Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions
Abstract
A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.
- Inventors:
-
- Oak Ridge, TN
- Knoxville, TN
- Ooltewah, TN
- Issue Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- OSTI Identifier:
- 873495
- Patent Number(s):
- 6174503
- Assignee:
- Lockheed Martin Energy Research Corporation (Oak Ridge, TN)
- Patent Classifications (CPCs):
-
C - CHEMISTRY C22 - METALLURGY C22B - PRODUCTION AND REFINING OF METALS
Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y02 - TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE Y02P - CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- DOE Contract Number:
- AC05-96OR22464
- Resource Type:
- Patent
- Country of Publication:
- United States
- Language:
- English
- Subject:
- calixarene; crown; solvent; composition; extraction; cesium; alkaline; waste; solutions; corresponding; method; extracting; cs; aqueous; neutral; containing; competing; metal; described; entails; contacting; cs-containing; solution; consisting; specific; lipophilic; calix; arene-crown; extractants; dissolved; hydrocarbon-based; diluent; alkyl-aromatic; alcohols; modifiers; values; subsequently; recovered; extractant; recycled; organic; stripping; combined; especially; useful; process; removal; radionuclide; cesium-137; highly; concentrated; sodium; potassium; pre-treatment; safe; inexpensive; water; dilute; millimolar; acid; salt; application; treatment; nuclear; tank; wastes; alternatively; applied; decontamination; acidic; reprocessing; reprocessing waste; stripping process; wastes containing; alkaline solutions; organic solution; salt solutions; method entails; alkaline waste; containing organic; diluent containing; stripping solution; acid solutions; salt solution; acid solution; especially useful; waste solutions; solutions containing; waste solution; solvent composition; alkaline solution; aqueous strip; reprocessing wastes; combined extraction; containing cesium; containing solution; corresponding method; extracting cesium; processing waste; /423/252/
Citation Formats
Moyer, Bruce A, Sachleben, Richard A, Bonnesen, Peter V, and Presley, Derek J. Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions. United States: N. p., 2001.
Web.
Moyer, Bruce A, Sachleben, Richard A, Bonnesen, Peter V, & Presley, Derek J. Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions. United States.
Moyer, Bruce A, Sachleben, Richard A, Bonnesen, Peter V, and Presley, Derek J. Mon .
"Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions". United States. https://www.osti.gov/servlets/purl/873495.
@article{osti_873495,
title = {Calixarene crown ether solvent composition and use thereof for extraction of cesium from alkaline waste solutions},
author = {Moyer, Bruce A and Sachleben, Richard A and Bonnesen, Peter V and Presley, Derek J},
abstractNote = {A solvent composition and corresponding method for extracting cesium (Cs) from aqueous neutral and alkaline solutions containing Cs and perhaps other competing metal ions is described. The method entails contacting an aqueous Cs-containing solution with a solvent consisting of a specific class of lipophilic calix[4]arene-crown ether extractants dissolved in a hydrocarbon-based diluent containing a specific class of alkyl-aromatic ether alcohols as modifiers. The cesium values are subsequently recovered from the extractant, and the solvent subsequently recycled, by contacting the Cs-containing organic solution with an aqueous stripping solution. This combined extraction and stripping method is especially useful as a process for removal of the radionuclide cesium-137 from highly alkaline waste solutions which are also very concentrated in sodium and potassium. No pre-treatment of the waste solution is necessary, and the cesium can be recovered using a safe and inexpensive stripping process using water, dilute (millimolar) acid solutions, or dilute (millimolar) salt solutions. An important application for this invention would be treatment of alkaline nuclear tank wastes. Alternatively, the invention could be applied to decontamination of acidic reprocessing wastes containing cesium-137.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Jan 01 00:00:00 EST 2001},
month = {Mon Jan 01 00:00:00 EST 2001}
}
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Works referenced in this record:
Nuclear waste treatment by means of supported liquid membranes containing calixcrown compounds
journal, January 1994
- Hill, C.; Dozol, J. -F.; Lamare, V.
- Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 19, Issue 1-4
Synthesis and Binding Property of Tunable Upper-Rim Calix[4]crowns
journal, April 1996
- Paek, Kyungsoo; Ihm, Hyejae
- Chemistry Letters, Vol. 25, Issue 4
Synthesis and co-ordination chemistry of a novel bis(benzo crown ether) substituted calix[4]arene that can simultaneously complex cations and anions
journal, January 1995
- Beer, Paul D.; Drew, Michael G. B.; Knubley, Rachel J.
- Journal of the Chemical Society, Dalton Transactions, Issue 19
Cation recognition by new diester- and diamide-calix[4]arenediquinones and a diamide-benzo-15-crown-5-calix[4]arene
journal, January 1994
- Beer, Paul D.; Chen, Zheng; Gale, Philip A.
- Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, Vol. 19, Issue 1-4
Upper rim calixcrowns: elucidation of the mechanism of conformational interconversion of calix[4]arenes by quantitative 2-D EXSY NMR spectroscopy
journal, March 1991
- Van Loon, Jan Dirk; Groenen, Leo C.; Wijmenga, Sybren S.
- Journal of the American Chemical Society, Vol. 113, Issue 7
III. Cesium extractive metallurgy Ore to metal
journal, November 1966
- Dean, K. C.; Nichols, I. L.; Clemmons, B. H.
- JOM, Vol. 18, Issue 11
Synthesis, Complexation, and Membrane Transport Studies of 1,3-Alternate Calix[4]arene-crown-6 Conformers: A New Class of Cesium Selective Ionophores
journal, March 1995
- Casnati, Alessandro; Pochini, Andrea; Ungaro, Rocco
- Journal of the American Chemical Society, Vol. 117, Issue 10
Molecular engineering. Part 2.1 Influence of side-chain substituents in lariat-type upper-rim calix[4]crowns on their binding properties and the reversal of these
journal, January 1997
- Ihm, Hyejae; Kim, Hyunjun; Paek, Kyungsoo
- Journal of the Chemical Society, Perkin Transactions 1, Issue 13
Applicability of a Calixarene-Crown Compound for the Removal of Cesium from Alkaline Tank Waste
journal, January 1997
- Haverlock, Tamara J.; Bonnesen, Peter V.; Sachleben, Richard A.
- Radiochimica Acta, Vol. 76, Issue 1-2
Doubly Crowned Calix[4]arenes in the 1,3-Alternate Conformation as Cesium-Selective Carriers in Supported Liquid Membranes
journal, September 1995
- Asfari, Zouhair.; Bressot, Christophe.; Vicens, Jacques.
- Analytical Chemistry, Vol. 67, Issue 18
1,3-Dialkoxycalix[4]arenecrowns-6 in 1,3-Alternate Conformation: Cesium-Selective Ligands that Exploit Cation-Arene Interactions
journal, August 1994
- Ungaro, Rocco; Casnati, Alessandro; Ugozzoli, Franco
- Angewandte Chemie International Edition in English, Vol. 33, Issue 14
Selective extraction of cesium from acidic nitrate solutions with didodecylnaphthalenesulfonic acid synergized with bis(tert-butylbenzo)-21-crown-7
journal, December 1992
- McDowell, W. Jack.; Case, Gerald N.; McDonough, Joseph A.
- Analytical Chemistry, Vol. 64, Issue 23