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Title: Synthesis of 2H- and 13C-substituted dithanes

Abstract

The present invention is directed to labeled compounds, [2-.sup.13 C]dithiane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to processes of preparing [2-.sup.13 C]dithiane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to labeled compounds, e.g., [.sup.2 H.sub.1-2, .sup.13 C]methanol (arylthio)-, acetates wherein the .sup.13 C atom is directly bonded to exactly one or two deuterium atoms.

Inventors:
 [1];  [1];  [2];  [3]
  1. Santa Fe, NM
  2. (Los Alamos, NM)
  3. Los Alamos, NM
Issue Date:
Research Org.:
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
OSTI Identifier:
875140
Patent Number(s):
6541671
Assignee:
The Regents of the University of California (Los Alamos, NM)
DOE Contract Number:  
W-7405-ENG-36
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
synthesis; 2h-; 13c-substituted; dithanes; directed; labeled; compounds; 2-sup13; cdithiane; sup13; atom; directly; bonded; deuterium; atoms; processes; preparing; sup2; hsub1-2; cmethanol; arylthio-; acetates; exactly; labeled compounds; /999/424/

Citation Formats

Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., and Unkefer, Clifford J. Synthesis of 2H- and 13C-substituted dithanes. United States: N. p., 2003. Web.
Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., & Unkefer, Clifford J. Synthesis of 2H- and 13C-substituted dithanes. United States.
Martinez, Rodolfo A, Alvarez, Marc A, Silks, III, Louis A., and Unkefer, Clifford J. Wed . "Synthesis of 2H- and 13C-substituted dithanes". United States. https://www.osti.gov/servlets/purl/875140.
@article{osti_875140,
title = {Synthesis of 2H- and 13C-substituted dithanes},
author = {Martinez, Rodolfo A and Alvarez, Marc A and Silks, III, Louis A. and Unkefer, Clifford J},
abstractNote = {The present invention is directed to labeled compounds, [2-.sup.13 C]dithiane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to processes of preparing [2-.sup.13 C]dithiane wherein the .sup.13 C atom is directly bonded to one or two deuterium atoms. The present invention is also directed to labeled compounds, e.g., [.sup.2 H.sub.1-2, .sup.13 C]methanol (arylthio)-, acetates wherein the .sup.13 C atom is directly bonded to exactly one or two deuterium atoms.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2003},
month = {1}
}

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Works referenced in this record:

Stereoelectronic effects in the gas-phase. 2. Negative ion reactions of 1,3-dithianes and 1,3-dithiane 1-oxides
journal, September 1989

  • Fisher, Cindy L.; Kahn, Scott D.; Hehre, Warren J.
  • Journal of the American Chemical Society, Vol. 111, Issue 19
  • DOI: 10.1021/ja00201a015

The use of metalloids (-SiMe3,-SnR3) as protected carbanions
journal, January 1981


9-Phenylfluorene: a powerful labeling agent
journal, July 2001


Protonic and conformational equilibriums of 1,3-dithiaalkanes and their congeners in highly acidic media
journal, December 1979

  • Lambert, Joseph B.; Majchrzak, Michal W.; Stec, Daniel
  • The Journal of Organic Chemistry, Vol. 44, Issue 25
  • DOI: 10.1021/jo00393a046