MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments
Abstract
A method includes containing a high-temperature alkali salt containing environment using a refractory containment liner containing MgAl.sub.2O.sub.4 spinel. A method, includes forming a refractory brick containing MgAl.sub.2O.sub.4 spinel having an exterior chill zone defined by substantially columnar crystallization and an interior zone defined by substantially equiaxed crystallization; and removing at least a portion of the exterior chill zone from the refractory brick containing MgAl.sub.2O.sub.4 spinel by scalping the refractory brick containing MgAl.sub.2O.sub.4 spinel to define at least one outer surface having an area of substantially equiaxed crystallization. A product of manufacture includes a refractory brick containing MgAl.sub.2O.sub.4 spinel including an interior zone defined by substantially equiaxed crystallization; and at least one outer surface having an area of substantially equiaxed crystallization.
- Inventors:
-
- Knoxville, TN
- Oak Ridge, TN
- Kent, WA
- Jamestown, NY
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 985347
- Patent Number(s):
- 7438004
- Application Number:
- 11/207,320
- Assignee:
- UT-Battelle, LLC (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C04 - CEMENTS C04B - LIME, MAGNESIA
C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10J - PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES
- DOE Contract Number:
- AC05-00OR22725
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Peascoe-Meisner, Roberta A, Keiser, James R, Hemric, James G, Hubbard, Camden R, Gorog, J Peter, and Gupta, Amul. MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments. United States: N. p., 2008.
Web.
Peascoe-Meisner, Roberta A, Keiser, James R, Hemric, James G, Hubbard, Camden R, Gorog, J Peter, & Gupta, Amul. MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments. United States.
Peascoe-Meisner, Roberta A, Keiser, James R, Hemric, James G, Hubbard, Camden R, Gorog, J Peter, and Gupta, Amul. Tue .
"MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments". United States. https://www.osti.gov/servlets/purl/985347.
@article{osti_985347,
title = {MgAl2O4 spinel refractory as containment liner for high-temperature alkali salt containing environments},
author = {Peascoe-Meisner, Roberta A and Keiser, James R and Hemric, James G and Hubbard, Camden R and Gorog, J Peter and Gupta, Amul},
abstractNote = {A method includes containing a high-temperature alkali salt containing environment using a refractory containment liner containing MgAl.sub.2O.sub.4 spinel. A method, includes forming a refractory brick containing MgAl.sub.2O.sub.4 spinel having an exterior chill zone defined by substantially columnar crystallization and an interior zone defined by substantially equiaxed crystallization; and removing at least a portion of the exterior chill zone from the refractory brick containing MgAl.sub.2O.sub.4 spinel by scalping the refractory brick containing MgAl.sub.2O.sub.4 spinel to define at least one outer surface having an area of substantially equiaxed crystallization. A product of manufacture includes a refractory brick containing MgAl.sub.2O.sub.4 spinel including an interior zone defined by substantially equiaxed crystallization; and at least one outer surface having an area of substantially equiaxed crystallization.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2008},
month = {10}
}
Works referenced in this record:
Study of mixed á/â-alumina and pure â-alumina fused cast refractories after exposure in the black liquor gasifier in New Bern, North Carolina. CRADA final report
report, March 1999
- Hoffmann, C. M.; Hubbard, C. R.; Keiser, J. R.
Reaction of molten sodium carbonate with aluminum oxide
journal, January 1978
- Christie, J. R.; Darnell, A. J.; Dustin, D. F.
- The Journal of Physical Chemistry, Vol. 82, Issue 1