. Method of producing imines. United States.
Sithambaram, Shanthakumar, Son, Young-Chan, and Suib, Steven L. Tue . "Method of producing imines". United States. https://www.osti.gov/servlets/purl/985687.
@article{osti_985687,
title = {Method of producing imines},
author = {Sithambaram, Shanthakumar and Son, Young-Chan and Suib, Steven L},
abstractNote = {A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2008},
month = {4}
}

Works referenced in this record:

Conversion of alcohols into N-alkyl anilines via an indirect aza-Wittig reaction
journal, January 2004


Synthesis of imines, diimines and macrocyclic diimines as possible ligands, in aqueous solution
journal, January 2001


A Review of Porous Manganese Oxide Materials
journal, October 1998


Molecular Sieves in Ionic Liquids as an Efficient and Recyclable Medium for the Synthesis of Imines
journal, January 2004


Some reactions of ammonia and primary amines with propanal, 2-chloroethanal, 2,2-dichloroethanal and 2,2,2-trichloroethanal in acetonitrile
journal, January 1997


Imines, enamines and oximes
journal, January 2000


Magnesium perchlorate as an efficient catalyst for the synthesis of imines and phenylhydrazones
journal, October 2004


Manganese Oxide Octahedral Molecular Sieves: Preparation, Characterization, and Applications
journal, April 1993


In Situ Oxidation−Imine Formation−Reduction Routes from Alcohols to Amines
journal, May 2001


Synthesis and Characterization of Octahedral Molecular Sieves (OMS-2) Having the Hollandite Structure
journal, June 1994