Corrosion-resistant metal surfaces

Sugama, Toshifumi

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Title: Corrosion-resistant metal surfaces

Abstract

The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.

Inventors:

Sugama, Toshifumi ^[1]

Wading River, NY

Issue Date:: 2009-03-24

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Assistant Secretary for Energy Efficiency and Renewable Energy (EE)

OSTI Identifier:: 951562

Patent Number(s):: 7507480

Application Number:: 11/141,674

Assignee:: Brookhaven Science Associates, LLC (Upton, NY)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

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B - PERFORMING OPERATIONS B82 - NANOTECHNOLOGY B82Y - SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES
B82Y30/00 - Nanotechnology for materials or surface science, e.g. nanocomposites

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
C08G77/26 - nitrogen-containing groups

C - CHEMISTRY C09 - DYES C09D - COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS
C09D4/00 - Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {
C09D5/084 - {Inorganic compounds}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
Y10T428/31663 - As siloxane, silicone or silane

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DOE Contract Number:: AC02-98CH10886

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

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                    Sugama, Toshifumi. Corrosion-resistant metal surfaces.  United States: N. p., 2009. 
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                    Sugama, Toshifumi. Corrosion-resistant metal surfaces.  United States.

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                    Sugama, Toshifumi. Tue .  
        "Corrosion-resistant metal surfaces".  United States.  https://www.osti.gov/servlets/purl/951562.

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@article{osti_951562,

  title        = {Corrosion-resistant metal surfaces},

  author       = {Sugama, Toshifumi},

  abstractNote = {The present invention relates to metal surfaces having thereon an ultrathin (e.g., less than ten nanometer thickness) corrosion-resistant film, thereby rendering the metal surfaces corrosion-resistant. The corrosion-resistant film includes an at least partially crosslinked amido-functionalized silanol component in combination with rare-earth metal oxide nanoparticles. The invention also relates to methods for producing such corrosion-resistant films.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2009},

  month        = {3}

}

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Works referenced in this record:

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journal, June 2002

Aramaki, Kunitsugu
Corrosion Science, Vol. 44, Issue 6
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An XPS study of cerium dopants in sol–gel coatings for aluminum 2024-T3
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Corrosion protection of high copper aluminium alloys by surface modification
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Mansfeld, F.; Wang, Y.
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The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl
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Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review
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The corrosion inhibition of zinc with cerous chloride
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Hinton, B. R. W.; Wilson, L.
Corrosion Science, Vol. 29, Issue 8
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Virtanen, S.; Ives, M. B.; Sproule, G. I.
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Mansfeld, F.; Breslin, C. B.; Pardo, A.
Surface and Coatings Technology, Vol. 90, Issue 3
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journal, March 1992

Hinton, B. R. W.
Journal of Alloys and Compounds, Vol. 180, Issue 1-2
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Electrochemical study of the corrosion behavior of Ce sealing of anodized 2024 aluminum alloy
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Yu, Xingwen; Cao, Chunan
Thin Solid Films, Vol. 423, Issue 2
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Pitting and surface modification of SIC/Al
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Corrosion Science, Vol. 27, Issue 9
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Influence of Rare-Earth Metal Passivation Treatments on the Dissolution of Tin-Zinc Coatings
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Breslin, C. B.; Geary, M.
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Chemical treatment with cerium to improve the crevice corrosion resistance of austenitic stainless steels
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Lu, Y. C.; Ives, M. B.
Corrosion Science, Vol. 37, Issue 1
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XPS and SEM characterization of hydrated cerium oxide conversion coatings
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Cationic-Film-Forming Inhibitors for the Protection of the AA 7075 Aluminum Alloy Against Corrosion in Aqueous Chloride Solution
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CORROSION, Vol. 45, Issue 1
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ATR characterisation of synergistic corrosion inhibition of mild steel surfaces by cerium salicylate
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Corrosion Science, Vol. 44, Issue 11
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Use of the Scanning Reference Electrode Technique for the Evaluation of Environmentally Friendly, Nonchromate Corrosion Inhibitors
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The Investigation of Cerium as a Cathodic Inhibitor for Aluminum-Copper Alloys
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An X-ray absorption study of the local structure of cerium in electrochemically deposited thin films
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Similar Records

Title: Corrosion-resistant metal surfaces

Abstract

Citation Formats

Cerium(III) chloride and sodium octylthiopropionate as an effective inhibitor mixture for zinc corrosion in 0.5 M NaCl journal, June 2002

An XPS study of cerium dopants in sol–gel coatings for aluminum 2024-T3 journal, May 2001

CeCl3 and LaCl3 binary solutions as environment-friendly corrosion inhibitors of AA5083 Al–Mg alloy in NaCl solutions journal, July 2001

Cerium: a suitable green corrosion inhibitor for tinplate journal, March 2002

Corrosion protection of high copper aluminium alloys by surface modification journal, January 1994

