Catalyst structure and method of fischer-tropsch synthesis

Wang, Yong; Vanderwiel, David P; Tonkovich, Anna Lee Y; Gao, Yufei; Baker, Eddie G

Title: Catalyst structure and method of fischer-tropsch synthesis

Abstract

The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.

Inventors:

Wang, Yong ^[1]; Vanderwiel, David P ^[1]; Tonkovich, Anna Lee Y ^[2]; Gao, Yufei ^[3]; Baker, Eddie G ^[2]

Richland, WA
Pasco, WA
Kennewick, WA

Issue Date:: 2002-12-10

Research Org.:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 874930

Patent Number(s):: 6491880

Application Number:: 09/492245

Assignee:: Battelle Memorial Institute (Richland, WA)

Patent Classifications (CPCs):: B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/32244 - Essentially circular apertures
B01J2219/00783 - Laminate assemblies, i.e. the reactor comprising a stack of plates

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/0455 - {Reaction conditions}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J37/0225 - {of metal substrates}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/33 - {characterised by the catalyst used}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/00984 - Residence time
B01J2219/32408 - Metal
B01J19/248 - {Reactors comprising multiple separated flow channels}
B01J19/2495 - {Net-type reactors}
B01J35/0006 - {Catalysts containing parts with different compositions}
B01J19/0093 - {Microreactors, e.g. miniaturised or microfabricated reactors

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/75 - Cobalt

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/2453 - Plates arranged in parallel
B01J2219/0086 - Dimensions of the flow channels
B01J12/007 - {in the presence of catalytically active bodies, e.g. porous plates}
B01J2219/00835 - Comprising catalytically active material
B01J35/04 - Foraminous structures, sieves, grids, honeycombs
B01J19/249 - {Plate-type reactors}
B01J37/0248 - {Coatings comprising impregnated particles}
B01J2219/00822 - Metal

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/32 - {with the use of catalysts}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J35/10 - characterised by their surface properties or porosity
B01J8/0285 - {Heating or cooling the reactor

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/341 - {with stationary catalyst bed}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/745 - Iron

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/32293 - Cubes or cubic blocks
B01J37/0238 - {via the gaseous phase-sublimation}
B01J37/0244 - {Coatings comprising several layers}
B01J2219/32296 - Honeycombs

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/0425 - {Catalysts

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/2462 - the reactants being in indirect heat exchange with a non reacting heat exchange medium
B01J2219/32475 - involving heat exchange
B01J2219/32466 - comprising catalytically active material
B01J2219/2458 - Flat plates, i.e. plates which are not corrugated or otherwise structured, e.g. plates with cylindrical shape

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C2523/46 - Ruthenium, rhodium, osmium or iridium

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J2219/00844 - Comprising porous material
B01J2219/00873 - Heat exchange

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/34 - {Apparatus, reactors}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C1/041 - {Reactors}

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
B01J37/0217 - {Pretreatment of the substrate before coating}
B01J23/8913 - {Cobalt and noble metals}
B01J35/1076 - {larger than 1000 nm}

C - CHEMISTRY C10 - PETROLEUM, GAS OR COKE INDUSTRIES C10G - CRACKING HYDROCARBON OILS
C10G2/332 - {of the iron-group}

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DOE Contract Number:: AC06-76RL01830

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: catalyst; structure; method; fischer-tropsch; synthesis; catalysts; reactions; methods; processes; hydrogenating; carbon; monoxide; fuels; provides; ability; hydrogenate; contact; times; conversion; rates; methane; selectivities; metal; foam; support; carbon monoxide; preferred method; fischer-tropsch synthesis; catalyst structure; /422/

Citation Formats


                    Wang, Yong, Vanderwiel, David P, Tonkovich, Anna Lee Y, Gao, Yufei, and Baker, Eddie G. Catalyst structure and method of fischer-tropsch synthesis.  United States: N. p., 2002. 
        Web.

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                    Wang, Yong, Vanderwiel, David P, Tonkovich, Anna Lee Y, Gao, Yufei, & Baker, Eddie G. Catalyst structure and method of fischer-tropsch synthesis.  United States.

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                    Wang, Yong, Vanderwiel, David P, Tonkovich, Anna Lee Y, Gao, Yufei, and Baker, Eddie G. Tue .  
        "Catalyst structure and method of fischer-tropsch synthesis".  United States.  https://www.osti.gov/servlets/purl/874930.

