Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen
Abstract
Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.
- Inventors:
-
- West Richland, WA
- Kennewick, WA
- Okemos, MI
- Issue Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 874873
- Patent Number(s):
- 6479713
- Assignee:
- Battelle Memorial Institute (Richland, WA)
- Patent Classifications (CPCs):
-
B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY
C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
- DOE Contract Number:
- AC06-76RL01830
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- hydrogenolysis; 5-carbon; sugars; sugar; alcohols; methods; compositions; reactions; involving; hydrogen; re-containing; catalyst; containing; alcohol; lactic; acid; described; surprisingly; discovered; reaction; multimetallic; resulted; superior; conversion; selectivity; products; propylene; glycol; process; synthesis; pg; lactate; lactic acid; compositions contain; /999/
Citation Formats
Werpy, Todd A, Zacher, Alan H, and Miller, Dennis J. Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen. United States: N. p., 2002.
Web.
Werpy, Todd A, Zacher, Alan H, & Miller, Dennis J. Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen. United States.
Werpy, Todd A, Zacher, Alan H, and Miller, Dennis J. Tue .
"Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen". United States. https://www.osti.gov/servlets/purl/874873.
@article{osti_874873,
title = {Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen},
author = {Werpy, Todd A and Zacher, Alan H and Miller, Dennis J},
abstractNote = {Methods and compositions for reactions of hydrogen over a Re-containing catalyst with compositions containing a 5-carbon sugar, sugar alcohol, or lactic acid are described. It has been surprisingly discovered that reaction with hydrogen over a Re-containing multimetallic catalyst resulted in superior conversion and selectivity to desired products such as propylene glycol. A process for the synthesis of PG from lactate or lactic acid is also described.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2002},
month = {11}
}
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Works referenced in this record:
Aqueous-phase hydrogenation of lactic acid to propylene glycol
journal, October 2001
- Zhang, Zhigang; Jackson, James E.; Miller, Dennis J.
- Applied Catalysis A: General, Vol. 219, Issue 1-2