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Title: Embedded cluster metal-polymeric micro interface and process for producing the same

Abstract

A micro interface between a polymeric layer and a metal layer includes isolated clusters of metal partially embedded in the polymeric layer. The exposed portion of the clusters is smaller than embedded portions, so that a cross section, taken parallel to the interface, of an exposed portion of an individual cluster is smaller than a cross section, taken parallel to the interface, of an embedded portion of the individual cluster. At least half, but not all of the height of a preferred spherical cluster is embedded. The metal layer is completed by a continuous layer of metal bonded to the exposed portions of the discontinuous clusters. The micro interface is formed by heating a polymeric layer to a temperature, near its glass transition temperature, sufficient to allow penetration of the layer by metal clusters, after isolated clusters have been deposited on the layer at lower temperatures. The layer is recooled after embedding, and a continuous metal layer is deposited upon the polymeric layer to bond with the discontinuous metal clusters.

Inventors:
 [1];  [2];  [2]
  1. Santa Clara, CA
  2. Champaign, IL
Issue Date:
OSTI Identifier:
874216
Patent Number(s):
6342307
Application Number:
08/976,670
Assignee:
The Board of Trustees of the University of Illinois (Urbana, IL)
Patent Classifications (CPCs):
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
C - CHEMISTRY C23 - COATING METALLIC MATERIAL C23C - COATING METALLIC MATERIAL
DOE Contract Number:  
1-5-27114
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
embedded; cluster; metal-polymeric; micro; interface; process; producing; polymeric; layer; metal; isolated; clusters; partially; exposed; portion; portions; section; parallel; individual; half; height; spherical; completed; continuous; bonded; discontinuous; formed; heating; temperature; near; glass; transition; sufficient; allow; penetration; deposited; temperatures; recooled; embedding; bond; metal layer; glass transition; /428/

Citation Formats

Menezes, Marlon E, Birnbaum, Howard K, and Robertson, Ian M. Embedded cluster metal-polymeric micro interface and process for producing the same. United States: N. p., 2002. Web.
Menezes, Marlon E, Birnbaum, Howard K, & Robertson, Ian M. Embedded cluster metal-polymeric micro interface and process for producing the same. United States.
Menezes, Marlon E, Birnbaum, Howard K, and Robertson, Ian M. Tue . "Embedded cluster metal-polymeric micro interface and process for producing the same". United States. https://www.osti.gov/servlets/purl/874216.
@article{osti_874216,
title = {Embedded cluster metal-polymeric micro interface and process for producing the same},
author = {Menezes, Marlon E and Birnbaum, Howard K and Robertson, Ian M},
abstractNote = {A micro interface between a polymeric layer and a metal layer includes isolated clusters of metal partially embedded in the polymeric layer. The exposed portion of the clusters is smaller than embedded portions, so that a cross section, taken parallel to the interface, of an exposed portion of an individual cluster is smaller than a cross section, taken parallel to the interface, of an embedded portion of the individual cluster. At least half, but not all of the height of a preferred spherical cluster is embedded. The metal layer is completed by a continuous layer of metal bonded to the exposed portions of the discontinuous clusters. The micro interface is formed by heating a polymeric layer to a temperature, near its glass transition temperature, sufficient to allow penetration of the layer by metal clusters, after isolated clusters have been deposited on the layer at lower temperatures. The layer is recooled after embedding, and a continuous metal layer is deposited upon the polymeric layer to bond with the discontinuous metal clusters.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2002},
month = {1}
}

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Works referenced in this record:

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