Catalytic reactive separation system for energy-efficient production of cumene
Abstract
The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.
- Inventors:
-
- Nuevo Laredo, MX
- Albuquerque, NM
- Issue Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 968335
- Patent Number(s):
- 7566429
- Application Number:
- 11/152,997
- Assignee:
- Sandia Corporation (Albuquerque, NM)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01D - SEPARATION
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
- DOE Contract Number:
- AC04-94AL85000
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Buelna, Genoveva, and Nenoff, Tina M. Catalytic reactive separation system for energy-efficient production of cumene. United States: N. p., 2009.
Web.
Buelna, Genoveva, & Nenoff, Tina M. Catalytic reactive separation system for energy-efficient production of cumene. United States.
Buelna, Genoveva, and Nenoff, Tina M. Tue .
"Catalytic reactive separation system for energy-efficient production of cumene". United States. https://www.osti.gov/servlets/purl/968335.
@article{osti_968335,
title = {Catalytic reactive separation system for energy-efficient production of cumene},
author = {Buelna, Genoveva and Nenoff, Tina M},
abstractNote = {The present invention relates to an atmospheric pressure, reactive separation column packed with a solid acid zeolite catalyst for producing cumene from the reaction of benzene with propylene. Use of this un-pressurized column, where simultaneous reaction and partial separation occur during cumene production, allow separation of un-reacted, excess benzene from other products as they form. This high-yielding, energy-efficient system allows for one-step processing of cumene, with reduced need for product purification. Reacting propylene and benzene in the presence of beta zeolite catalysts generated a selectivity greater than 85% for catalytic separation reactions at a reaction temperature of 115 degrees C and at ambient pressure. Simultaneously, up to 76% of un-reacted benzene was separated from the product; which could be recycled back to the reactor for re-use.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 28 00:00:00 EDT 2009},
month = {Tue Jul 28 00:00:00 EDT 2009}
}
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Reactive distillation — industrial applications, process design & scale-up
journal, January 2001
- Tuchlenski, A.; Beckmann, A.; Reusch, D.
- Chemical Engineering Science, Vol. 56, Issue 2
Alkylation of Benzene with Short-Chain Olefins over MCM-22 Zeolite: Catalytic Behaviour and Kinetic Mechanism
journal, May 2000
- Corma, A.; Martı́nez-Soria, V.; Schnoeveld, E.
- Journal of Catalysis, Vol. 192, Issue 1
Acetalization of ethylene glycol with formaldehyde using cation-exchange resins as catalysts: batch versus reactive distillation
journal, September 1997
- Chopade, Shubham P.; Sharma, Man Mohan
- Reactive and Functional Polymers, Vol. 34, Issue 1
Alkylation of benzene by propene on a series of Beta zeolites: toward a better understanding of the mechanisms
journal, March 2000
- Siffert, S.; Gaillard, L.; Su, B. -L
- Journal of Molecular Catalysis A: Chemical, Vol. 153, Issue 1-2
Reactive distillation: Non-ideal flow behaviour of the liquid phase in structured catalytic packings
journal, May 2002
- Noeres, C.; Hoffmann, A.; Górak, A.
- Chemical Engineering Science, Vol. 57, Issue 9
Scale-up of reactive distillation columns with catalytic packings
journal, March 2004
- Hoffmann, Achim; Noeres, Christoph; Górak, Andrzej
- Chemical Engineering and Processing: Process Intensification, Vol. 43, Issue 3
Study on alkylation of benzene with ethylene over β-zeolite catalyst to ethylbenzene by in situ IR
journal, February 2002
- Du, Yingchun; Wang, Hai; Chen, Shu
- Journal of Molecular Catalysis A: Chemical, Vol. 179, Issue 1-2
A New, Improved, Solid-Acid Catalyzed Process for Generating Linear Alkylbenzenes (LABs)
journal, August 2001
- Knifton, John F.; Anantaneni, Prakasa Rao; Dai, P. Eugene
- Catalysis Letters, Vol. 75, Issue 1/2, p. 113-117
Multifunctional reactors
journal, June 1992
- Westerterp, K. R.
- Chemical Engineering Science, Vol. 47, Issue 9-11
Study on a catalytic distillation column with a novel internal
journal, November 2002
- Lin, Hongfei; Han, Minghan; Wang, Jinfu
- Chemical Engineering Communications, Vol. 189, Issue 11