Catalytic oxidative dehydrogenation process

Schmidt, Lanny D; Huff, Marylin

Title: Catalytic oxidative dehydrogenation process

Abstract

A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting said hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consist essentially of platinum supported on alumina or zirconia monolith, preferably zirconia and more preferably in the absence of palladium, rhodium and gold.

Inventors:

Schmidt, Lanny D ^[1]; Huff, Marylin ^[2]

Minneapolis, MN
St. Paul, MN

Issue Date:: 2002-01-01

Research Org.:: Univ. of Minnesota, Minneapolis, MN (United States)

OSTI Identifier:: 874738

Patent Number(s):: 6452061

Assignee:: Regents of the University of Minnesota (Minneapolis, MN)

Patent Classifications (CPCs):: C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS

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C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07C - ACYCLIC OR CARBOCYCLIC COMPOUNDS
C07C11/02 - Alkenes
C07C2521/04 - Alumina
C07C2521/06 - Silicon, titanium, zirconium or hafnium
C07C2523/42 - Platinum
C07C5/48 - with oxygen as an acceptor

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DOE Contract Number:: FG02-88ER13878

Resource Type:: Patent

Country of Publication:: United States

Language:: English

Subject:: catalytic; oxidative; dehydrogenation; process; production; mono-olefin; gaseous; paraffinic; hydrocarbon; carbon; atoms; mixtures; comprising; reacting; hydrocarbons; molecular; oxygen; presence; platinum; catalyst; consist; essentially; supported; alumina; zirconia; monolith; absence; palladium; rhodium; gold; molecular oxygen; carbon atom; hydrogenation process; /585/

Citation Formats


                    Schmidt, Lanny D, and Huff, Marylin. Catalytic oxidative dehydrogenation process.  United States: N. p., 2002. 
        Web.

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                    Schmidt, Lanny D, & Huff, Marylin. Catalytic oxidative dehydrogenation process.  United States.

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                    Schmidt, Lanny D, and Huff, Marylin. Tue .  
        "Catalytic oxidative dehydrogenation process".  United States.  https://www.osti.gov/servlets/purl/874738.

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@article{osti_874738,

  title        = {Catalytic oxidative dehydrogenation process},

  author       = {Schmidt, Lanny D and Huff, Marylin},

  abstractNote = {A process for the production of a mono-olefin from a gaseous paraffinic hydrocarbon having at least two carbon atoms or mixtures thereof comprising reacting said hydrocarbons and molecular oxygen in the presence of a platinum catalyst. The catalyst consist essentially of platinum supported on alumina or zirconia monolith, preferably zirconia and more preferably in the absence of palladium, rhodium and gold.},

  doi          = {},

  journal      = {},
number       = ,

  volume       = ,

  place        = {United States},

  year         = {2002},

  month        = {1}

}

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Works referenced in this record:

Dehydrogenation of isobutane to isobutene in a palladium membrane reactor
journal, March 1993

Matsuda, Takeshi; Koike, Isao; Kubo, Noboru
Applied Catalysis A: General, Vol. 96, Issue 1
https://doi.org/10.1016/0926-860X(93)80002-8

Ethylene formation by oxidative dehydrogenation of ethane over monoliths at very short contact times
journal, November 1993

Huff, M.; Schmidt, L. D.
The Journal of Physical Chemistry, Vol. 97, Issue 45
https://doi.org/10.1021/j100147a040

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Title: Catalytic oxidative dehydrogenation process

Abstract

Citation Formats

Dehydrogenation of isobutane to isobutene in a palladium membrane reactor journal, March 1993

Ethylene formation by oxidative dehydrogenation of ethane over monoliths at very short contact times journal, November 1993

Dehydrogenation of isobutane to isobutene in a palladium membrane reactor
journal, March 1993

Ethylene formation by oxidative dehydrogenation of ethane over monoliths at very short contact times
journal, November 1993