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Title: Synthesis and use of (perfluoroaryl) fluoro-aluminate anion

Abstract

A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl)-fluoroaluminate (PBA.sup..crclbar.) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed. Gallium and indium analogs are also disclosed, as are analogs with different anyl groups or different numbers of flourine atoms thereon.

Inventors:
 [1];  [2]
  1. (Evanston, IL)
  2. (Midland, MI)
Issue Date:
Research Org.:
Northwestern University
OSTI Identifier:
873714
Patent Number(s):
6229034
Assignee:
Northwestern University (Evanston, IL) CHO
DOE Contract Number:  
FG02-86ER13511
Resource Type:
Patent
Country of Publication:
United States
Language:
English
Subject:
synthesis; perfluoroaryl; fluoro-aluminate; anion; trityl; perfluorophenyl; alumninate; tris; -nonafluorobiphenyl; -fluoroaluminate; pba; crclbar; role; cocatalyst; metallocene-mediated; olefin; polymerization; disclosed; gallium; indium; analogs; anyl; flourine; atoms; thereon; olefin polymerization; perfluorophenyl alumninate; metallocene-mediated olefin; trityl perfluorophenyl; fluoro-aluminate anion; olefin polymer; /999/

Citation Formats

Marks, Tobin J., and Chen, You-Xian. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion. United States: N. p., 2001. Web.
Marks, Tobin J., & Chen, You-Xian. Synthesis and use of (perfluoroaryl) fluoro-aluminate anion. United States.
Marks, Tobin J., and Chen, You-Xian. Mon . "Synthesis and use of (perfluoroaryl) fluoro-aluminate anion". United States. https://www.osti.gov/servlets/purl/873714.
@article{osti_873714,
title = {Synthesis and use of (perfluoroaryl) fluoro-aluminate anion},
author = {Marks, Tobin J. and Chen, You-Xian},
abstractNote = {A trityl perfluorophenyl alumninate such as tris(2,2',2"-nonafluorobiphenyl)-fluoroaluminate (PBA.sup..crclbar.) and its role as a cocatalyst in metallocene-mediated olefin polymerization is disclosed. Gallium and indium analogs are also disclosed, as are analogs with different anyl groups or different numbers of flourine atoms thereon.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {2001},
month = {1}
}

Patent:

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