Lithium metal oxide electrodes for lithium batteries

Thackeray, Michael M; Kim, Jeom-Soo; Johnson, Christopher S

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Title: Lithium metal oxide electrodes for lithium batteries

Abstract

An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

Inventors:

Thackeray, Michael M ^[1]; Kim, Jeom-Soo ^[1]; Johnson, Christopher S ^[1]

Naperville, IL

Issue Date:: 2008-01-01

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 921670

Patent Number(s):: 7314682

Application Number:: 10/825,931

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Classifications (CPCs):: C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

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C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01G - COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
C01G45/1228 - {of the type [MnO2]n- , e.g. LiMnO2, Li[MxMn1-x]O2}
C01G45/125 - {of the type[MnO3]n-, e.g. Li2MnO3, Li2[MxMn1-xO3],
C01G51/50 - {of the type [MnO2]n- , e.g. Li
C01G53/50 - {of the type [MnO2]n- , e.g. Li

C - CHEMISTRY C01 - INORGANIC CHEMISTRY C01P - INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
C01P2002/72 - by d-values or two theta-values, e.g. as X-ray diagram
C01P2002/77 - by unit-cell parameters, atom positions or structure diagrams
C01P2004/80 - Particles consisting of a mixture of two or more inorganic phases
C01P2006/40 - Electric properties

H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
H01M10/052 - Li-accumulators
H01M2004/021 - {Physical characteristics, e.g. porosity, surface area}
H01M4/04 - Processes of manufacture in general
H01M4/0471 - {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
H01M4/131 - Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
H01M4/485 - of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
H01M4/505 - of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
H01M4/525 - of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02E - REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
Y02E60/10 - Energy storage

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DOE Contract Number:: W-31109-ENG-38

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Thackeray, Michael M, Kim, Jeom-Soo, and Johnson, Christopher S. Lithium metal oxide electrodes for lithium batteries.  United States: N. p., 2008. 
        Web.

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                    Thackeray, Michael M, Kim, Jeom-Soo, & Johnson, Christopher S. Lithium metal oxide electrodes for lithium batteries.  United States.

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                    Thackeray, Michael M, Kim, Jeom-Soo, and Johnson, Christopher S. Tue .  
        "Lithium metal oxide electrodes for lithium batteries".  United States.  https://www.osti.gov/servlets/purl/921670.

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@article{osti_921670,

  title        = {Lithium metal oxide electrodes for lithium batteries},

  author       = {Thackeray, Michael M and Kim, Jeom-Soo and Johnson, Christopher S},

  abstractNote = {An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2008},

  month        = {1}

}

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Works referenced in this record:

Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel
journal, December 1993

Gummow, R. J.; Liles, Dc; Thackeray, Mm
Materials Research Bulletin, Vol. 28, Issue 12
https://doi.org/10.1016/0025-5408(93)90172-A

High-Performance ZrO₂-Coated LiNiO₂ Cathode Material
journal, January 2001

Cho, Jaephil; Kim, Tae-Joon; Kim, Yong Jeong
Electrochemical and Solid-State Letters, Vol. 4, Issue 10, p. A159-A161
https://doi.org/10.1149/1.1398556

Effect of a ZrO₂ Coating on the Structure and Electrochemistry of Li_xCoO₂ When Cycled to 4.5 V
journal, January 2002

Chen, Zhaohui; Dahn, J. R.
Electrochemical and Solid-State Letters, Vol. 5, Issue 10, p. A213-A216
https://doi.org/10.1149/1.1503202

Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999

Johnson, C. S.; Korte, S. D.; Vaughey, J. T.
Journal of Power Sources, Vol. 81-82
https://doi.org/10.1016/S0378-7753(99)00248-7

Surface treatments of Li_1+xMn_2−xO₄ spinels for improved elevated temperature performance
journal, December 1997

Amatucci, G. G.; Blyr, A.; Sigala, C.
Solid State Ionics, Vol. 104, Issue 1-2, p. 13-25
https://doi.org/10.1016/S0167-2738(97)00407-4

Improvement of Structural Stability of LiMn[sub 2]O[sub 4] Cathode Material on 55°C Cycling by Sol-Gel Coating of LiCoO[sub 2]
journal, January 1999

Cho, Jaephil
Electrochemical and Solid-State Letters, Vol. 2, Issue 12
https://doi.org/10.1149/1.1390922

Novel LiCoO₂ Cathode Material with Al₂O₃ Coating for a Li Ion Cell
journal, December 2000

Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791
https://doi.org/10.1021/cm000511k

The Effect of Al[sub 2]O[sub 3] Coating on the Cycle Life Performance in Thin-Film LiCoO[sub 2] Cathodes
journal, January 2002

Kim, Yong Jeong; Kim, Tae-Joon; Shin, Jae Wook
Journal of The Electrochemical Society, Vol. 149, Issue 10
https://doi.org/10.1149/1.1505634

Zero-Strain Intercalation Cathode for Rechargeable Li-Ion Cell
journal, September 2001

Cho, Jaephil; Kim, Yong Jeong; Kim, Tae-Joon
Angewandte Chemie International Edition, Vol. 40, Issue 18, p. 3367-3369
URL: 10.1002/1521-3773(20010917)40:18<3367::AID-ANIE3367>3.0.CO;2-A

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Similar Records

Title: Lithium metal oxide electrodes for lithium batteries

Abstract

Citation Formats

Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel journal, December 1993

High-Performance ZrO2-Coated LiNiO2 Cathode Material journal, January 2001

Effect of a ZrO2 Coating on the Structure and Electrochemistry of LixCoO2 When Cycled to 4.5 V journal, January 2002

Structural and electrochemical analysis of layered compounds from Li2MnO3 journal, September 1999

Surface treatments of Li1+xMn2−xO4 spinels for improved elevated temperature performance journal, December 1997

Improvement of Structural Stability of LiMn[sub 2]O[sub 4] Cathode Material on 55°C Cycling by Sol-Gel Coating of LiCoO[sub 2] journal, January 1999

Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell journal, December 2000

The Effect of Al[sub 2]O[sub 3] Coating on the Cycle Life Performance in Thin-Film LiCoO[sub 2] Cathodes journal, January 2002

Zero-Strain Intercalation Cathode for Rechargeable Li-Ion Cell journal, September 2001

Lithium extraction from orthorhombic lithium manganese oxide and the phase transformation to spinel
journal, December 1993

High-Performance ZrO₂-Coated LiNiO₂ Cathode Material
journal, January 2001

Effect of a ZrO₂ Coating on the Structure and Electrochemistry of Li_xCoO₂ When Cycled to 4.5 V
journal, January 2002

Structural and electrochemical analysis of layered compounds from Li2MnO3
journal, September 1999

Surface treatments of Li_1+xMn_2−xO₄ spinels for improved elevated temperature performance
journal, December 1997

Improvement of Structural Stability of LiMn[sub 2]O[sub 4] Cathode Material on 55°C Cycling by Sol-Gel Coating of LiCoO[sub 2]
journal, January 1999

Novel LiCoO₂ Cathode Material with Al₂O₃ Coating for a Li Ion Cell
journal, December 2000

The Effect of Al[sub 2]O[sub 3] Coating on the Cycle Life Performance in Thin-Film LiCoO[sub 2] Cathodes
journal, January 2002

Zero-Strain Intercalation Cathode for Rechargeable Li-Ion Cell
journal, September 2001