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Title: Synthesis of perhydroxydodecaborate salts and related species

Abstract

New icosahedral borohydrates Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ]; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with a hydroxylating agent, preferably 30%.sub.w hydrogen peroxide.

Inventors:
 [1];  [2];  [2]
  1. (Encino, CA)
  2. (Los Angeles, CA)
Issue Date:
Research Org.:
University of California
OSTI Identifier:
874138
Patent Number(s):
6323372
Assignee:
The Regents of the University of California (Oakland, CA) OAK
DOE Contract Number:  
FG03-95ER61975
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
synthesis; perhydroxydodecaborate; salts; related; species; icosahedral; borohydrates; cssub2; closo-bsub12; ohsub12; cscloso-1-h-1-cbsub11; ohsub11; closo-112-hsub2; -112-csub2; bsub10; ohsub10; disclosed; set; forth; preparation; refluxing; boranes; hsub12; sup2-; closo-1-cbsub11; sup-; closo-112-chsub2; ohsub2; hsub10; hydroxylating; agent; 30subw; hydrogen; peroxide; set forth; /999/

Citation Formats

Hawthorne, M. Frederick, Peymann, Toralf, and Herzog, Axel Hans-Joachim. Synthesis of perhydroxydodecaborate salts and related species. United States: N. p., 2001. Web.
Hawthorne, M. Frederick, Peymann, Toralf, & Herzog, Axel Hans-Joachim. Synthesis of perhydroxydodecaborate salts and related species. United States.
Hawthorne, M. Frederick, Peymann, Toralf, and Herzog, Axel Hans-Joachim. Mon . "Synthesis of perhydroxydodecaborate salts and related species". United States. https://www.osti.gov/servlets/purl/874138.
@article{osti_874138,
title = {Synthesis of perhydroxydodecaborate salts and related species},
author = {Hawthorne, M. Frederick and Peymann, Toralf and Herzog, Axel Hans-Joachim},
abstractNote = {New icosahedral borohydrates Cs.sub.2 [closo-B.sub.12 (OH).sub.12 ]; Cs[closo-1-H-1-CB.sub.11 (OH).sub.11 ]; and closo-1,12-H.sub.2 -1,12-C.sub.2 B.sub.10 (OH).sub.10 are disclosed. Also set forth are their preparation by refluxing the icosahedral boranes [closo-B.sub.12 H.sub.12 ].sup.2-, [closo-1-CB.sub.11 H.sub.12 ].sup.- and closo-1,12-(CH.sub.2 OH).sub.2 -1,12-C.sub.2 B.sub.10 H.sub.10 with a hydroxylating agent, preferably 30%.sub.w hydrogen peroxide.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2001},
month = {1}
}

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