The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl journal, March 2001

Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review journal, November 1998

The corrosion inhibition of zinc with cerous chloride journal, January 1989

A surface analytical and electrochemical study on the role of cerium in the chemical surface treatment of stainless steels journal, October 1997

Surface modification of stainless steels: green technology for corrosion protection journal, April 1997

Corrosion inhibition with rare earth metal salts journal, March 1992

Electrochemical study of the corrosion behavior of Ce sealing of anodized 2024 aluminum alloy journal, January 2003

Pitting and surface modification of SIC/Al journal, January 1987

Influence of Rare-Earth Metal Passivation Treatments on the Dissolution of Tin-Zinc Coatings journal, December 1998

Chemical treatment with cerium to improve the crevice corrosion resistance of austenitic stainless steels journal, January 1995

XPS and SEM characterization of hydrated cerium oxide conversion coatings journal, July 1995

Cerium-based conversion layers on aluminum alloys journal, March 2001

Cationic-Film-Forming Inhibitors for the Protection of the AA 7075 Aluminum Alloy Against Corrosion in Aqueous Chloride Solution journal, January 1989

ATR characterisation of synergistic corrosion inhibition of mild steel surfaces by cerium salicylate journal, November 2002

Use of the Scanning Reference Electrode Technique for the Evaluation of Environmentally Friendly, Nonchromate Corrosion Inhibitors journal, November 1999

The Investigation of Cerium as a Cathodic Inhibitor for Aluminum-Copper Alloys journal, January 1995

An X-ray absorption study of the local structure of cerium in electrochemically deposited thin films journal, June 1999

The improvement of the localized corrosion resistance of stainless steel by cerium journal, November 1993

Development of “Stainless Aluminum” journal, January 1991

Characterization of cerium-based conversion coatings for corrosion protection of aluminum alloys journal, June 2002

Corrosion behavior of rare earth metal (REM) conversion coatings on aluminum alloy LY12 journal, May 2000

Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts journal, January 2001

Development of “stainless” aluminum alloys by surface modification journal, July 1995

Cerium(III) chloride and sodium octylthiopropionate as an effective inhibitor mixture for zinc corrosion in 0.5 M NaCl
journal, June 2002

An XPS study of cerium dopants in sol–gel coatings for aluminum 2024-T3
journal, May 2001

CeCl3 and LaCl3 binary solutions as environment-friendly corrosion inhibitors of AA5083 Al–Mg alloy in NaCl solutions
journal, July 2001

Cerium: a suitable green corrosion inhibitor for tinplate
journal, March 2002

Corrosion protection of high copper aluminium alloys by surface modification
journal, January 1994

The inhibition effects of chromate-free, anion inhibitors on corrosion of zinc in aerated 0.5 M NaCl
journal, March 2001

Lanthanide compounds as environmentally-friendly corrosion inhibitors of aluminium alloys: a review
journal, November 1998

The corrosion inhibition of zinc with cerous chloride
journal, January 1989

A surface analytical and electrochemical study on the role of cerium in the chemical surface treatment of stainless steels
journal, October 1997

Surface modification of stainless steels: green technology for corrosion protection
journal, April 1997

Corrosion inhibition with rare earth metal salts
journal, March 1992

Electrochemical study of the corrosion behavior of Ce sealing of anodized 2024 aluminum alloy
journal, January 2003

Pitting and surface modification of SIC/Al
journal, January 1987

Influence of Rare-Earth Metal Passivation Treatments on the Dissolution of Tin-Zinc Coatings
journal, December 1998

Chemical treatment with cerium to improve the crevice corrosion resistance of austenitic stainless steels
journal, January 1995

XPS and SEM characterization of hydrated cerium oxide conversion coatings
journal, July 1995

Cerium-based conversion layers on aluminum alloys
journal, March 2001

Cationic-Film-Forming Inhibitors for the Protection of the AA 7075 Aluminum Alloy Against Corrosion in Aqueous Chloride Solution
journal, January 1989

ATR characterisation of synergistic corrosion inhibition of mild steel surfaces by cerium salicylate
journal, November 2002

Use of the Scanning Reference Electrode Technique for the Evaluation of Environmentally Friendly, Nonchromate Corrosion Inhibitors
journal, November 1999

The Investigation of Cerium as a Cathodic Inhibitor for Aluminum-Copper Alloys
journal, January 1995

An X-ray absorption study of the local structure of cerium in electrochemically deposited thin films
journal, June 1999

The improvement of the localized corrosion resistance of stainless steel by cerium
journal, November 1993

Development of “Stainless Aluminum”
journal, January 1991

Characterization of cerium-based conversion coatings for corrosion protection of aluminum alloys
journal, June 2002

Corrosion behavior of rare earth metal (REM) conversion coatings on aluminum alloy LY12
journal, May 2000

Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts
journal, January 2001

Development of “stainless” aluminum alloys by surface modification
journal, July 1995