Method for reducing NOx during combustion of coal in a burner

Zhou, Bing; Parasher, Sukesh; Hare, Jeffrey J; Harding, N Stanley; Black, Stephanie E; Johnson, Kenneth R

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Title: Method for reducing NOx during combustion of coal in a burner

Abstract

An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.

Inventors:

Zhou, Bing ^[1]; Parasher, Sukesh ^[2]; Hare, Jeffrey J ^[3]; Harding, N Stanley ^[4]; Black, Stephanie E ^[5]; Johnson, Kenneth R ^[6]

Cranbury, NJ
Lawrenceville, NJ
Provo, UT
North Salt Lake, UT
Sandy, UT
Highland, UT

Issue Date:: 2008-04-15

Research Org.:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 985660

Patent Number(s):: 7357903

Application Number:: 11/129,833

Assignee:: Headwaters Heavy Oil, LLC (South Jordan, UT)

Patent Classifications (CPCs):: A - HUMAN NECESSITIES A24 - TOBACCO A24B - MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION

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A - HUMAN NECESSITIES A24 - TOBACCO A24B - MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING
A24B15/28 - by chemical substances
A24B15/286 - {Nanoparticles}
A24B15/288 - {Catalysts or catalytic material, e.g. included in the wrapping material}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B01D53/8625 - {Nitrogen oxides}

Show less

DOE Contract Number:: FG26-02NT41618

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 01 COAL, LIGNITE, AND PEAT

Citation Formats


                    Zhou, Bing, Parasher, Sukesh, Hare, Jeffrey J, Harding, N Stanley, Black, Stephanie E, and Johnson, Kenneth R. Method for reducing NOx during combustion of coal in a burner.  United States: N. p., 2008. 
        Web.

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                    Zhou, Bing, Parasher, Sukesh, Hare, Jeffrey J, Harding, N Stanley, Black, Stephanie E, & Johnson, Kenneth R. Method for reducing NOx during combustion of coal in a burner.  United States.

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                    Zhou, Bing, Parasher, Sukesh, Hare, Jeffrey J, Harding, N Stanley, Black, Stephanie E, and Johnson, Kenneth R. Tue .  
        "Method for reducing NOx during combustion of coal in a burner".  United States.  https://www.osti.gov/servlets/purl/985660.

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@article{osti_985660,

  title        = {Method for reducing NOx during combustion of coal in a burner},

  author       = {Zhou, Bing and Parasher, Sukesh and Hare, Jeffrey J and Harding, N Stanley and Black, Stephanie E and Johnson, Kenneth R},

  abstractNote = {An organically complexed nanocatalyst composition is applied to or mixed with coal prior to or upon introducing the coal into a coal burner in order to catalyze the removal of coal nitrogen from the coal and its conversion into nitrogen gas prior to combustion of the coal. This process leads to reduced NOx production during coal combustion. The nanocatalyst compositions include a nanoparticle catalyst that is made using a dispersing agent that can bond with the catalyst atoms. The dispersing agent forms stable, dispersed, nano-sized catalyst particles. The catalyst composition can be formed as a stable suspension to facilitate storage, transportation and application of the catalyst nanoparticles to a coal material. The catalyst composition can be applied before or after pulverizing the coal material or it may be injected directly into the coal burner together with pulverized coal.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2008},

  month        = {4}

}

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Works referenced in this record:

Selective conversion of coal nitrogen to N2 with iron
journal, November 1993

Ohtsuka, Yasuo; Mori, Hiroshi; Nonaka, Katsutoshi
Energy & Fuels, Vol. 7, Issue 6
https://doi.org/10.1021/ef00042a056

Novel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell
journal, January 2003

Zhou, Zhenhua; Wang, Suli; Zhou, Weijiang
Chemical Communications, Issue 3
https://doi.org/10.1039/b211075j

Remarkable Formation of N ₂ from a Chinese Lignite during Coal Pyrolysis
journal, January 1996

Wu, Zhiheng; Ohtsuka, Yasuo
Energy & Fuels, Vol. 10, Issue 6
https://doi.org/10.1021/ef960050i

