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Title: Electrochromic Salts, Solutions, and Devices

Abstract

Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.

Inventors:
 [1];  [1];  [1]
  1. Los Alamos, NM
Issue Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
953748
Patent Number(s):
7436570
Application Number:
10/996,927
Assignee:
Los Alamos National Security, LLC (Los Alamos, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C09 - DYES C09K - MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
G - PHYSICS G02 - OPTICS G02F - DEVICES OR ARRANGEMENTS, THE OPTICAL OPERATION OF WHICH IS MODIFIED BY CHANGING THE OPTICAL PROPERTIES OF THE MEDIUM OF THE DEVICES OR ARRANGEMENTS FOR THE CONTROL OF THE INTENSITY, COLOUR, PHASE, POLARISATION OR DIRECTION OF LIGHT, e.g. SWITCHING, GATING, MODULATING OR DEMODULATING
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English

Citation Formats

Burrell, Anthony K, Warner, Benjamin P, and McClesky, T Mark. Electrochromic Salts, Solutions, and Devices. United States: N. p., 2008. Web.
Burrell, Anthony K, Warner, Benjamin P, & McClesky, T Mark. Electrochromic Salts, Solutions, and Devices. United States.
Burrell, Anthony K, Warner, Benjamin P, and McClesky, T Mark. Tue . "Electrochromic Salts, Solutions, and Devices". United States. https://www.osti.gov/servlets/purl/953748.
@article{osti_953748,
title = {Electrochromic Salts, Solutions, and Devices},
author = {Burrell, Anthony K and Warner, Benjamin P and McClesky, T Mark},
abstractNote = {Electrochromic salts. Electrochromic salts of dicationic viologens such as methyl viologen and benzyl viologen associated with anions selected from bis(trifluoromethylsulfonyl)imide, bis(perfluoroethylsulfonyl)imide, and tris(trifluoromethylsulfonyl)methide are produced by metathesis with the corresponding viologen dihalide. They are highly soluble in molten quarternary ammonium salts and together with a suitable reductant provide electrolyte solutions that are used in electrochromic windows.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 14 00:00:00 EDT 2008},
month = {Tue Oct 14 00:00:00 EDT 2008}
}

Works referenced in this record:

Room-Temperature Molten Salts Based on the Quaternary Ammonium Ion
journal, October 1998


Low Temperature Molten Viologens-Phase Transition and Electrochemical Properties
journal, January 1999