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@article{osti_874930,

  title        = {Catalyst structure and method of fischer-tropsch synthesis},

  author       = {Wang, Yong and Vanderwiel, David P and Tonkovich, Anna Lee Y and Gao, Yufei and Baker, Eddie G},

  abstractNote = {The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2002},

  month        = {12}

}

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Works referenced in this record:

Foam metal catalysts with intermediate support for deep oxidation of hydrocarbons
journal, November 1994

Pestryakov, A. N.; Fyodorov, A. A.; Shurov, V. A.
Reaction Kinetics & Catalysis Letters, Vol. 53, Issue 2
https://doi.org/10.1007/BF02073041

Low methane selectivity using Co/MnO catalysts for the Fischer-Tropsch reaction: Effect of increasing pressure and Co-feeding ethene
journal, March 1995

Hutchings, Graham J.; Copperthwaite, Richard G.; van der Riet, Mark
Topics in Catalysis, Vol. 2, Issue 1-4
https://doi.org/10.1007/BF01491964

Monolithic catalyst supports with foam structure
journal, March 1997

Leonov, A. N.; Smorygo, O. L.; Sheleg, V. K.
Reaction Kinetics and Catalysis Letters, Vol. 60, Issue 2
https://doi.org/10.1007/BF02475687

Support effects in cobalt-based fischer-tropsch catalysis
journal, March 1993

Bessell, Sandra
Applied Catalysis A: General, Vol. 96, Issue 2
https://doi.org/10.1016/0926-860X(90)80014-6

Hydrogenation of Carbon Monoxide and Carbon Dioxide on Supported Ruthenium Catalysts at Moderate Pressures
journal, December 1965

Karn, F. S.; Shultz, J. F.; Anderson, R. B.
Industrial & Engineering Chemistry Product Research and Development, Vol. 4, Issue 4
https://doi.org/10.1021/i360016a014

Fischer-Tropsch reaction studies with supported ruthenium catalysts I. Product distributions at moderate pressures and catalyst deactivation
journal, June 1978

Everson, R.
Journal of Catalysis, Vol. 53, Issue 2
https://doi.org/10.1016/0021-9517(78)90066-0

On the reported attempts to radically improve the performance of the steam methane reforming reactor
journal, April 1996

Adris, A. M.; Pruden, B. B.; Lim, C. J.
The Canadian Journal of Chemical Engineering, Vol. 74, Issue 2
https://doi.org/10.1002/cjce.5450740202

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Title: Catalyst structure and method of fischer-tropsch synthesis

Abstract

Citation Formats

Foam metal catalysts with intermediate support for deep oxidation of hydrocarbons journal, November 1994

Low methane selectivity using Co/MnO catalysts for the Fischer-Tropsch reaction: Effect of increasing pressure and Co-feeding ethene journal, March 1995

Monolithic catalyst supports with foam structure journal, March 1997

Support effects in cobalt-based fischer-tropsch catalysis journal, March 1993

Hydrogenation of Carbon Monoxide and Carbon Dioxide on Supported Ruthenium Catalysts at Moderate Pressures journal, December 1965

Fischer-Tropsch reaction studies with supported ruthenium catalysts I. Product distributions at moderate pressures and catalyst deactivation journal, June 1978

On the reported attempts to radically improve the performance of the steam methane reforming reactor journal, April 1996

Foam metal catalysts with intermediate support for deep oxidation of hydrocarbons
journal, November 1994

Low methane selectivity using Co/MnO catalysts for the Fischer-Tropsch reaction: Effect of increasing pressure and Co-feeding ethene
journal, March 1995

Monolithic catalyst supports with foam structure
journal, March 1997

Support effects in cobalt-based fischer-tropsch catalysis
journal, March 1993

Hydrogenation of Carbon Monoxide and Carbon Dioxide on Supported Ruthenium Catalysts at Moderate Pressures
journal, December 1965

Fischer-Tropsch reaction studies with supported ruthenium catalysts I. Product distributions at moderate pressures and catalyst deactivation
journal, June 1978

On the reported attempts to radically improve the performance of the steam methane reforming reactor
journal, April 1996