Method for Supporting Platinum on Single-Walled Carbon Nanotubes for a Selective Hydrogenation Catalyst
journal, March 2001

Lordi, Vincenzo; Yao, Nan; Wei, James
Chemistry of Materials, Vol. 13, Issue 3
https://doi.org/10.1021/cm000210a

Catalytic nitrogen release during a fixed-bed pyrolysis of model coals containing pyrrolic or pyridinic nitrogen
journal, January 2001

Wu, Zhiheng; Sugimoto, Y.; Kawashima, H.
Fuel, Vol. 80, Issue 2
https://doi.org/10.1016/S0016-2361(00)00085-5

Nitrogen removal during atmospheric-pressure pyrolysis of brown coal with iron
journal, July 1994

Ohtsuka, Y.; Mori, H.; Watanabe, T.
Fuel, Vol. 73, Issue 7
https://doi.org/10.1016/0016-2361(94)90243-7

Highly active iron catalysts from ferric chloride for the steam gasification of brown coal
journal, August 1993

Asami, Kenji; Ohtsuka, Yasuo
Industrial & Engineering Chemistry Research, Vol. 32, Issue 8
https://doi.org/10.1021/ie00020a014

Carbon nanotubes as support for cathode catalyst of a direct methanol fuel cell
journal, April 2002

Li, Wenzhen; Liang, Changhai; Qiu, Jieshan
Carbon, Vol. 40, Issue 5
https://doi.org/10.1016/S0008-6223(02)00039-8

Nitrogen Distribution in a Fixed Bed Pyrolysis of Coals with Different Ranks: Formation and Source of N ₂
journal, March 1997

Wu, Zhiheng; Ohtsuka, Yasuo
Energy & Fuels, Vol. 11, Issue 2
https://doi.org/10.1021/ef9601226

Char-Nitrogen Functionality and Interactions between the Nitrogen and Iron in the Iron-Catalyzed Conversion Process of Coal Nitrogen to N ₂
journal, November 1998

Ohtsuka, Yasuo; Watanabe, Takashi; Asami, Kenji
Energy & Fuels, Vol. 12, Issue 6
https://doi.org/10.1021/ef980100e

Nitrogen release during high temperature pyrolysis of coals and catalytic role of calcium in N2 formation
journal, December 2002

Tsubouchi, Naoto; Ohtsuka, Yasuo
Fuel, Vol. 81, Issue 18
https://doi.org/10.1016/S0016-2361(02)00173-4

Formation of Nitrogen-Containing Compounds during Slow Pyrolysis and Oxidation of Petroleum Coke
journal, September 1997

Furimsky, Edward; Ohtsuka, Yasuo
Energy & Fuels, Vol. 11, Issue 5
https://doi.org/10.1021/ef970009v

Spectroscopic studies of coal maceral depolymerization effected by an iron-based catalyst
journal, July 1992

Wang, H. Paul; Lo, Robert; Sommerfeld, David A.
Fuel, Vol. 71, Issue 7
https://doi.org/10.1016/0016-2361(92)90120-D

Key Factors for Formation of N ₂ from Low-Rank Coals during Fixed Bed Pyrolysis: Pyrolysis Conditions and Inherent Minerals
journal, July 1997

Wu, Zhiheng; Ohtsuka, Yasuo
Energy & Fuels, Vol. 11, Issue 4
https://doi.org/10.1021/ef9700238

Role of Iron Catalyst in Fate of Fuel Nitrogen during Coal Pyrolysis
journal, January 1996

Mori, Hiroshi; Asami, Kenji; Ohtsuka, Yasuo
Energy & Fuels, Vol. 10, Issue 4
https://doi.org/10.1021/ef960035d

Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles
journal, June 1996

Ahmadi, T. S.; Wang, Z. L.; Green, T. C.
Science, Vol. 272, Issue 5270, p. 1924-1925
https://doi.org/10.1126/science.272.5270.1924

Preparation and Characterization of Multiwalled Carbon Nanotube-Supported Platinum for Cathode Catalysts of Direct Methanol Fuel Cells
journal, July 2003

Li, Wenzhen; Liang, Changhai; Zhou, Weijiang
The Journal of Physical Chemistry B, Vol. 107, Issue 26
https://doi.org/10.1021/jp022505c

