Synthesis Of 2h- And 13c-Substituted Dithanes

Martinez, Rodolfo A; Alvarez, Marc A; Unkefer, Clifford J

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Title: Synthesis Of 2h- And 13c-Substituted Dithanes

Abstract

The present invention is directed to labeled compounds, [2-.sup.13 C]dithane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to processes of preparing [2-.sup.13 C]dithane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to labeled compounds, e.g., [.sup.2 H.sub.1-2, .sup.13 C]methanol (arylthio)-, acetates wherein the .sup.13 C atom is directly bonded to exactly one or two deuterium atoms.

Inventors:

Martinez, Rodolfo A ^[1]; Alvarez, Marc A ^[1]; Silks, III, Louis A. ^[2]; Unkefer, Clifford J ^[3]

Santa Fe, NM
(Los Alamos, NM)
Los Alamos, NM

Issue Date:: 2004-05-04

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

OSTI Identifier:: 879987

Patent Number(s):: 6730805

Application Number:: 10/405683

Assignee:: The Regents of the University of California (Los Alamos, NM)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07B - GENERAL METHODS OF ORGANIC CHEMISTRY
C07B2200/05 - Isotopically modified compounds, e.g. labelled

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C319/14 - of sulfides
C07C323/12 - the carbon skeleton being acyclic and saturated

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
G01N33/54373 - {involving physiochemical end-point determination, e.g. wave-guides, FETS, gratings}
G01N33/5438 - {Electrodes}
G01N33/54386 - {Analytical elements}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10S - TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y10S435/808 - Optical sensing apparatus
Y10S435/966 - involving an enzyme system with high turnover rate or complement magnified assay, e.g. multi-enzyme systems
Y10S436/805 - Optical property
Y10S436/806 - Electrical property or magnetic property
Y10S436/808 - Automated or kit
Y10S436/823 - Immunogenic carrier or carrier per se
Y10S530/811 - Peptides or proteins is immobilized on, or in, an inorganic carrier
Y10S530/812 - Peptides or proteins is immobilized on, or in, an organic carrier

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DOE Contract Number:: W-7405-ENG-36

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Citation Formats


                    Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., and Unkefer, Clifford J. Synthesis Of 2h- And 13c-Substituted Dithanes.  United States: N. p., 2004. 
        Web.

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                    Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., & Unkefer, Clifford J. Synthesis Of 2h- And 13c-Substituted Dithanes.  United States.

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                    Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., and Unkefer, Clifford J. Tue .  
        "Synthesis Of 2h- And 13c-Substituted Dithanes".  United States.  https://www.osti.gov/servlets/purl/879987.

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@article{osti_879987,

  title        = {Synthesis Of 2h- And 13c-Substituted Dithanes},

  author       = {Martinez, Rodolfo A and Alvarez, Marc A and Silks, III, Louis A. and Unkefer, Clifford J},

  abstractNote = {The present invention is directed to labeled compounds, [2-.sup.13 C]dithane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to processes of preparing [2-.sup.13 C]dithane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to labeled compounds, e.g., [.sup.2 H.sub.1-2, .sup.13 C]methanol (arylthio)-, acetates wherein the .sup.13 C atom is directly bonded to exactly one or two deuterium atoms.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2004},

  month        = {5}

}

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Works referenced in this record:

Copper induced solvolysis of sulfur compounds
journal, January 1984

Uguen, D.
Tetrahedron Letters, Vol. 25, Issue 5
https://doi.org/10.1016/S0040-4039(00)99932-5

Formation of thioacetals from sulfoxides under Pummerer-type conditions
journal, August 1976

Harris, Thomas D.; Boekelheide, V.
The Journal of Organic Chemistry, Vol. 41, Issue 16
https://doi.org/10.1021/jo00878a028

Pummerer-Type Reaction of Sulfilimines with Acetic Anhydride
journal, September 1977

Furukawa, Naomichi; Yoshimura, Toshiaki; Oae, Shigeru
Phosphorus and Sulfur and the Related Elements, Vol. 3, Issue 3
https://doi.org/10.1080/03086647708079934

Relative Reactivities of Various Sulfides, Selenides and Halides Towards SH2 Attack by Tributyltin Radicals
journal, January 1986

Beckwith, Alj; Pigou, Pe
Australian Journal of Chemistry, Vol. 39, Issue 1
https://doi.org/10.1071/CH9860077

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Similar Records

Title: Synthesis Of 2h- And 13c-Substituted Dithanes

Abstract

Citation Formats

Copper induced solvolysis of sulfur compounds journal, January 1984

Formation of thioacetals from sulfoxides under Pummerer-type conditions journal, August 1976

Pummerer-Type Reaction of Sulfilimines with Acetic Anhydride journal, September 1977

Relative Reactivities of Various Sulfides, Selenides and Halides Towards SH2 Attack by Tributyltin Radicals journal, January 1986

Copper induced solvolysis of sulfur compounds
journal, January 1984

Formation of thioacetals from sulfoxides under Pummerer-type conditions
journal, August 1976

Pummerer-Type Reaction of Sulfilimines with Acetic Anhydride
journal, September 1977

Relative Reactivities of Various Sulfides, Selenides and Halides Towards SH2 Attack by Tributyltin Radicals
journal, January 1986