Palladium (II) catalyized polymers of norbornene and acrylates
Abstract
Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.
- Inventors:
- Issue Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 880587
- Patent Number(s):
- 6300440
- Application Number:
- 09/565,137
- Assignee:
- The Penn State Research Foundation (N/A)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- DOE Contract Number:
- FG02-84ER13295
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2000 May 05
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. Palladium (II) catalyized polymers of norbornene and acrylates. United States: N. p., 2001.
Web.
Sen, Ayusman, Kacker, Smita, Hennis, April, & Polley, Jennifer D. Palladium (II) catalyized polymers of norbornene and acrylates. United States.
Sen, Ayusman, Kacker, Smita, Hennis, April, and Polley, Jennifer D. Tue .
"Palladium (II) catalyized polymers of norbornene and acrylates". United States. https://www.osti.gov/servlets/purl/880587.
@article{osti_880587,
title = {Palladium (II) catalyized polymers of norbornene and acrylates},
author = {Sen, Ayusman and Kacker, Smita and Hennis, April and Polley, Jennifer D.},
abstractNote = {Homopolymers or copolymers of acrylates, homopolymers or copolymers of norbornenes, and copolymers of acrylates with norbornenes, may be prepared by contacting acrylate and/or norbornene monomer reactant under polymerization conditions and in the presence of a solvent with a catalyst system consisting essentially of a Pd(II) dimer component having the formula: where L is a monodentate phosphorus or nitrogen ligand, X is an anionic group, and R is an alkyl or aryl group.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Oct 09 00:00:00 EDT 2001},
month = {Tue Oct 09 00:00:00 EDT 2001}
}
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Works referenced in this record:
Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate
journal, February 1998
- Mecking, Stefan; Johnson, Lynda K.; Wang, Lin
- Journal of the American Chemical Society, Vol. 120, Issue 5