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Similar Records

Title: Method for reducing NOx during combustion of coal in a burner

Abstract

Citation Formats

Selective conversion of coal nitrogen to N2 with iron journal, November 1993

Novel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell journal, January 2003

Remarkable Formation of N 2 from a Chinese Lignite during Coal Pyrolysis journal, January 1996

Method for Supporting Platinum on Single-Walled Carbon Nanotubes for a Selective Hydrogenation Catalyst journal, March 2001

Catalytic nitrogen release during a fixed-bed pyrolysis of model coals containing pyrrolic or pyridinic nitrogen journal, January 2001

Nitrogen removal during atmospheric-pressure pyrolysis of brown coal with iron journal, July 1994

Highly active iron catalysts from ferric chloride for the steam gasification of brown coal journal, August 1993

Carbon nanotubes as support for cathode catalyst of a direct methanol fuel cell journal, April 2002

Nitrogen Distribution in a Fixed Bed Pyrolysis of Coals with Different Ranks: Formation and Source of N 2 journal, March 1997

Char-Nitrogen Functionality and Interactions between the Nitrogen and Iron in the Iron-Catalyzed Conversion Process of Coal Nitrogen to N 2 journal, November 1998

Nitrogen release during high temperature pyrolysis of coals and catalytic role of calcium in N2 formation journal, December 2002

Formation of Nitrogen-Containing Compounds during Slow Pyrolysis and Oxidation of Petroleum Coke journal, September 1997

Spectroscopic studies of coal maceral depolymerization effected by an iron-based catalyst journal, July 1992

Key Factors for Formation of N 2 from Low-Rank Coals during Fixed Bed Pyrolysis: Pyrolysis Conditions and Inherent Minerals journal, July 1997

Role of Iron Catalyst in Fate of Fuel Nitrogen during Coal Pyrolysis journal, January 1996

Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles journal, June 1996

Preparation and Characterization of Multiwalled Carbon Nanotube-Supported Platinum for Cathode Catalysts of Direct Methanol Fuel Cells journal, July 2003

Selective conversion of coal nitrogen to N2 with iron
journal, November 1993

Novel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell
journal, January 2003

Remarkable Formation of N ₂ from a Chinese Lignite during Coal Pyrolysis
journal, January 1996

Method for Supporting Platinum on Single-Walled Carbon Nanotubes for a Selective Hydrogenation Catalyst
journal, March 2001

Catalytic nitrogen release during a fixed-bed pyrolysis of model coals containing pyrrolic or pyridinic nitrogen
journal, January 2001

Nitrogen removal during atmospheric-pressure pyrolysis of brown coal with iron
journal, July 1994

Highly active iron catalysts from ferric chloride for the steam gasification of brown coal
journal, August 1993

Carbon nanotubes as support for cathode catalyst of a direct methanol fuel cell
journal, April 2002

Nitrogen Distribution in a Fixed Bed Pyrolysis of Coals with Different Ranks: Formation and Source of N ₂
journal, March 1997

Char-Nitrogen Functionality and Interactions between the Nitrogen and Iron in the Iron-Catalyzed Conversion Process of Coal Nitrogen to N ₂
journal, November 1998

Nitrogen release during high temperature pyrolysis of coals and catalytic role of calcium in N2 formation
journal, December 2002

Formation of Nitrogen-Containing Compounds during Slow Pyrolysis and Oxidation of Petroleum Coke
journal, September 1997

Spectroscopic studies of coal maceral depolymerization effected by an iron-based catalyst
journal, July 1992

Key Factors for Formation of N ₂ from Low-Rank Coals during Fixed Bed Pyrolysis: Pyrolysis Conditions and Inherent Minerals
journal, July 1997

Role of Iron Catalyst in Fate of Fuel Nitrogen during Coal Pyrolysis
journal, January 1996

Shape-Controlled Synthesis of Colloidal Platinum Nanoparticles
journal, June 1996

Preparation and Characterization of Multiwalled Carbon Nanotube-Supported Platinum for Cathode Catalysts of Direct Methanol Fuel Cells
journal, July 2003