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Title: Oxygen-consuming chlor alkali cell configured to minimize peroxide formation

Abstract

Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.

Inventors:
 [1];  [2];  [3]
  1. Los Alamos, NM
  2. Brookfield, CT
  3. Niskayuna, NY
Issue Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
908309
Patent Number(s):
7083708
Application Number:
10/631,073
Assignee:
The Regents of the University of California (Los Alamos, NM)
Patent Classifications (CPCs):
C - CHEMISTRY C25 - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES C25B - ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS
H - ELECTRICITY H01 - BASIC ELECTRIC ELEMENTS H01M - PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Chlistunoff, Jerzy B, Lipp, Ludwig, and Gottesfeld, Shimshon. Oxygen-consuming chlor alkali cell configured to minimize peroxide formation. United States: N. p., 2006. Web.
Chlistunoff, Jerzy B, Lipp, Ludwig, & Gottesfeld, Shimshon. Oxygen-consuming chlor alkali cell configured to minimize peroxide formation. United States.
Chlistunoff, Jerzy B, Lipp, Ludwig, and Gottesfeld, Shimshon. Tue . "Oxygen-consuming chlor alkali cell configured to minimize peroxide formation". United States. https://www.osti.gov/servlets/purl/908309.
@article{osti_908309,
title = {Oxygen-consuming chlor alkali cell configured to minimize peroxide formation},
author = {Chlistunoff, Jerzy B and Lipp, Ludwig and Gottesfeld, Shimshon},
abstractNote = {Oxygen-consuming zero gap chlor-alkali cell was configured to minimize peroxide formation. The cell included an ion-exchange membrane that divided the cell into an anode chamber including an anode and a cathode chamber including an oxygen gas diffusion cathode. The cathode included a single-piece of electrically conducting graphitized carbon cloth. Catalyst and polytetrafluoroethylene were attached to only one side of the cloth. When the cathode was positioned against the cation exchange membrane with the catalyst side away from the membrane, electrolysis of sodium chloride to chlorine and caustic (sodium hydroxide) proceeded with minimal peroxide formation.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Aug 01 00:00:00 EDT 2006},
month = {Tue Aug 01 00:00:00 EDT 2006}
}